Thermodynamics, Diffusion and the Kirkendall Effect in Solids PDF Download
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Author: Aloke Paul
Publisher: Springer
ISBN: 331907461X
Category : Science
Languages : en
Pages : 543
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Book Description
In this book basic and some more advanced thermodynamics and phase as well as stability diagrams relevant for diffusion studies are introduced. Following, Fick’s laws of diffusion, atomic mechanisms, interdiffusion, intrinsic diffusion, tracer diffusion and the Kirkendall effect are discussed. Short circuit diffusion is explained in detail with an emphasis on grain boundary diffusion. Recent advances in the area of interdiffusion will be introduced. Interdiffusion in multi-component systems is also explained. Many practical examples will be given, such that researches working in this area can learn the practical evaluation of various diffusion parameters from experimental results. Large number of illustrations and experimental results are used to explain the subject. This book will be appealing for students, academicians, engineers and researchers in academic institutions, industry research and development laboratories.
Author: Aloke Paul
Publisher: Springer
ISBN: 331907461X
Category : Science
Languages : en
Pages : 543
Get Book Here
Book Description
In this book basic and some more advanced thermodynamics and phase as well as stability diagrams relevant for diffusion studies are introduced. Following, Fick’s laws of diffusion, atomic mechanisms, interdiffusion, intrinsic diffusion, tracer diffusion and the Kirkendall effect are discussed. Short circuit diffusion is explained in detail with an emphasis on grain boundary diffusion. Recent advances in the area of interdiffusion will be introduced. Interdiffusion in multi-component systems is also explained. Many practical examples will be given, such that researches working in this area can learn the practical evaluation of various diffusion parameters from experimental results. Large number of illustrations and experimental results are used to explain the subject. This book will be appealing for students, academicians, engineers and researchers in academic institutions, industry research and development laboratories.
Author: Boris Samuilovich Bokshteĭn
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 328
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Book Description
Author: Eugene Machlin
Publisher: Elsevier
ISBN: 0080549683
Category : Science
Languages : en
Pages : 478
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Book Description
This book is based on a set of notes developed over many years for an introductory course taught to seniors and entering graduate students in materials science. An Introduction to Aspects of Thermodynamics and Kinetics Relevant to Materials Science is about the application of thermodynamics and kinetics to solve problems within Materials Science. Emphasis is to provide a physical understanding of the phenomenon under discussion, with the mathematics presented as a guide. The problems are used to provide practice in quantitative application of principles, and also to give examples of applications of the general subject matter to problems having current interest and to emphasize the important physical concepts. End of chapter problems are included, as are references, and bibliography to reinforce the text. This book provides students with the theory and mathematics to understand the important physical understanding of phenomena. - Based on a set of notes developed over many years for an introductory course taught to seniors and entering graduate students in materials science - Provides students with the theory and mathematics to understand the important physical understanding of phenomena - Includes end of chapter problems, references, and bibliography to reinforce the text
Author: A. R. Allnatt
Publisher: Cambridge University Press
ISBN: 9780521543422
Category : Science
Languages : en
Pages : 604
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Book Description
This book provides the fundamental statistical theory of atomic transport in crystalline solids, that is the means by which processes occurring at the atomic level are related to macroscopic transport coefficients and other observable quantities. The cornerstones of the authors' treatment are (i) the physical concepts of lattice defects, (ii) the phenomenological description provided by non-equilibrium thermodynamics and (iii) the various methods of statistical mechanics used to link these (kinetic theory, random-walk theory, linear response theory etc.). The book is primarily concerned with transport in the body of crystal lattices and not with transport on surfaces, within grain boundaries or along dislocations, although much of the theory here presented can be applied to these low-dimensional structures when they are atomically well ordered and regular.
Author: Han-Ill Yoo
Publisher: Springer Nature
ISBN: 3030259501
Category : Technology & Engineering
Languages : en
Pages : 348
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Book Description
This book provides beginning graduate or senior-level undergraduate students in materials disciplines with a primer of the fundamental and quantitative ideas on kinetic processes in solid materials. Kinetics is concerned with the rate of change of the state of existence of a material system under thermodynamic driving forces. Kinetic processes in materials typically involve chemical reactions and solid state diffusion in parallel or in tandem. Thus, mathematics of diffusion in continuum is first dealt with in some depth, followed by the atomic theory of diffusion and a brief review of chemical reaction kinetics. Chemical diffusion in metals and ionic solids, diffusion-controlled kinetics of phase transformations, and kinetics of gas-solid reactions are examined. Through this course of learning, a student will become able to predict quantitatively how fast a kinetic process takes place, to understand the inner workings of the process, and to design the optimal process of material state change. Provides students with the tools to predict quantitatively how fast a kinetic process takes place and solve other diffusion related problems; Learns fundamental and quantitative ideas on kinetic processes in solid materials; Examines chemical diffusion in metals and ionic solids, diffusion-controlled kinetics of phase transformations, and kinetics of gas-solid reactions, among others; Contains end-of chapter exercise problems to help reinforce students' grasp of the concepts presented within each chapter.
Author: John C. Mauro
Publisher: Elsevier
ISBN: 0128242167
Category : Technology & Engineering
Languages : en
Pages : 554
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Book Description
Materials Kinetics: Transport and Rate Phenomena provides readers with a clear understanding of how physical-chemical principles are applied to fundamental kinetic processes. The book integrates advanced concepts with foundational knowledge and cutting-edge computational approaches, demonstrating how diffusion, morphological evolution, viscosity, relaxation and other kinetic phenomena can be applied to practical materials design problems across all classes of materials. The book starts with an overview of thermodynamics, discussing equilibrium, entropy, and irreversible processes. Subsequent chapters focus on analytical and numerical solutions of the diffusion equation, covering Fick's laws, multicomponent diffusion, numerical solutions, atomic models, and diffusion in crystals, polymers, glasses, and polycrystalline materials. Dislocation and interfacial motion, kinetics of phase separation, viscosity, and advanced nucleation theories are examined next, followed by detailed analyses of glass transition and relaxation behavior. The book concludes with a series of chapters covering molecular dynamics, energy landscapes, broken ergodicity, chemical reaction kinetics, thermal and electrical conductivities, Monte Carlo simulation techniques, and master equations. - Covers the full breadth of materials kinetics, including organic and inorganic materials, solids and liquids, theory and experiments, macroscopic and microscopic interpretations, and analytical and computational approaches - Demonstrates how diffusion, viscosity microstructural evolution, relaxation, and other kinetic phenomena can be leveraged in the practical design of new materials - Provides a seamless connection between thermodynamics and kinetics - Includes practical exercises that reinforce key concepts at the end of each chapter
Author: Robert W. Balluffi
Publisher: John Wiley & Sons
ISBN: 0471749303
Category : Science
Languages : en
Pages : 672
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Book Description
A classroom-tested textbook providing a fundamental understandingof basic kinetic processes in materials This textbook, reflecting the hands-on teaching experience of itsthree authors, evolved from Massachusetts Institute of Technology'sfirst-year graduate curriculum in the Department of MaterialsScience and Engineering. It discusses key topics collectivelyrepresenting the basic kinetic processes that cause changes in thesize, shape, composition, and atomistic structure of materials.Readers gain a deeper understanding of these kinetic processes andof the properties and applications of materials. Topics are introduced in a logical order, enabling students todevelop a solid foundation before advancing to more sophisticatedtopics. Kinetics of Materials begins with diffusion, offering adescription of the elementary manner in which atoms and moleculesmove around in solids and liquids. Next, the more complex motion ofdislocations and interfaces is addressed. Finally, still morecomplex kinetic phenomena, such as morphological evolution andphase transformations, are treated. Throughout the textbook, readers are instilled with an appreciationof the subject's analytic foundations and, in many cases, theapproximations commonly used in the field. The authors offer manyextensive derivations of important results to help illuminate theirorigins. While the principal focus is on kinetic phenomena incrystalline materials, select phenomena in noncrystalline materialsare also discussed. In many cases, the principles involved apply toall materials. Exercises with accompanying solutions are provided throughoutKinetics of Materials, enabling readers to put their newfoundknowledge into practice. In addition, bibliographies are offeredwith each chapter, helping readers to investigate specializedtopics in greater detail. Several appendices presenting importantbackground material are also included. With its unique range of topics, progressive structure, andextensive exercises, this classroom-tested textbook provides anenriching learning experience for first-year graduate students.
Author: David Albertovich Frank-Kamenetskii
Publisher: Princeton University Press
ISBN: 1400877199
Category : Science
Languages : en
Pages : 383
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Book Description
Frank-Kamenetskii, a leader in Russian science, was the first to define conditions for two stable operating regimes in chemical reactions, one controlled by chemical reactions, the other by diffusion processes. In this book he treats mathematically the subjects of reaction ignition, quenching, and periodic processes in chemical kinetics as found in flames, combustion of solids, and other chemical reactions. The book was translated from the Russian by the late N. Thou and edited by R. Wilhelm. Originally published in 1955. The Princeton Legacy Library uses the latest print-on-demand technology to again make available previously out-of-print books from the distinguished backlist of Princeton University Press. These editions preserve the original texts of these important books while presenting them in durable paperback and hardcover editions. The goal of the Princeton Legacy Library is to vastly increase access to the rich scholarly heritage found in the thousands of books published by Princeton University Press since its founding in 1905.
Author: Boris S. Bokstein
Publisher: OUP Oxford
ISBN: 0191523682
Category : Technology & Engineering
Languages : en
Pages : 330
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Book Description
This text presents a concise and thorough introduction to the main concepts and practical applications of thermodynamics and kinetics in materials science. It is designed with two types of uses in mind: firstly for a one or two semester university course for mid- to upper-level undergraduate or first year graduate students in a materials-science-oriented discipline and secondly for individuals who want to study the material on their own. The following major topics are discussed: basic laws of classical and irreversible thermodynamics, phase equilibria, theory of solutions, chemical reaction thermodynamics and kinetics, surface phenomena, stressed systems, diffusion and statistical thermodynamics. A large number of example problems with detailed solutions are included as well as accompanying computer-based self-tests, consisting of over 400 questions and 2000 answers with hints for students. Computer-based laboratories are provided, in which a laboratory problem is posed and the experiment described. The student can "perform" the experiments and change the laboratory conditions to obtain the data required for meeting the laboratory objective. Each "laboratory" is augmented with background material to aid analysis of the experimental results.
Author: Dimitri D Vvedensky
Publisher: Morgan & Claypool Publishers
ISBN: 1643276204
Category : Science
Languages : en
Pages : 184
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Book Description
Phase transformations are among the most intriguing and technologically useful phenomena in materials, particularly with regard to controlling microstructure. After a review of thermodynamics, this book has chapters on Brownian motion and the diffusion equation, diffusion in solids based on transition-state theory, spinodal decomposition, nucleation and growth, instabilities in solidification, and diffusionless transformations. Each chapter includes exercises whose solutions are available in a separate manual. This book is based on the notes from a graduate course taught in the Centre for Doctoral Training in the Theory and Simulation of Materials. The course was attended by students with undergraduate degrees in physics, mathematics, chemistry, materials science, and engineering. The notes from this course, and this book, were written to accommodate these diverse backgrounds.
