Synthesis, Characterization, and Theory of Polymeric Networks and Gels

Synthesis, Characterization, and Theory of Polymeric Networks and Gels PDF Author: Shaul M. Aharoni
Publisher: Springer Science & Business Media
ISBN: 1461530164
Category : Science
Languages : en
Pages : 354

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Book Description
Polymer science is a technology-driven science. More often than not, technological breakthroughs opened the gates to rapid fundamental and theoretical advances, dramatically broadening the understanding of experimental observations, and expanding the science itself. Some of the breakthroughs involved the creation of new materials. Among these one may enumerate the vulcanization of natural rubber, the derivatization of cellulose, the giant advances right before and during World War II in the preparation and characterization of synthetic elastomers and semi crystalline polymers such as polyesters and polyamides, the subsequent creation of aromatic high-temperature resistant amorphous and semi-crystal line polymers, and the more recent development of liquid-crystalline polymers mostly with n~in-chain mesogenicity. other breakthroughs involve the development of powerful characterization techniques. Among the recent ones, the photon correlation spectroscopy owes its success to the advent of laser technology, small angle neutron scattering evolved from n~clear reactors technology, and modern solid-state nuclear magnetic resonance spectroscopy exists because of advances in superconductivity. The growing need for high modulus, high-temperature resistant polymers is opening at present a new technology, that of more or less rigid networks. The use of such networks is rapidly growing in applications where they are used as such or where they serve as matrices for fibers or other load bearing elements. The rigid networks are largely aromatic. Many of them are prepared from multifunctional wholly or almost-wholly aromatic kernels, while others contain large amount of stiff difunctional residus leading to the presence of many main-chain "liquid-crystalline" segments in the "infinite" network.

Synthesis, Characterization, and Theory of Polymeric Networks and Gels

Synthesis, Characterization, and Theory of Polymeric Networks and Gels PDF Author: Shaul M. Aharoni
Publisher: Springer Science & Business Media
ISBN: 1461530164
Category : Science
Languages : en
Pages : 354

Get Book Here

Book Description
Polymer science is a technology-driven science. More often than not, technological breakthroughs opened the gates to rapid fundamental and theoretical advances, dramatically broadening the understanding of experimental observations, and expanding the science itself. Some of the breakthroughs involved the creation of new materials. Among these one may enumerate the vulcanization of natural rubber, the derivatization of cellulose, the giant advances right before and during World War II in the preparation and characterization of synthetic elastomers and semi crystalline polymers such as polyesters and polyamides, the subsequent creation of aromatic high-temperature resistant amorphous and semi-crystal line polymers, and the more recent development of liquid-crystalline polymers mostly with n~in-chain mesogenicity. other breakthroughs involve the development of powerful characterization techniques. Among the recent ones, the photon correlation spectroscopy owes its success to the advent of laser technology, small angle neutron scattering evolved from n~clear reactors technology, and modern solid-state nuclear magnetic resonance spectroscopy exists because of advances in superconductivity. The growing need for high modulus, high-temperature resistant polymers is opening at present a new technology, that of more or less rigid networks. The use of such networks is rapidly growing in applications where they are used as such or where they serve as matrices for fibers or other load bearing elements. The rigid networks are largely aromatic. Many of them are prepared from multifunctional wholly or almost-wholly aromatic kernels, while others contain large amount of stiff difunctional residus leading to the presence of many main-chain "liquid-crystalline" segments in the "infinite" network.

Polymer Gels

Polymer Gels PDF Author: Vijay Kumar Thakur
Publisher: Springer
ISBN: 9811060835
Category : Technology & Engineering
Languages : en
Pages : 412

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Book Description
This book addresses a range of synthesis and characterization techniques that are critical for tailoring and broadening the various aspects of polymer gels, as well as the numerous advantages that polymer gel-based materials offer. It presents a comprehensive collection of chapters on the recent advances and developments in the science and fundamentals of both synthetic and natural polymer-based gels. Topics covered include: synthesis and structure of physically/chemically cross-linked polymer-gels/polymeric nanogels; gel formation through non-covalent cross-linking; molecular design and characterization; polysaccharide-based polymer gels: synthesis, characterization, and properties; modified polysaccharide gels: silica-based polymeric gels as platforms for the delivery of pharmaceuticals; gel-based approaches in genomic and proteomic sciences; emulgels in drug delivery; and organogels. The book provides a cutting-edge resource for researchers and scientists working in various fields involving polymers, biomaterials, bio-nanotechnology and functional materials.

Handbook of Polymer Synthesis, Characterization, and Processing

Handbook of Polymer Synthesis, Characterization, and Processing PDF Author: Enrique Saldivar-Guerra
Publisher: John Wiley & Sons
ISBN: 1118480775
Category : Technology & Engineering
Languages : en
Pages : 660

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Book Description
Covering a broad range of polymer science topics, Handbook of Polymer Synthesis, Characterization, and Processing provides polymer industry professionals and researchers in polymer science and technology with a single, comprehensive handbook summarizing all aspects involved in the polymer production chain. The handbook focuses on industrially important polymers, analytical techniques, and formulation methods, with chapters covering step-growth, radical, and co-polymerization, crosslinking and grafting, reaction engineering, advanced technology applications, including conjugated, dendritic, and nanomaterial polymers and emulsions, and characterization methods, including spectroscopy, light scattering, and microscopy.

Heterophase Network Polymers

Heterophase Network Polymers PDF Author: Boris A Rozenberg
Publisher: CRC Press
ISBN: 1134453841
Category : Technology & Engineering
Languages : en
Pages : 252

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Book Description
This volume explains the theory and experimental investigations in the preparation of heterophase polymer network materials through cure reaction-induced microphase separation (CRIMPS). It describes the synthesis of a new family of block- and graft-copolymers with controlled solubility in epoxies and characterizes CRIMPS processes using novel applications of known methods such as nuclear magnetic resonance, electron spin resonance and photochemistry. The text develops a new method for characterizing the molecular mass distribution (MMD) of linear and network polymers using thermomechanical analysis data, as well as new methods for determining internal stresses and flaw formation during thermoset curing. The CRIMPS theory will be helpful for researchers and engineers designing and improving toughened plastics and other smart heterophase network materials for different applications. The new method for MMD characterization of polymers in bulk will be very useful to quickly analyze a polymer's MMD and to design new polymers. This book will provide a useful reference for graduates, researchers and working professionals in polymer chemistry and physics and materials science.

Gels Handbook, Four-Volume Set

Gels Handbook, Four-Volume Set PDF Author: Kanji Kajiwara
Publisher: Elsevier
ISBN: 0080532349
Category : Science
Languages : en
Pages : 1588

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Book Description
This major reference work, covering the important materials science area of gels, is a translation of a Japanese handbook. The three-volume set is organized to cover the following: fundamentals, functions, and environmental issues. Gels Handbook also contains an appendix, complete references, and data on gel compounds.Recently, polymer gels have attracted many scientific researchers, medical doctors, and pharmaceutical, chemical, and agricultural engineers to the rapidly growing field. Gels are considered to be one of the most promising materials in the 21st Century. They are unique in that they are soft, gentle, and can sense and accommodate environmental changes. Because of these unique characteristics gels have a huge potential in technological and medical applications. They are irreplaceable in the separation of molecules, the release of drugs, artificial skins and organs, sensors, actuators, chemical memories, and many other applications.The 21st century is also said to be the century of biotechnology, where two kinds of biopolymers play crucial roles: DNA as a bearer of geneticinformation and proteins as molecular machines. In spite of the dramatic progress in molecular biology and the Human Genome project, the basic principles behind the function and design of such polymeric machines are in the black box. Science and technologies that will emerge from those of polymer gels will shed light on such principles.Some researchers have already developed prototypes of artificial glands (pancreas), artificial muscles and actuators, and chemical sensors and molecular recovery systems using polymer gels.The Gels Handbook is an invaluable source of information on this rapidly growing field. It covers the entire area from the scientific basics to the applications of the materials. The authors are among the leading researchers, doctors, engineers, and patent officers in Japan. This book can be used as a textbook or an encyclopedia and is a must for those involved in gel research or applications. Key Features* Comprehensive coverage of a popular topic in materials science* Is the first english-language gels handbook* Includes numerous figures, tables, and photos

Amphiphilic Polymer Co-networks

Amphiphilic Polymer Co-networks PDF Author: Costas S Patrickios
Publisher: Royal Society of Chemistry
ISBN: 1839161345
Category : Science
Languages : en
Pages : 347

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Book Description
Amphiphilic polymer co-networks (APCNs) are a type of polymeric hydrogel, their hydrophobic polymer segments and hydrophilic components produce less aqueous swelling, giving better mechanical properties than conventional hydrogels. This new class of polymers is attracting increasing attention, resulting in further basic research on the system, as well as new applications. This book focuses on new developments in the field of APCNs, and is organised in four sections: synthesis, properties, applications and modelling. Co-network architectures included in the book chapters are mainly those deriving from hydrophobic macro-cross-linkers, representing the classical approach; however, more modern designs are also presented. Properties of interest discussed include aqueous swelling, thermophysical and mechanical properties, self-assembly, electrical actuation, and protein adsorption. Applications described in the book chapters include the use of co-networks as soft contact lenses, scaffolds for drug delivery and tissue engineering, matrices for heterogeneous biocatalysis, and membranes of controllable permeability. Finally, an important theory chapter on the modelling of the self-assembly of APCNs is also included. The book is suitable for graduate students and researchers interested in hydrogels, polymer networks, polymer chemistry, block copolymers, self-assembly and nanomaterials, as well as their applications in contact lenses, drug delivery, tissue engineering, membranes and biocatalysis.

Hypercrosslinked Polymeric Networks and Adsorbing Materials

Hypercrosslinked Polymeric Networks and Adsorbing Materials PDF Author: Vadim Davankov
Publisher: Elsevier
ISBN: 0444537015
Category : Technology & Engineering
Languages : en
Pages : 673

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Book Description
Hypercrosslinked network polymers present a new class of polymeric materials with very wide application possibilities, including adsorption technology, ion exchange, HPLC, analytical chemistry, nanotechnology (nanocomposites), medical polymers - First book describing the theory, practice of preparation and use of polymeric adsorbing materials with the emphasis on new hypercrosslinked polystyrene-type polymers - Written by the originators of the concept of hypercrosslinked polymers - Complex phenomena are explained by appealing to common sense, analogies and well-known effects, rather than complex mathematical treatment and computer modelling - Reviews many Russian, German and even Czech language publications - Contains numerous experimental data in the form of Figures and Tables

Polymer Gels

Polymer Gels PDF Author: Vijay Kumar Thakur
Publisher: Springer
ISBN: 9811060800
Category : Technology & Engineering
Languages : en
Pages : 419

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Book Description
This book summarizes the recent advances in the science and engineering of polymer-gel-based materials in different fields. It also discusses the extensive research developments for the next generation of smart materials. It takes an in-depth look at the current perspectives and market opportunities while pointing to new possibilities and applications. The book addresses important topics such as stimuli responsive polymeric nanoparticles for cancer therapy; polymer gel containing metallic materials; chemotherapeutic applications in oncology; conducting polymer-based gels and their applications in biological sensors; imprinted polymeric gels for pharmaceutical and biomedical purposes; applications of biopolymeric gels in the agricultural sector; application of polymer gels and their nanocomposites in electrochemistry; smart polyelectrolyte gels as a platform for biomedical applications; agro-based polymer gels and their application in purification of industrial water wastes; polymer gel composites for bio-applications. It will be of interest to researchers working in both industry and academia.

Polymers and Other Advanced Materials

Polymers and Other Advanced Materials PDF Author: Ting Joo Fai
Publisher: Springer Science & Business Media
ISBN: 1489905022
Category : Science
Languages : en
Pages : 770

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Book Description
Proceedings of the Third International Conference on Frontiers of Polymers and Advanced Materials held in Kuala Lumpur, Malaysia, January 16-20, 1995

Handbook of Benzoxazine Resins

Handbook of Benzoxazine Resins PDF Author: Hatsuo Ishida
Publisher: Elsevier
ISBN: 0444537910
Category : Technology & Engineering
Languages : en
Pages : 709

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Book Description
This handbook provides a wide overview of the field, fundamental understanding of the synthetic methods and structure/property correlation, as well as studies related to applications in a wide range of subjects. The handbook also provides 1H and 13C NMR spectra, FTIR spectra, DSC and TGA thermograms to aid in research activities. Additional tables on key NMR and FTIR frequencies unique to benzoxazine, heat of polymerization, Tg, and char yield will greatly aid in the choice of proper benzoxazine for a specific application. - Provides thorough coverage of the chemistry and applications of benzoxazine resins with an evidence-based approach to enable chemists, engineers and material scientists to evaluate effectiveness - Features spectra, which allow researchers to compare results, avoid repetition and save time as well as tables on key NMR frequency, IR frequency, heat of polymerization, of many benzoxazine resins to aid them in selection of materials - Written by the foremost experts in the field