Synthesis and Characterization of Some Nanostructured Materials for Visible Light-driven Photo Processes

Synthesis and Characterization of Some Nanostructured Materials for Visible Light-driven Photo Processes PDF Author: Rania Elhadi Adam
Publisher: Linköping University Electronic Press
ISBN: 9179298788
Category :
Languages : en
Pages : 107

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Book Description
Nanostructured materials for visible light driven photo-processes such as photodegradation of organic pollutants and photoelectrochemical (PEC) water oxidation for hydrogen production are very attractive because of the positive impact on the environment. Metal oxides-based nanostructures are widely used in these photoprocesses due to their unique properties. But single nanostructured metal oxide material might suffer from low efficiency and instability in aqueous solutions under visible light. These facts make it important to have an efficient and reliable nanocomposite for the photo-processes. The combination of different nanomaterials to form a composite configuration can produce a material with new properties. The new properties which are due to the synergetic effect, are a combination of the properties of all the counterparts of the nanocomposite. Zinc oxides (ZnO) have unique optical and electrical properties which grant it to be used in optoelectronics, sensors, solar cells, nanogenerators, and photocatalysis activities. Although ZnO absorbs visible light from the sun due to the deep level band, it mainly absorbs ultraviolet wavelengths which constitute a small portion of the whole solar spectrum range. Also, ZnO has a problem with the high recombination rate of the photogenerated electrons. These problems might reduce its applicability to the photo-process. Therefore, our aim is to develop and investigate different nanocomposites materials based on the ZnO nanostructures for the enhancement of photocatalysis processes using the visible solar light as a green source of energy. Two photo-processes were applied to examine the developed nanocomposites through photocatalysis: (1) the photodegradation of organic dyes, (2) PEC water splitting. In the first photo-process, we used the ZnO nanoparticles (NPs), Magnesium (Mg)-doped ZnO NPs, and plasmonic ZnO/graphene-based nanocomposite for the decomposition of some organic dyes that have been used in industries. For the second photo-process, ZnO photoelectrode composite with different silver-based semiconductors to enhance the performance of the ZnO photoelectrode was used for PEC reaction analysis to perform water splitting. The characterization and photocatalysis experiment results showed remarkable enhancement in the photocatalysis efficiency of the synthesized nanocomposites. The observed improved properties of the ZnO are due to the synergetic effects are caused by the addition of the other nanomaterials. Hence, the present thesis attends to the synthesis and characterization of some nanostructured materials composite with ZnO that are promising candidates for visible light-driven photo-processes.

Synthesis and Characterization of Some Nanostructured Materials for Visible Light-driven Photo Processes

Synthesis and Characterization of Some Nanostructured Materials for Visible Light-driven Photo Processes PDF Author: Rania Elhadi Adam
Publisher: Linköping University Electronic Press
ISBN: 9179298788
Category :
Languages : en
Pages : 107

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Book Description
Nanostructured materials for visible light driven photo-processes such as photodegradation of organic pollutants and photoelectrochemical (PEC) water oxidation for hydrogen production are very attractive because of the positive impact on the environment. Metal oxides-based nanostructures are widely used in these photoprocesses due to their unique properties. But single nanostructured metal oxide material might suffer from low efficiency and instability in aqueous solutions under visible light. These facts make it important to have an efficient and reliable nanocomposite for the photo-processes. The combination of different nanomaterials to form a composite configuration can produce a material with new properties. The new properties which are due to the synergetic effect, are a combination of the properties of all the counterparts of the nanocomposite. Zinc oxides (ZnO) have unique optical and electrical properties which grant it to be used in optoelectronics, sensors, solar cells, nanogenerators, and photocatalysis activities. Although ZnO absorbs visible light from the sun due to the deep level band, it mainly absorbs ultraviolet wavelengths which constitute a small portion of the whole solar spectrum range. Also, ZnO has a problem with the high recombination rate of the photogenerated electrons. These problems might reduce its applicability to the photo-process. Therefore, our aim is to develop and investigate different nanocomposites materials based on the ZnO nanostructures for the enhancement of photocatalysis processes using the visible solar light as a green source of energy. Two photo-processes were applied to examine the developed nanocomposites through photocatalysis: (1) the photodegradation of organic dyes, (2) PEC water splitting. In the first photo-process, we used the ZnO nanoparticles (NPs), Magnesium (Mg)-doped ZnO NPs, and plasmonic ZnO/graphene-based nanocomposite for the decomposition of some organic dyes that have been used in industries. For the second photo-process, ZnO photoelectrode composite with different silver-based semiconductors to enhance the performance of the ZnO photoelectrode was used for PEC reaction analysis to perform water splitting. The characterization and photocatalysis experiment results showed remarkable enhancement in the photocatalysis efficiency of the synthesized nanocomposites. The observed improved properties of the ZnO are due to the synergetic effects are caused by the addition of the other nanomaterials. Hence, the present thesis attends to the synthesis and characterization of some nanostructured materials composite with ZnO that are promising candidates for visible light-driven photo-processes.

Photocatalytic Semiconductors

Photocatalytic Semiconductors PDF Author: Aracely Hernández-Ramírez
Publisher: Springer
ISBN: 3319109995
Category : Science
Languages : en
Pages : 298

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Book Description
This critical volume examines the different methods used for the synthesis of a great number of photocatalysts, including TiO2, ZnO and other modified semiconductors, as well as characterization techniques used for determining the optical, structural and morphological properties of the semiconducting materials. Additionally, the authors discuss photoelectrochemical methods for determining the light activity of the photocatalytic semiconductors by means of measurement of properties such as band gap energy, flat band potential and kinetics of hole and electron transfer. Photocatalytic Semiconductors: Synthesis, Characterization and Environmental Applications provide an overview of the semiconductor materials from first- to third-generation photocatalysts and their applications in wastewater treatment and water disinfection. The book further presents economic and toxicological aspects in the production and application of photocatalytic materials.

Chalcogenide-Based Nanomaterials as Photocatalysts

Chalcogenide-Based Nanomaterials as Photocatalysts PDF Author: Mohammad Mansoob Khan
Publisher: Elsevier
ISBN: 0128209178
Category : Technology & Engineering
Languages : en
Pages : 378

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Book Description
Chalcogenide-Based Nanomaterials as Photocatalysts deals with the different types of chalcogenide-based photocatalytic reactions, covering the fundamental concepts of photocatalytic reactions involving chalcogenides for a range of energy and environmental applications. Sections focus on nanostructure control, synthesis methods, activity enhancement strategies, environmental applications, and perspectives of chalcogenide-based nanomaterials. The book offers guidelines for designing new chalcogenide-based nanoscale photocatalysts at low cost and high efficiency for efficient utilization of solar energy in the areas of energy production and environment remediation. - Provides information on the development of novel chalcogenide-based nanomaterials - Outlines the fundamentals of chalcogenides-based photocatalysis - Includes techniques for heterogeneous catalysis based on chalcogenide-based nanomaterials

RECENT TRENDS IN CHEMICAL SCIENCES AND ENVIRONMENTAL SCIENCE

RECENT TRENDS IN CHEMICAL SCIENCES AND ENVIRONMENTAL SCIENCE PDF Author: Dr. Azad Kumar
Publisher: THANUJ INTERNATIONAL PUBLISHERS
ISBN: 8195252990
Category : Antiques & Collectibles
Languages : en
Pages : 150

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Book Description
Our intention in publishing this book was to discuss and interpret all of the major issues in the chemical and environmental science disciplines, because this book covers such a broad range of chemical and environmental science research area. Rather, we have selected the themes and challenges, briefly defined them and demonstrated how they connect, clarified the terminology, and indicated where further research may be accessed. We hope that the result is an excellent introduction to 'chemical and environmental science. It is primarily aimed towards researchers in chemical science and related fields, but it should be accessible to new researchers as well. We have explored into more depth on issues that have received little attention elsewhere. There are several useful sources for topics such as chemical science, environmental science, nanotechnology, ionic liquids, solid waste management, photodegradation, Nanomaterial, adsorption of hazardous metals, and conducting polymers. However we attempted to provide up-to-current knowledge, we are well aware that books may soon go out of date if they seek to provide too much detail, so we concentrated on basic concepts that should not go out of fashion too quickly. Our book differs somewhat from other texts in the chemical and environmental sciences in its concentration. We have focused on ideas and theories because we feel that a solid grasp of them will be more useful in the long run than specifics of present systems, services, and approaches. We've also highlighted the dimension since we feel it's critical to understand where the discipline and its components originated from and why some things are the way they are. This approach is based on the research, with several references provided at the end of each chapter for convenience. Our intention is that the content of this book will be sufficient to provide a fundamental knowledge of the entire field, and that readers will refer to the references for more information and examples of the parts of which they are most interested. The conclusion words and captions, as well as the important references, at the conclusion of each chapter are intended to present the main points in a factual way.

Advanced Oxidation Processes for Wastewater Treatment

Advanced Oxidation Processes for Wastewater Treatment PDF Author: Maulin P Shah
Publisher: CRC Press
ISBN: 1000546632
Category : Science
Languages : en
Pages : 298

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Book Description
Advanced Oxidation Processes for Wastewater Treatment: An Innovative Approach: This book highlights the importance of various innovative advanced oxidation technology to clean up the environment from pollution caused by human activities. It assesses the potential application of several existing bioremediation techniques and introduces new emerging technologies. This book is an updated vision of the existing advanced oxidation strategies with their limitations and challenges and their potential application to remove environmental pollutants. It also introduces the new trends and advances in environmental bioremediation technology with thorough discussion of recent developments in this field. This book highlights the importance of different innovative advanced oxidation process to deal with the ever-increasing number of environmental pollutants. Features: Illustrates the importance of various advance oxidation processes in effluent treatment plant Points out the reuse of the treated wastewater through emerging advance oxidation technologies for effluent treatment plant Highlights the recovery of resources from wastewater Pays attention to the occurrence of novel micro-pollutants Emphasizes the role of nanotechnology in bioremediation of pollutants Introduces new trends in environmental bioremediation

Heterogeneous Photocatalysis

Heterogeneous Photocatalysis PDF Author: M. Schiavello
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 218

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Book Description
Photocatalysis is a reaction which is accelerated by light while a heterogeneous reaction consists of two phases ( a solid and a liquid for example). Heterogeneous Photocatalysis is a fast developing science which to date has not been fully detailed in a monograph. This title discusses the basic principles of heterogeneous photocatalysis and describes the bulk and surface properties of semiconductors. Applications of various types of photoreactions are described and the problems related to the modeling and design of photoreactors are covered.

Nanostructured Materials for Visible Light Photocatalysis

Nanostructured Materials for Visible Light Photocatalysis PDF Author: Arpan Kumar Nayak
Publisher: Elsevier
ISBN: 0128230509
Category : Technology & Engineering
Languages : en
Pages : 638

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Book Description
Nanostructured Materials for Visible Light Photocatalysis describes the various methods of synthesizing different classes of nanostructured materials that are used as photocatalysts for the degradation of organic hazardous dyes under visible light irradiation. The first three chapters include a general introduction, basic principles, mechanisms, and synthesis methods of nanomaterials for visible light photocatalysis. Recent advances in carbon, bismuth series, transition metal oxide and chalcogenides-based nanostructured materials for visible light photocatalysis are discussed. Later chapters describe the role of phosphides, nitrides, and rare earth-based nanostructured-based materials in visible light photocatalysis, as well as the characteristics, synthesis, and fabrication of photocatalysts. The role of doping, composites, defects, different facets, morphology of nanostructured materials and green technology for efficient dye removal under visible-light irradiation are also explored. Other topics covered include large-scale production of nanostructured materials, the challenges in present photocatalytic research, the future scope of nanostructured materials regarding environmental hazard remediation under visible light, and solar light harvesting. This book is a valuable reference to researchers and enables them to learn more about designing advanced nanostructured materials for wastewater treatment and visible-light irradiation. - Covers all the recent developments of nanostructured photocatalytic materials - Provides a clear overview of the mechanism of visible light photocatalysis and the controlled synthesis of nanostructured materials - Assesses the major challenges of creating visible light photocatalysis systems at the nanoscale

Diversity and Applications of New Age Nanoparticles

Diversity and Applications of New Age Nanoparticles PDF Author: Bansal, Suneev Anil
Publisher: IGI Global
ISBN: 1668473607
Category : Technology & Engineering
Languages : en
Pages : 439

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Book Description
Nanoparticles are revolutionizing and helping to improve every sector including engineering, medicine, food safety, transportation, energy, and environmental science. To ensure industries take full advantage of the opportunities nanoparticles provide, further study on the advancements and challenges within the field is required. Diversity and Applications of New Age Nanoparticles considers new developments and applications of nanoparticles and addresses the development of new materials, synthesis routes, and emerging research in this field. Covering key topics such as antibiotics, thin films, battery technologies, and composites, this premier reference source is ideal for industry professionals, computer scientists, policymakers, engineers, pharmacists, medical professionals, researchers, scholars, practitioners, instructors, and students.

Synthesis, Characterization and Applications of Nanomaterials in the Field of Photocatalysis

Synthesis, Characterization and Applications of Nanomaterials in the Field of Photocatalysis PDF Author: Shamaila Sajjad
Publisher: GRIN Verlag
ISBN: 3640986342
Category : Science
Languages : en
Pages : 177

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Book Description
Doctoral Thesis / Dissertation from the year 2011 in the subject Chemistry - Materials Chemistry, East China University of Science and Technology (-), language: English, abstract: Considerable effort has been made to design, fabricate, and manipulate nanostructured materials by innovative approaches. The precise control of nanoscale structures will pave the way not only for elucidating unique size/shape dependent physicochemical properties but also for realizing new applications in science and technology. Nanotechnology offers unprecedented opportunities for improving our daily lives and the environment in which we live. This thesis mainly describes recent progress in the design, fabrication, and modification of nanostructured semiconductor materials for environmental applications. The scope of this thesis covers TiO2, Bi2O3 and BiOCl materials, focusing particularly on TiO2-based nanostructures (e.g., pure, doped, coupled, mesoporous, hierarchically porous, and ordered mesoporous TiO2). Mesoporous titania is of particular interest since this class of materials possesses well-defined porosity and large specific surface areas. For photocatalytic degradation of organics, these desirable properties are anticipated to improve the efficiency. So in the first part of work, I have synthesized the mesoporous titania by using poly ethylene glycol as a template in dilute acetic acid aqueous solution by hydrothermal process and investigated the effect of PEG molecular weights and thermal treatment on the resultant structure and photocatalytic activity. When the molecular weights of PEG vary from 600 to 20,000, the particle sizes of mesoporous-TiO2 structure decrease from 15.1 to 13.3 nm and mean pore sizes increase from 6.9-10.6 nm. The activities of these mesoporous-TiO2 photocatalysts prepared by using PEG are evaluated and compared with Degussa P-25 using chloro-phenol as a testing compound. [...]

Encyclopedia of Renewable Energy, Sustainability and the Environment

Encyclopedia of Renewable Energy, Sustainability and the Environment PDF Author:
Publisher: Elsevier
ISBN: 0323939414
Category : Science
Languages : en
Pages : 4061

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Book Description
Encyclopedia of Renewable Energy, Sustainability and the Environment, Four Volume Set comprehensively covers all renewable energy resources, including wind, solar, hydro, biomass, geothermal energy, and nuclear power, to name a few. In addition to covering the breadth of renewable energy resources at a fundamental level, this encyclopedia delves into the utilization and ideal applications of each resource and assesses them from environmental, economic, and policy standpoints. This book will serve as an ideal introduction to any renewable energy source for students, while also allowing them to learn about a topic in more depth and explore related topics, all in a single resource.Instructors, researchers, and industry professionals will also benefit from this comprehensive reference. - Covers all renewable energy technologies in one comprehensive resource - Details renewable energies' processes, from production to utilization in a single encyclopedia - Organizes topics into concise, consistently formatted chapters, perfect for readers who are new to the field - Assesses economic challenges faced to implement each type of renewable energy - Addresses the challenges of replacing fossil fuels with renewables and covers the environmental impacts of each renewable energy