Author: Michael E. Brown
Publisher: Elsevier
ISBN: 0080868169
Category : Science
Languages : en
Pages : 355
Book Description
The whole of Volume 22 is devoted to the kinetics and mechanisms of the decomposition and interaction of inorganic solids, extended to include metal carboxylates. After an introductory chapter on the characteristic features of reactions in the solid phase, experimental methods of investigation of solid reactions and the measurement of reaction rates are reviewed in Chapter 2 and the theory of solid state kinetics in Chapter 3. The reactions of single substances, loosely grouped on the basis of a common anion since it is this constituent which most frequently undergoes breakdown, are discussed in Chapter 4, the sequence being effectively that of increasing anion complexity. Chapter 5 covers reactions between solids, and includes catalytic processes where one solid component remains unchanged, double compound formation and rate processes involving the interactions of more than three crystalline phases. The final chapter summarises the general conclusions drawn in the text of Chapter 2-5.
Reactions in the Solid State
Author: Michael E. Brown
Publisher: Elsevier
ISBN: 0080868169
Category : Science
Languages : en
Pages : 355
Book Description
The whole of Volume 22 is devoted to the kinetics and mechanisms of the decomposition and interaction of inorganic solids, extended to include metal carboxylates. After an introductory chapter on the characteristic features of reactions in the solid phase, experimental methods of investigation of solid reactions and the measurement of reaction rates are reviewed in Chapter 2 and the theory of solid state kinetics in Chapter 3. The reactions of single substances, loosely grouped on the basis of a common anion since it is this constituent which most frequently undergoes breakdown, are discussed in Chapter 4, the sequence being effectively that of increasing anion complexity. Chapter 5 covers reactions between solids, and includes catalytic processes where one solid component remains unchanged, double compound formation and rate processes involving the interactions of more than three crystalline phases. The final chapter summarises the general conclusions drawn in the text of Chapter 2-5.
Publisher: Elsevier
ISBN: 0080868169
Category : Science
Languages : en
Pages : 355
Book Description
The whole of Volume 22 is devoted to the kinetics and mechanisms of the decomposition and interaction of inorganic solids, extended to include metal carboxylates. After an introductory chapter on the characteristic features of reactions in the solid phase, experimental methods of investigation of solid reactions and the measurement of reaction rates are reviewed in Chapter 2 and the theory of solid state kinetics in Chapter 3. The reactions of single substances, loosely grouped on the basis of a common anion since it is this constituent which most frequently undergoes breakdown, are discussed in Chapter 4, the sequence being effectively that of increasing anion complexity. Chapter 5 covers reactions between solids, and includes catalytic processes where one solid component remains unchanged, double compound formation and rate processes involving the interactions of more than three crystalline phases. The final chapter summarises the general conclusions drawn in the text of Chapter 2-5.
Organic Solid-State Reactions
Author: Fumio Toda
Publisher: Springer Science & Business Media
ISBN: 9401700893
Category : Science
Languages : en
Pages : 279
Book Description
Most organic reactions have long been carried out in organic solvents without concern for their real necessity, reaction efficiency, and pollution problems. Very recently, we have found that most organic reactions can be carried out in the absence of a solvent, namely, in the solid state. In many cases, the solid-state reaction proceeds more easily and efficiently, and even more selectively than solution reaction. This shows that molecules move easily and selectively in the solid state. This finding changed the classical idea which suggests "molecules do not move and reactions do not occur in the solid state", and opened up a new research field for the study molecular dynamics in the solid state. The organic solid state reactions have many possibilities to be developed. For example, enantioselective reactions can easily be accomplished by carrying out the reaction in an inclusion complex crystal with an optically active host compound. Catalytic reactions also proceed in the solid state. Moreover, the solid-state reactions are more economical and ecologically sound. In the future, pollution-free synthetic procedures in the solid state will become increasingly important, not only in chemical industries but also in university laboratories.
Publisher: Springer Science & Business Media
ISBN: 9401700893
Category : Science
Languages : en
Pages : 279
Book Description
Most organic reactions have long been carried out in organic solvents without concern for their real necessity, reaction efficiency, and pollution problems. Very recently, we have found that most organic reactions can be carried out in the absence of a solvent, namely, in the solid state. In many cases, the solid-state reaction proceeds more easily and efficiently, and even more selectively than solution reaction. This shows that molecules move easily and selectively in the solid state. This finding changed the classical idea which suggests "molecules do not move and reactions do not occur in the solid state", and opened up a new research field for the study molecular dynamics in the solid state. The organic solid state reactions have many possibilities to be developed. For example, enantioselective reactions can easily be accomplished by carrying out the reaction in an inclusion complex crystal with an optically active host compound. Catalytic reactions also proceed in the solid state. Moreover, the solid-state reactions are more economical and ecologically sound. In the future, pollution-free synthetic procedures in the solid state will become increasingly important, not only in chemical industries but also in university laboratories.
Solid State Reactions
Author: Hermann Schmalzried
Publisher:
ISBN:
Category : Chemical reaction, Conditions and laws of
Languages : en
Pages : 272
Book Description
Publisher:
ISBN:
Category : Chemical reaction, Conditions and laws of
Languages : en
Pages : 272
Book Description
Chemical Kinetics of Solids
Author: Hermann Schmalzried
Publisher: John Wiley & Sons
ISBN: 3527615520
Category : Science
Languages : en
Pages : 450
Book Description
Many different chemical processes take place inside solids or at solid surfaces and interfaces. However, their quantitative description sometimes seems difficult to understand. This book by Professor Schmalzried, author of the eminently successful Solid State Reactions; bridges the gap between the 'physical' and 'chemical' approaches to this subject because it is written in a language which both sides understand. For the first time, a comprehensive coverage of the rapidly developing field of Solid State Kinetics is available. The topics covered in this book go far beyond diffusional transport. Homogeneous and heterogeneous solid-state reactions, phase transitions or the influence of external fields are also treated in detail. With this background, the author explains e.g. charge transport mechanisms in ionic conductors, principles of sensor technology, or oxidation processes clearly and comprehensibly. This book is a must for every solid-state chemist and an indispensable tool for academic and industrial readers alike. From reviews: 'a first-rate reference work that a must for any science library' (J. Am Chem. Soc.) 'can be recommended without restrictions ...' (Z. Phys. Chem.)
Publisher: John Wiley & Sons
ISBN: 3527615520
Category : Science
Languages : en
Pages : 450
Book Description
Many different chemical processes take place inside solids or at solid surfaces and interfaces. However, their quantitative description sometimes seems difficult to understand. This book by Professor Schmalzried, author of the eminently successful Solid State Reactions; bridges the gap between the 'physical' and 'chemical' approaches to this subject because it is written in a language which both sides understand. For the first time, a comprehensive coverage of the rapidly developing field of Solid State Kinetics is available. The topics covered in this book go far beyond diffusional transport. Homogeneous and heterogeneous solid-state reactions, phase transitions or the influence of external fields are also treated in detail. With this background, the author explains e.g. charge transport mechanisms in ionic conductors, principles of sensor technology, or oxidation processes clearly and comprehensibly. This book is a must for every solid-state chemist and an indispensable tool for academic and industrial readers alike. From reviews: 'a first-rate reference work that a must for any science library' (J. Am Chem. Soc.) 'can be recommended without restrictions ...' (Z. Phys. Chem.)
Organic Solid-State Reactions
Author: Fumio Toda
Publisher: Springer Science & Business Media
ISBN: 9781402002274
Category : Science
Languages : en
Pages : 292
Book Description
Most organic reactions have long been carried out in organic solvents without concern for their real necessity, reaction efficiency, and pollution problems. Very recently, we have found that most organic reactions can be carried out in the absence of a solvent, namely, in the solid state. In many cases, the solid-state reaction proceeds more easily and efficiently, and even more selectively than solution reaction. This shows that molecules move easily and selectively in the solid state. This finding changed the classical idea which suggests "molecules do not move and reactions do not occur in the solid state", and opened up a new research field for the study molecular dynamics in the solid state. The organic solid state reactions have many possibilities to be developed. For example, enantioselective reactions can easily be accomplished by carrying out the reaction in an inclusion complex crystal with an optically active host compound. Catalytic reactions also proceed in the solid state. Moreover, the solid-state reactions are more economical and ecologically sound. In the future, pollution-free synthetic procedures in the solid state will become increasingly important, not only in chemical industries but also in university laboratories.
Publisher: Springer Science & Business Media
ISBN: 9781402002274
Category : Science
Languages : en
Pages : 292
Book Description
Most organic reactions have long been carried out in organic solvents without concern for their real necessity, reaction efficiency, and pollution problems. Very recently, we have found that most organic reactions can be carried out in the absence of a solvent, namely, in the solid state. In many cases, the solid-state reaction proceeds more easily and efficiently, and even more selectively than solution reaction. This shows that molecules move easily and selectively in the solid state. This finding changed the classical idea which suggests "molecules do not move and reactions do not occur in the solid state", and opened up a new research field for the study molecular dynamics in the solid state. The organic solid state reactions have many possibilities to be developed. For example, enantioselective reactions can easily be accomplished by carrying out the reaction in an inclusion complex crystal with an optically active host compound. Catalytic reactions also proceed in the solid state. Moreover, the solid-state reactions are more economical and ecologically sound. In the future, pollution-free synthetic procedures in the solid state will become increasingly important, not only in chemical industries but also in university laboratories.
An Introduction to Solid State Diffusion
Author: Richard J. Borg
Publisher: Elsevier
ISBN: 0323138403
Category : Science
Languages : en
Pages : 377
Book Description
The energetics and mechanisms of diffusion control the kinetics of such diverse phenomena as the fabrication of semiconductors and superconductors, the tempering of steel, geological metamorphism, the precipitation hardening of nonferrous alloys and corrosion of metals and alloys. This work explains the fundamentals of diffusion in the solid state at a level suitable for upper-level undergraduate and beginning graduate students in materials science, metallurgy, mineralogy, and solid state physics and chemistry. A knowledge of physical chemistry such as is generally provided by a one-year undergraduate course is a prerequisite, though no detailed knowledge of solid state physics or crystallography is required.
Publisher: Elsevier
ISBN: 0323138403
Category : Science
Languages : en
Pages : 377
Book Description
The energetics and mechanisms of diffusion control the kinetics of such diverse phenomena as the fabrication of semiconductors and superconductors, the tempering of steel, geological metamorphism, the precipitation hardening of nonferrous alloys and corrosion of metals and alloys. This work explains the fundamentals of diffusion in the solid state at a level suitable for upper-level undergraduate and beginning graduate students in materials science, metallurgy, mineralogy, and solid state physics and chemistry. A knowledge of physical chemistry such as is generally provided by a one-year undergraduate course is a prerequisite, though no detailed knowledge of solid state physics or crystallography is required.
Solid State Polymerization
Author: Constantine D. Papaspyrides
Publisher: John Wiley & Sons
ISBN: 0470451823
Category : Technology & Engineering
Languages : en
Pages : 314
Book Description
The most current guide to solid state polymerization Solid State Polymerization (SSP)is an indispensable tool in the design, manufacture, and study of polymers, plastics, and fibers. SSP presents significant advantages over other polymerization techniques due to low operating temperatures, inexpensive equipment, and simple and environmentally sound procedures. Combining fundamentals of polymer science, chemistry, physical chemistry, and engineering, SSP also offers many research applications for a wide range of students and investigators. Gathering and filtering the latest literature on SSP, Solid Solid State Polymerization offers a unique, one-stop resource on this important process. With chapters contributed by leaders in the field, this text summarizes SSP, and provides essential coverage that includes: An introduction to SSP, with chemical and physical steps, apparatus, advantages, and parameters SSP physical chemistry and mechanisms Kinetic aspects of polyesters and polyamides SSP Catalysis in SSP processes Application of SSP under high pressure conditions in the laboratory Engineering aspects regarding process modeling and industrial application Recent developments and future possibilities Solid State Polymerization provides the most up-to-date coverage of this constantly developing field to academic and industry professionals, as well as graduate and postgraduate-level students in chemical engineering, materials science and engineering, polymer chemistry, polymer processing and polymer engineering.
Publisher: John Wiley & Sons
ISBN: 0470451823
Category : Technology & Engineering
Languages : en
Pages : 314
Book Description
The most current guide to solid state polymerization Solid State Polymerization (SSP)is an indispensable tool in the design, manufacture, and study of polymers, plastics, and fibers. SSP presents significant advantages over other polymerization techniques due to low operating temperatures, inexpensive equipment, and simple and environmentally sound procedures. Combining fundamentals of polymer science, chemistry, physical chemistry, and engineering, SSP also offers many research applications for a wide range of students and investigators. Gathering and filtering the latest literature on SSP, Solid Solid State Polymerization offers a unique, one-stop resource on this important process. With chapters contributed by leaders in the field, this text summarizes SSP, and provides essential coverage that includes: An introduction to SSP, with chemical and physical steps, apparatus, advantages, and parameters SSP physical chemistry and mechanisms Kinetic aspects of polyesters and polyamides SSP Catalysis in SSP processes Application of SSP under high pressure conditions in the laboratory Engineering aspects regarding process modeling and industrial application Recent developments and future possibilities Solid State Polymerization provides the most up-to-date coverage of this constantly developing field to academic and industry professionals, as well as graduate and postgraduate-level students in chemical engineering, materials science and engineering, polymer chemistry, polymer processing and polymer engineering.
Green Organic Reactions
Author: Gopinathan Anilkumar
Publisher: Springer Nature
ISBN: 9813368977
Category : Technology & Engineering
Languages : en
Pages : 349
Book Description
This book presents important developments and applications of green chemistry, especially in the field of organic chemistry. The chapters give a brief account of green organic reactions in water, green organic reactions using microwave and in solvent-free conditions. In depth discussions on the green aspects of ionic liquids, flow reactions, and recoverable catalysts are provided in this book. An exclusive chapter devoted to green Lewis acid is also included. The potential of supercritical fluids as green solvents in various areas of organic reactions is explained as well. This book will be a valuable reference for beginners as well as advanced researchers interested in green organic chemistry.
Publisher: Springer Nature
ISBN: 9813368977
Category : Technology & Engineering
Languages : en
Pages : 349
Book Description
This book presents important developments and applications of green chemistry, especially in the field of organic chemistry. The chapters give a brief account of green organic reactions in water, green organic reactions using microwave and in solvent-free conditions. In depth discussions on the green aspects of ionic liquids, flow reactions, and recoverable catalysts are provided in this book. An exclusive chapter devoted to green Lewis acid is also included. The potential of supercritical fluids as green solvents in various areas of organic reactions is explained as well. This book will be a valuable reference for beginners as well as advanced researchers interested in green organic chemistry.
Solid State Chemistry
Author: Richard C. Ropp
Publisher: Elsevier
ISBN: 0080541453
Category : Science
Languages : en
Pages : 461
Book Description
Solid State Chemistry is a general textbook, composed for those with little background knowledge of the subject, but who wish to learn more about the various segments of solid state theory and technology. The information is presented in a form that can easily be understood and will be useful to readers wishing to build on their own store of knowledge and experience. Well presented in easy to understand format Informative textbook aimed primarily at the novice Comprehensively covers the segments of solid state theory and technology
Publisher: Elsevier
ISBN: 0080541453
Category : Science
Languages : en
Pages : 461
Book Description
Solid State Chemistry is a general textbook, composed for those with little background knowledge of the subject, but who wish to learn more about the various segments of solid state theory and technology. The information is presented in a form that can easily be understood and will be useful to readers wishing to build on their own store of knowledge and experience. Well presented in easy to understand format Informative textbook aimed primarily at the novice Comprehensively covers the segments of solid state theory and technology
Materials Chemistry of Ceramics
Author: Junichi Hojo
Publisher: Springer Nature
ISBN: 9811399352
Category : Technology & Engineering
Languages : en
Pages : 237
Book Description
This book provides fundamental knowledge of ceramics science and technology in a compact volume. Based on inorganic chemistry, it is intended as a reader for graduate students and young researchers beginning work in ceramics. The importance of the book is that it provides a scientific understanding of structure, properties, and processing from the chemical aspect, leading to creation of future ceramics. Ceramics have high hardness, strength, thermal and chemical stability, as well as various electromagnetic functions. To take full advantage of ceramics, their use has been advanced to engineering and electronic ceramics. Most ceramics have been fabricated by powder processing, and new technologies have also evolved such as CVD and sol-gel methods: new ceramics aimed at new functions of highly pure oxides and artificial nitrides, carbides, and borides; fine ceramics focused on precise control of composition and microstructure; and design of unique morphology, such as nanoparticles, nanofibers, nanosheets, mesoporous materials, and hybrids. Materials are composed of atoms and molecules. They are assembled into crystals and are amorphous, leading to 3-D micro/nano structures. In addition to the topics described above, this book shows the importance of chemistry for materials design at the nanometer scale, and that chemistry develops new fields of environment, energy, informatics, biomaterials, and other areas.
Publisher: Springer Nature
ISBN: 9811399352
Category : Technology & Engineering
Languages : en
Pages : 237
Book Description
This book provides fundamental knowledge of ceramics science and technology in a compact volume. Based on inorganic chemistry, it is intended as a reader for graduate students and young researchers beginning work in ceramics. The importance of the book is that it provides a scientific understanding of structure, properties, and processing from the chemical aspect, leading to creation of future ceramics. Ceramics have high hardness, strength, thermal and chemical stability, as well as various electromagnetic functions. To take full advantage of ceramics, their use has been advanced to engineering and electronic ceramics. Most ceramics have been fabricated by powder processing, and new technologies have also evolved such as CVD and sol-gel methods: new ceramics aimed at new functions of highly pure oxides and artificial nitrides, carbides, and borides; fine ceramics focused on precise control of composition and microstructure; and design of unique morphology, such as nanoparticles, nanofibers, nanosheets, mesoporous materials, and hybrids. Materials are composed of atoms and molecules. They are assembled into crystals and are amorphous, leading to 3-D micro/nano structures. In addition to the topics described above, this book shows the importance of chemistry for materials design at the nanometer scale, and that chemistry develops new fields of environment, energy, informatics, biomaterials, and other areas.