Chemistry, Manufacture and Applications of Natural Rubber PDF Download
Are you looking for read ebook online? Search for your book and save it on your Kindle device, PC, phones or tablets. Download Chemistry, Manufacture and Applications of Natural Rubber PDF full book. Access full book title Chemistry, Manufacture and Applications of Natural Rubber by Shinzo Kohjiya. Download full books in PDF and EPUB format.
Author: Shinzo Kohjiya
Publisher: Woodhead Publishing
ISBN: 0128188448
Category : Technology & Engineering
Languages : en
Pages : 508
Get Book Here
Book Description
Chemistry, Manufacture and Applications of Natural Rubber, Second Edition presents the latest advances in the processing, properties and advanced applications of natural rubber (NR), drawing on state-of-the-art research in the field. Chapters cover manufacturing, processing and properties of natural rubber, describing biosynthesis, vulcanization for improved performance, strain-induced crystallization, self-reinforcement, rheology and mechanochemistry for processing, computer simulation of properties, scattering techniques and stabilizing agents. Applications covered include natural rubber, carbon allotropes, eco-friendly soft bio-composites using NR matrices and marine products, the use of NR for high functionality such as shape memory, NR for the tire industry, and natural rubber latex with advanced applications. This is an essential resource for academic researchers, scientists and (post)graduate students in rubber science, polymer science, materials science and engineering, and chemistry. In industry, this book enables professionals, R&D, and producers across the natural rubber, tire, rubber and elastomer industries, as well as across industries looking to use natural rubber products, to understand and utilize natural rubber for cutting-edge applications. - Explains the latest manufacture and processing techniques for natural rubber (NR) with enhanced properties - Explores novel applications of natural rubber across a range of industries, including current and potential uses - Discusses resources and utilization, and considers sustainable future development of natural rubber
Author: Shinzo Kohjiya
Publisher: Woodhead Publishing
ISBN: 0128188448
Category : Technology & Engineering
Languages : en
Pages : 508
Get Book Here
Book Description
Chemistry, Manufacture and Applications of Natural Rubber, Second Edition presents the latest advances in the processing, properties and advanced applications of natural rubber (NR), drawing on state-of-the-art research in the field. Chapters cover manufacturing, processing and properties of natural rubber, describing biosynthesis, vulcanization for improved performance, strain-induced crystallization, self-reinforcement, rheology and mechanochemistry for processing, computer simulation of properties, scattering techniques and stabilizing agents. Applications covered include natural rubber, carbon allotropes, eco-friendly soft bio-composites using NR matrices and marine products, the use of NR for high functionality such as shape memory, NR for the tire industry, and natural rubber latex with advanced applications. This is an essential resource for academic researchers, scientists and (post)graduate students in rubber science, polymer science, materials science and engineering, and chemistry. In industry, this book enables professionals, R&D, and producers across the natural rubber, tire, rubber and elastomer industries, as well as across industries looking to use natural rubber products, to understand and utilize natural rubber for cutting-edge applications. - Explains the latest manufacture and processing techniques for natural rubber (NR) with enhanced properties - Explores novel applications of natural rubber across a range of industries, including current and potential uses - Discusses resources and utilization, and considers sustainable future development of natural rubber
Author: Brendan Rodgers
Publisher: CRC Press
ISBN: 1420030469
Category : Technology & Engineering
Languages : en
Pages : 656
Get Book Here
Book Description
Highlighting more than a decade of research, this one-of-a-kind reference reviews the production, processing, and characteristics of a wide range of materials utilized in the modern tire and rubber industry. Rubber Compounding investigates the chemistry and modification of raw materials, elastomers, and material compounds for optimal formulation an
Author: D.C. Blackley
Publisher: Springer Science & Business Media
ISBN: 9400966199
Category : Technology & Engineering
Languages : en
Pages : 381
Get Book Here
Book Description
This book has its origin in a proposal made a few years ago that I should collaborate with Dr H. J. Stern in the production of a third edition of his well-known text-book entitled Rubber: Natural and Synthetic. The sugges tion was that I should contribute a series of chapters on synthetic rubbers. Although, in the event, it has not proved possible to publish the full book in the form originally planned, it was apparent that, with some restructuring, the material which I had collected would be valuable as an independent summary of the chemistry and technology of synthetic rubbers. It is in this form that the material is now offered. The primary purpose of this book is to provide a brief up-to-date survey of the principal types of synthetic rubber which have been and are currently available. Two classes of material are included which are regarded by some as being thermoplastics rather than rubbers, namely, plasticised polyvinyl chloride and the thermoplastic synthetic rubbers. The topics which are covered for each main family of synthetic rubbers are (i) the sources of the monomers, (ii) polymerisation procedures and the effects of important polymerisation variables upon the rubber produced, (iii) the types of rubber currently available commercially, (iv) interesting aspects of the compounding of the rubbers, with special reference to such matters as vulcanisation, reinforcement, protection against degradation, and (where appropriate) plasticisation, and (v) an indication of applications.
Author: James E. Mark
Publisher: Elsevier
ISBN: 0080456014
Category : Science
Languages : en
Pages : 762
Get Book Here
Book Description
The Science and Technology of Rubber, Third Edition provides a broad survey of elastomers with special emphasis on materials with a rubber-like elasticity. As in the 2nd edition, the emphasis remains on a unified treatment of the material; exploring topics from the chemical aspects such as elastomer synthesis and curing, through recent theoretical developments and characterization of equilibrium and dynamic properties, to the final applications of rubber, including tire engineering and manufacturing. Many advances have been made in polymer and elastomers research over the past ten years since the 2nd edition was published. Updated material stresses the continuous relationship between the ongoing research in synthesis, physics, structure and mechanics of rubber technology and industrial applications. Special attention is paid to recent advances in rubber-like elasticity theory and new processing techniques for elastomers. This new edition is comprised of 20% new material, including a new chapter on environmental issues and tire recycling.
Author: Brendan Rodgers
Publisher: CRC Press
ISBN: 1482235501
Category : Technology & Engineering
Languages : en
Pages : 614
Get Book Here
Book Description
Rubber Compounding: Chemistry and Applications describes the production, processing, and characteristics of a wide range of materials utilized in the modern tire and rubber industry, from natural to butyl rubber, carbon black, silica, silanes, and beyond. Containing contributions from leading specialists in the field, the text investigates the chem
Author: P.K. Freakley
Publisher: Springer Science & Business Media
ISBN: 1461323754
Category : Science
Languages : en
Pages : 458
Get Book Here
Book Description
The absence of a book dealing with rubber processing has been apparent for some time and it is surprising that a straightforward text has not been produced. However, this book goes far beyond the scope of a simple technical approach and deals with the full spectrum of activities which lead to successful and profitable product manufacture. The need to deliver a product to a customer at the right time, at the right cost, and at the right quality is a basic premise on which the book is based. The increasingly stringent demands of customers for products that can be introduced directly into an assembly or production line without goods inwards inspection, are placing increasing pressures on the manufacturer. As a result, it is becoming essential to achieve and sustain product quality and consistency, by the monitoring and control of manufacture, at a level which renders all products saleable. The book has been written to satisfy the needs of practitioners in the rubber industry and is certainly not another descriptive text which is only read for interest when more important matters are not pressing. My close cooperation with Philip K. Freakley during the writing of the book has resulted in the incorporation of many of the viewpoints and methods which I have developed and refined during more than 38 years in the rubber industry.
Author: Peter S. Johnson
Publisher: Hanser Gardner Publications
ISBN: 9781569903094
Category : Technology & Engineering
Languages : en
Pages : 145
Get Book Here
Book Description
1 Overview of Rubber Processing p. 1 1.1 Introduction p. 1 1.2 Testing p. 2 1.2.1 Raw Materials Quality Assurance p. 2 1.2.2 Processability Testing of Mixed Compounds p. 2 1.2.3 End Product Testing p. 3 1.3 Conclusion p. 3 References p. 4 2 Raw Materials Acceptance and Specifications p. 5 2.1 Introduction p. 5 2.2 Raw Materials Specifications p. 5 2.2.1 Elastomers p. 6 2.2.2 Fillers p. 7 3 Mixing of Rubber Compounds p. 9 3.1 Introduction p. 9 3.2 Material Flow to the Mixer p. 10 3.2.1 Receipt and Storage of Raw Materials p. 11 3.2.2 Feeding, Weighing, and Charging Raw Materials p. 12 3.2.2.1 Weighing Major Ingredients p. 14 3.2.2.2 Small Component Weighing p. 14 3.3 The Mixing Process p. 15 3.3.1 Incorporation p. 16 3.3.2 Dispersion p. 17 3.3.3 Distribution p. 19 3.3.4 Plasticization p. 20 3.3.5 Natural Rubber Mastication p. 20 3.3.6 Flow Visualization and Modeling of the Mixing Process p. 20 3.3.6.1 Flow Visualization p. 21 3.3.6.2 Modeling p. 21 3.3.7 Flow Behavior on Mills p. 24 3.4 Internal Mixers p. 26 3.4.1 Developments in Internal Mixers p. 29 3.4.1.1 Farrel Mixers p. 29 3.4.1.2 Kobelco Stewart Bolling Mixers p. 30 3.4.1.3 Krupp-Midwest Werner und Pfleiderer Mixers p. 31 3.4.1.4. Pomini Mixers p. 31 3.4.2 Choosing a Mixer p. 32 3.4.3 Inspection and Preventative Maintenance of Mixers p. 32 3.4.4 Internal Mixer Operation p. 33 3.4.4.1 Mixing Procedures p. 33 3.4.4.2 Temperature Control in Internal Mixers p. 37 3.4.4.3 Rotor Speed p. 37 3.4.4.4 Ram Pressure p. 38 3.4.4.5 Batch Size p. 38 3.4.4.6 Dump Criteria p. 40 3.4.5 Control of the Mixing Process p. 41 3.4.6 Scale-Up p. 41 3.5 Take-Off Systems p. 43 3.5.1 Dump Mills p. 43 3.5.2 Packaging p. 44 3.5.3 Single Pass Mixing p. 45 3.6 Other Mixing Equipment p. 45 3.6.1 Mill Mixing p. 45 3.6.2 Continuous Mixing p. 47 3.7 Custom Compounding p. 47 3.8 Troubleshooting the Mixing Process p. 48 3.8.1 Inadequate Dispersion or Distribution p. 49 3.8.2 Scorchy Compound p. 49 3.8.3 Contamination p. 49 3.8.4 Poor Handling on Dump Mill p. 49 3.8.5 Batch-to-Batch Variation p. 49 3.9 Concluding Comments p. 50 References p. 50 4 Flow Behavior of Compounds p. 53 4.1 Introduction p. 53 4.2 Fundamentals of Rheology p. 53 4.3 Effect of Compounding Ingredients on Processing Behavior p. 58 4.3.1 Elastomers p. 58 4.3.2 Fillers p. 59 4.3.2.1 Carbon Blacks p. 59 4.3.3 Plasticizers and Processing Aids p. 60 4.3.3.1 Plasticizers p. 61 4.3.3.2 Processing Aids p. 62 4.3.4 Elasticity p. 63 4.3.5 Conclusion p. 64 References p. 64 5 Testing of Compounds After Mixing p. 65 5.1 Introduction p. 65 5.2 Processability Test Instruments p. 68 5.2.1 The Mooney Viscometer p. 68 5.2.1.1 Delta Mooney p. 69 5.2.1.2 TMS Rheometer p. 70 5.2.2 Capillary Rheometers p. 80 5.2.3 Oscillating Disk Curemeters p. 73 5.2.4 Rotorless Curemeters p. 75 5.2.5 Dynamic Mechanical Rheological Testers p. 75 5.2.6 Stress Relaxation Instruments p. 75 5.2.7 ODR Cure Times Correlation with MDR p. 77 5.3 Comparison of Alpha Technologies Processability Test Instruments p. 78 5.4 Conclusion p. 80 References p. 80 6 The Curing Process p. 83 6.1 Introduction p. 84 6.2 Scorch or Premature Vulcanization p. 84 References p. 85 7 Calendering of Rubber p. 87 7.1 Introduction p. 87 7.2 Equipment p. 87 7.3 Processes p. 88 7.3.1 Feeding p. 88 7.3.2 Sheeting p. 88 7.3.3 Frictioning p. 88 7.3.4 Coating p. 89 7.3.5 Roller Dies p. 89 7.3.6 Downstream Processes p. 90 7.4 Modeling the Calendering Process p. 90 7.5 Troubleshooting Problems in Calendering p. 91 7.5.1 Scorch p. 91 7.5.2 Blistering p. 91 7.5.3 Rough or Holed Sheet p. 91 7.5.4 Tack p. 91 7.5.5 Bloom p. 91 7.6 Conclusions p. 91 References p. 92 8 Extrusion of Rubber p. 93 8.1 Introduction p. 93 8.2 Feeding p. 93 8.2.1 Cold-Feed versus Hot-Feed Extruders p. 94 8.3 Mass Transfer, Conveying, or Pumping p. 96 8.3.1 Flow Mechanism p. 97 8.3.2 Extruder Designs p. 98 8.3.2.1 The Maillefer Screw p. 99 8.3.2.2 The Iddon Screw p. 100 8.3.2.3 The Transfermix p. 101 8.3.2.4 The EVK Screw p. 101 8.3.2.5 The Pin Barrel Extruder p. 101 8.3.2.6 The Cavity Transfer Mixer p. 102 8.3.2.7 Vented Extruders p. 104 8.3.2.8 Dump Extruders p. 104 8.3.2.9 Strainers p. 105 8.3.2.10 Extruder Barrels p. 105 8.4 Extruder Operation and Control p. 105 8.5 Shaping p. 108 8.5.1 Extruder Heads p. 108 8.5.1.1 Coextrusion p. 109 8.5.1.2 Crossheading p. 109 8.5.1.3 Shear Heads p. 109 8.5.2 Dies p. 111 8.5.2.1 Pressure Drop p. 111 8.5.2.2 Die Swell p. 111 8.6 Take-Off and Curing p. 112 8.6.1 Continuous Vulcanization Systems p. 113 8.6.1.1 Pressurized Steam Systems p. 113 8.6.1.2 Hot Air Curing Systems p. 113 8.6.1.3 Hot Air Fluidized Bed Systems p. 114 8.6.1.4 Liquid Salt Bath Systems p. 114 8.6.1.5 Microwave Systems p. 114 8.6.1.6 Shear Head Systems p. 115 8.6.1.7 Electron Beam Systems p. 115 8.6.1.8 Steel Belt Presses p. 116 8.6.1.9 Ultrasonic Vulcanization p. 116 8.7 Troubleshooting the Extrusion Process p. 116 8.7.1 Low Output Rate p. 116 8.7.2 Poor Dimensional Stability of Extrudate p. 117 8.7.3 Excessive Heat Buildup in Compound p. 117 8.7.4 Rough Surface on Extrudate p. 117 8.7.5 Contamination p. 117 8.7.6 Porosity in Extrudate p. 117 8.7.7 Strip Difficult to Feed p. 117 8.7.8 Surging Output p. 118 8.8 Concluding Comments p. 118 References p. 118 9 Molding of Rubber p. 119 9.1 Introduction p. 119 9.2 Compression and Transfer Molding p. 120 9.3 Injection Molding of Rubber p. 122 9.3.1 Injection Molding Equipment p. 125 9.3.1.1 Delivery Systems p. 125 9.3.1.2 Nozzles, Runners, and Gates p. 127 9.3.1.3 Molds p. 128 9.3.1.4 Automatic Ejection p. 129 9.3.1.5 Deflashing p. 129 9.3.2 The Injection Molding Process p. 130 9.3.2.1 Injection Temperature p. 130 9.3.2.2 Screw Speed p. 131 9.3.2.3 Back Pressure p. 131 9.3.2.4 Injection Pressure p. 131 9.3.2.5 Summary p. 131 9.3.3 Monitoring and Modeling the Injection Molding Process p. 131 9.3.4 Control of the Injection Molding Process p. 132 9.3.5 Compounds for Injection Molding p. 133 9.3.6 Problems in Injection Molding of Rubber p. 133 References p. 136 10 Finished Product Testing p. 137 10.1 Introduction p. 137 10.2 Test of Filler Distribution and Dispersion p. 138 10.2.1 Microscopy p. 138 10.2.2 Surface Roughness p. 138 10.3 Tests on Cured Specimens p. 138 10.3.1 Tensile Tests p. 139 10.3.2 Hardness p. 139 10.3.3 Compression Set p. 139 10.3.4 Solvent Resistance p. 140 10.3.5 Aging p. 140 10.3.6 Ozone Cracking p. 140 References p. 140 Index p. 143.
Author: Jin Kuk Kim
Publisher: Royal Society of Chemistry
ISBN: 1788015444
Category : Science
Languages : en
Pages : 354
Get Book Here
Book Description
Rubber is used in a vast number of products, from tyres on vehicles to disposable surgical gloves. Increasingly both manufacturers and legislators are realising that recycling is essential for environmental sustainability and can improve the cost of manufacture. The volume of rubber waste produced globally makes it difficult to manage as accumulated waste rubber, especially in the form of tyres, can pose a significant fire risk. Recycling rubber not only prevents this problem but can produce new materials with desirable properties that virgin rubbers lack. This book presents an up-to-date overview of the fundamental and applied aspects of renewability and recyclability of rubber materials, emphasising existing recycling technologies with significant potential for future applications along with a detailed outline of new technology based processing of rubber to reuse and recycle. This book will be of interest to researchers in both academia and industry as well as postgraduate students working in polymer chemistry, materials processing, materials science and engineering.
Author: Saikat Das Gupta
Publisher: CRC Press
ISBN: 0849373166
Category : Technology & Engineering
Languages : en
Pages : 360
Get Book Here
Book Description
Reverse engineering is widely practiced in the rubber industry. Companies routinely analyze competitors’ products to gather information about specifications or compositions. In a competitive market, introducing new products with better features and at a faster pace is critical for any manufacturer. Reverse Engineering of Rubber Products: Concepts, Tools, and Techniques explains the principles and science behind rubber formulation development by reverse engineering methods. The book describes the tools and analytical techniques used to discover which materials and processes were used to produce a particular vulcanized rubber compound from a combination of raw rubber, chemicals, and pigments. A Compendium of Chemical, Analytical, and Physical Test Methods Organized into five chapters, the book first reviews the construction of compounding ingredients and formulations, from elastomers, fillers, and protective agents to vulcanizing chemicals and processing aids. It then discusses chemical and analytical methods, including infrared spectroscopy, thermal analysis, chromatography, and microscopy. It also examines physical test methods for visco-elastic behavior, heat aging, hardness, and other features. A chapter presents important reverse engineering concepts. In addition, the book includes a wide variety of case studies of formula reconstruction, covering large products such as tires and belts as well as smaller products like seals and hoses. Get Practical Insights on Reverse Engineering from the Book’s Case Studies Combining scientific principles and practical advice, this book brings together helpful insights on reverse engineering in the rubber industry. It is an invaluable reference for scientists, engineers, and researchers who want to produce comparative benchmark information, discover formulations used throughout the industry, improve product performance, and shorten the product development cycle.
Author: M. Morton
Publisher: Springer Science & Business Media
ISBN: 9401729255
Category : Science
Languages : en
Pages : 643
Get Book Here
Book Description
About ten years after the publication of the Second Edition (1973), it became apparent that it was time for an up-date of this book. This was especially true in this case, since the subject matter has traditionally dealt mainly with the structure, properties, and technology of the various elastomers used in industry, and these are bound to undergo significant changes over the period of a decade. In revising the contents of this volume, it was thought best to keep the orig inal format. Hence the first five chapters discuss the same general subject matter as before. The chapters dealing with natural rubber and the synthetic elastomers are up-dated, and an entirely new chapter has been added on the thermoplastic elastomers, which have, of course, grown tremendously in importance. Another innovation is the addition of a new chapter, "Miscellaneous Elastomers," to take care of "old" elastomers, e.g., polysulfides, which have decreased some what in importance, as well as to introduce some of the newly-developed syn thetic rubbers which have not yet reached high production levels. The editor wishes to express his sincere appreciation to all the contributors, without whose close cooperation this task would have been impossible. He would especially like to acknowledge the invaluable assistance of Dr. Howard Stephens in the planning of this book, and for his suggestion of suitable authors.
