Studies and Modelling of High Temperature Diffusion Processes in Selected High Performance Structural Coating Systems PDF Download
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Author: Haifa G. Ahmad
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Book Description
The central theme of the work undertaken in this thesis involved modelling of diffusion? numerical and microstructural? occurring during high temperature exposure of selected materials and coatings. The materials and coatings and their high temperature treatments included carburization of steel (nonsteady-state diffusion of iron carburized at 950o C after 7.1 hours), a two component Cu-Ni diffusion couple subjected to diffusion anneal at 1054oC for 300 hours, a three component Pt-Ni-Al solid alloy subjected to oxidation and diffusion anneal, Multicomponent Ni -aluminide and Pt-aluminide coatings on MAR M002 subjected to 150 hours of diffusion treatment at temperature 1273K, a Jr and Jr/Pt Low-activity aluminide / MAR M002 system at 1100oC after 100 hours, aluminise coating on low alloy steels at 650oC, Jnnovatial coatings- Ti45Al8Nb coated with Al2Au subjected to air oxidation at 750oC for 1000 hours, and Ti45Al8Nb coated with TiAlCrY subjected to air oxidation at 750oC for 500 hours. Such coatings are being increasingly used to protect materials against high temperature (600-1000oC) degradation by oxidation. The demands for using such coatings have arisen because of the need to increase the efficiency by increasing the operation temperature in many areas of technological applications such as power operation, aero engines, and energy conversion systems and in processing industries. However the one of the major obstacles to use these coatings to prevent high temperature oxidation of materials is the degradation of the coatings due to the coating/substrate interdiffusion. Jnterdiffusion of critical elements from the coating to the substrate will deplete the protective scale forming elements in the coating.
Author: Haifa G. Ahmad
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Book Description
The central theme of the work undertaken in this thesis involved modelling of diffusion? numerical and microstructural? occurring during high temperature exposure of selected materials and coatings. The materials and coatings and their high temperature treatments included carburization of steel (nonsteady-state diffusion of iron carburized at 950o C after 7.1 hours), a two component Cu-Ni diffusion couple subjected to diffusion anneal at 1054oC for 300 hours, a three component Pt-Ni-Al solid alloy subjected to oxidation and diffusion anneal, Multicomponent Ni -aluminide and Pt-aluminide coatings on MAR M002 subjected to 150 hours of diffusion treatment at temperature 1273K, a Jr and Jr/Pt Low-activity aluminide / MAR M002 system at 1100oC after 100 hours, aluminise coating on low alloy steels at 650oC, Jnnovatial coatings- Ti45Al8Nb coated with Al2Au subjected to air oxidation at 750oC for 1000 hours, and Ti45Al8Nb coated with TiAlCrY subjected to air oxidation at 750oC for 500 hours. Such coatings are being increasingly used to protect materials against high temperature (600-1000oC) degradation by oxidation. The demands for using such coatings have arisen because of the need to increase the efficiency by increasing the operation temperature in many areas of technological applications such as power operation, aero engines, and energy conversion systems and in processing industries. However the one of the major obstacles to use these coatings to prevent high temperature oxidation of materials is the degradation of the coatings due to the coating/substrate interdiffusion. Jnterdiffusion of critical elements from the coating to the substrate will deplete the protective scale forming elements in the coating.
Author: Committee on Coatings for High-Temperature Structural Materials
Publisher: National Academies Press
ISBN: 0309578256
Category : Technology & Engineering
Languages : en
Pages : 102
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Book Description
This book assesses the state of the art of coatings materials and processes for gas-turbine blades and vanes, determines potential applications of coatings in high-temperature environments, identifies needs for improved coatings in terms of performance enhancements, design considerations, and fabrication processes, assesses durability of advanced coating systems in expected service environments, and discusses the required inspection, repair, and maintenance methods. The promising areas for research and development of materials and processes for improved coating systems and the approaches to increased coating standardization are identified, with an emphasis on materials and processes with the potential for improved performance, quality, reproducibility, or manufacturing cost reduction.
Author: Justyna Kulczyk-Malecka
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Book Description
Low emissivity (Low-E) coatings are applied to large area architectural glazing to reduce heat losses from buildings. They combine high visible transparency with high reflectance in the far-infrared region. To achieve this combination of properties, Low-E coatings generally consist of dielectric-silver-dielectric multi-layer systems or stacks, where the thin (~1 0 nm) silver layer reflects long wavelength IR back into the building and the dielectric layers both protect the silver and act as anti-reflectance layers. The dielectric layers are commonly Ti02, Sn02 or ZnO, and all the layers are usually deposited by magnetron sputtering. The market for Low-E coatings has grown considerably in recent years due to environmental legislation and increased energy costs. To further expand the market, the next generation of Low-E coatings are increasingly being deposited onto toughenable glass, which is post-deposition annealed at temperatures of up to 650°C. However, under these conditions, silver atoms are highly mobile and can rapidly diffuse through the other constituent layers of the coating stack, which can have a detrimental impact on the performance of the coating. Diffusion in polycrystalline films occurs much faster than in bulk samples and by different mechanisms. This is caused by the physical properties of thin films, which may contain a high density of defects such as dislocations, vacancies and grain boundaries that can act as pathways for diffusion processes. The aim of this project therefore is to carry out a detailed study of diffusion processes in dielectric-silver coating systems deposited under industrially relevant conditions (i.e. using commercially available magnetron designs and power deliver modes). Ti02 coatings have been deposited onto float glass substrates by reactive pulsed magnetron sputtering and characterised using Raman spectroscopy, scanning electron microscopy, energy-dispersive X-ray spectroscopy, atomic force microscopy and X-ray diffraction. The coatings have been annealed at temperatures in the range of 100°C to 800°C and re-analysed to determine the effect of annealing on the film structures. An interesting transition from a weakly crystalline rutile-like structure with very small grain sizes to a strongly crystalline anatase structure or mixed-phase structure with much larger grains was observed as annealing temperature was increased. Selected coatings were over coated with silver and annealed for a second time. These coatings were analysed by X-ray photoelectron spectroscopy and secondary ion mass spectrometry to determine the diffusion profiles of silver through the titania layer and the reverse diffusion of sodium from the glass substrates. Little difference in the diffusion rate of silver was observed with annealing temperature, but sodium was observed to diffuse significantly faster through samples annealed at higher temperature range. Similar studies have been performed for Al-doped ZnO, Zn2Sn04 and ShN4 coatings. These films have been post-deposition annealed at 650°C then over coated with silver and re- annealed at 250°C. Diffusion profiles for both Ag and Na atoms were measured using secondary ion mass spectrometry. Finally dielectric/ Ag/dielectric layers were deposited to investigate the behaviour of silver and sodium after annealing at 250°C. The basic models of diffusion mechanisms in thin films have been developed using Fick's second diffusion law. Analytical modelling was used to fit the experimental data into a concentration dependent curve that represents the solution to Fick's second law. Moreover selected dielectric/Ag/dielectric stacks were subjected to temperature dependency of silver diffusion studies using Arrhenius diffusion principle. Samples were post-deposition annealed at the temperature range of 200-650oC for 5 minutes to investigate silver diffusion at different heat treatment conditions and diffusivity values were used to find activation energies and frequency factors from Arrhenius plot. Overall findings from the diffusion studies are that from dielectric materials investigated in this work Al-doped ZnO coatings have the best barrier properties for silver atoms diffusion and show relatively low values for sodium diffusion, when not annealed at relatively high temperatures. Zinc stannate, on the other hand, was found to be the material through which atoms investigated here diffuse fairly easily. Both silver and sodium atoms were found to have the highest diffusion rates through zinc stannate films relative to the other coatings investigated in this work.
Author: National Research Council
Publisher: National Academies Press
ISBN: 0309053811
Category : Technology & Engineering
Languages : en
Pages : 102
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Book Description
This book assesses the state of the art of coatings materials and processes for gas-turbine blades and vanes, determines potential applications of coatings in high-temperature environments, identifies needs for improved coatings in terms of performance enhancements, design considerations, and fabrication processes, assesses durability of advanced coating systems in expected service environments, and discusses the required inspection, repair, and maintenance methods. The promising areas for research and development of materials and processes for improved coating systems and the approaches to increased coating standardization are identified, with an emphasis on materials and processes with the potential for improved performance, quality, reproducibility, or manufacturing cost reduction.
Author:
Publisher:
ISBN:
Category : Aeronautics
Languages : en
Pages : 652
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Book Description
Lists citations with abstracts for aerospace related reports obtained from world wide sources and announces documents that have recently been entered into the NASA Scientific and Technical Information Database.
Author: Advisory Committee on Technology and Society
Publisher: National Academies Press
ISBN: 9780309037860
Category : Social Science
Languages : en
Pages : 1298
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Book Description
Cities and Their Vital Systems asks basic questions about the longevity, utility, and nature of urban infrastructures; analyzes how they grow, interact, and change; and asks how, when, and at what cost they should be replaced. Among the topics discussed are problems arising from increasing air travel and airport congestion; the adequacy of water supplies and waste treatment; the impact of new technologies on construction; urban real estate values; and the field of "telematics," the combination of computers and telecommunications that makes money machines and national newspapers possible.
Author:
Publisher:
ISBN:
Category : Power resources
Languages : en
Pages : 1344
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Book Description
Author: United States. Energy Research and Development Administration
Publisher:
ISBN:
Category : Medicine
Languages : en
Pages : 800
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Book Description
Author:
Publisher:
ISBN:
Category : Nuclear energy
Languages : en
Pages : 912
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Book Description
Author: National Research Council (U.S.). Committee on Coatings for High-Temperature Structural Materials
Publisher: National Academies
ISBN:
Category : Technology & Engineering
Languages : en
Pages : 106
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Book Description
This report reviews the state of the art for coating systems based on the following approach. First, the application needs were identified and a description of the domain of use was developed. Second, the environment that currently exists and the substrate materials that are now used in the hot section of gas-turbine engines were examined. This, in turn, led to a more complete definition of the coatings systems required. Third, the application processes, the industrial base, and the repair and overhaul requirements were discussed and the support capabilities were assessed. This review provided a baseline for discussion of future trends and indicated how U.S. industry, government, and academia are planning to address the requirements of advanced propulsion systems.
