Molecular Propagation through Electron Energy Level Crossings PDF Download
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Author: George Allan Hagedorn
Publisher: American Mathematical Soc.
ISBN: 0821826050
Category : Mathematics
Languages : en
Pages : 142
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Book Description
The principal results of this paper involve the extension of the time-dependent Born-Oppenheimer approximation to accommodate the propagation of nuclei through generic, minimal multiplicity electron energy level crossings. The Born-Oppenheimer approximation breaks down at electron energy level crossings, which are prevalent in molecular systems. We classify generic, minimal multiplicity level crossings and derives a normal form for the electron Hamiltonian near each type of crossing. We then extend the time-dependent Born-Oppenheimer approximation to accommodate the propagation of nuclei through each type of electron energy level crossing.
Author: George Allan Hagedorn
Publisher: American Mathematical Soc.
ISBN: 0821826050
Category : Mathematics
Languages : en
Pages : 142
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Book Description
The principal results of this paper involve the extension of the time-dependent Born-Oppenheimer approximation to accommodate the propagation of nuclei through generic, minimal multiplicity electron energy level crossings. The Born-Oppenheimer approximation breaks down at electron energy level crossings, which are prevalent in molecular systems. We classify generic, minimal multiplicity level crossings and derives a normal form for the electron Hamiltonian near each type of crossing. We then extend the time-dependent Born-Oppenheimer approximation to accommodate the propagation of nuclei through each type of electron energy level crossing.
Author: George Allan Hagedorn
Publisher:
ISBN: 9781470401153
Category : Born-Oppenheimer approximation
Languages : en
Pages : 130
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Book Description
Author: Paul Bourdon
Publisher: American Mathematical Soc.
ISBN: 0821806300
Category : Mathematics
Languages : en
Pages : 122
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Book Description
We undertake a systematic study of cyclic phenomena for composition operators. Our work shows that composition operators exhibit strikingly diverse types of cyclic behavior, and it connects this behavior with classical problems involving complex polynomial approximation and analytic functional equations.
Author: James Damon
Publisher: American Mathematical Soc.
ISBN: 0821804812
Category : Mathematics
Languages : en
Pages : 130
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Book Description
Almost free divisors and complete intersections form a general class of nonisolated hypersurface and completer intersection singularities. They also include discriminants of mappings, bifurcation sets, and certain types of arrangements of hyperplanes such as Coxeter arrangements and generic arrangements. Associated to the singularities of this class is a "singular Milnor fibration" which has the same homotopy properties as the Milnor fibration for isolated singularities. This memoir deduces topological properties of singularities in a number of situations including: complements of hyperplane arrangements, various nonisolated complete intersections, nonlinear arrangements of hypersurfaces, functions on discriminants, singularities defined by compositions of functions, and bifurcation sets.
Author: Paul Kirk
Publisher: American Mathematical Soc.
ISBN: 082180538X
Category : Mathematics
Languages : en
Pages : 73
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Book Description
The analytic perturbation theory for eigenvalues of Dirac operators on odd dimensional manifolds with boundary is described in terms of [italic]extended L2 eigenvectors [end italics] on manifolds with cylindrical ends. These are generalizations of the Atiyah-Patodi-Singer extended [italic capital]L2 kernel of a Dirac operator. We prove that they form a discrete set near zero and deform analytically, in contrast to [italic capital]L2 eigenvectors, which can be absorbed into the continuous spectrum under deformations when the tangential operator is not invertible. We show that the analytic deformation theory for extended [italic capital]L2 eigenvectors and Atiyah-Patodi-Singer eigenvectors coincides.
Author: Christian Krattenthaler
Publisher: American Mathematical Soc.
ISBN: 0821826131
Category : Mathematics
Languages : en
Pages : 122
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Book Description
A theory of counting nonintersecting lattice paths by the major index and its generalizations is developed. We obtain determinantal expressions for the corresponding generating functions for families of nonintersecting lattice paths with given starting points and given final points, where the starting points lie on a line parallel to [italic]x + [italic]y = 0. In some cases these determinants can be evaluated to result in simple products. As applications we compute the generating function for tableaux with [italic]p odd rows, with at most [italic]c columns, and with parts between 1 and [italic]n. Moreover, we compute the generating function for the same kind of tableaux which in addition have only odd parts. We thus also obtain a closed form for the generating function for symmetric plane partitions with at most [italic]n rows, with parts between 1 and [italic]c, and with [italic]p odd entries on the main diagonal. In each case the result is a simple product. By summing with respect to [italic]p we provide new proofs of the Bender-Knuth and MacMahon (ex-)conjectures, which were first proved by Andrews, Gordon, and Macdonald. The link between nonintersecting lattice paths and tableaux is given by variations of the Knuth correspondence.
Author: Huaxin Lin
Publisher: American Mathematical Soc.
ISBN: 0821826115
Category : Mathematics
Languages : en
Pages : 102
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Book Description
We show that the Weyl-von Neumann theorem for unitaries holds for [lowercase Greek]Sigma-unital [italic capital]A[italic capital]F-algebras and their multiplier algebras.
Author: Freddy Dumortier
Publisher: American Mathematical Soc.
ISBN: 082180443X
Category : Mathematics
Languages : en
Pages : 117
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Book Description
In this book, the ``canard phenomenon'' occurring in Van der Pol's equation $\epsilon \ddot x+(x^2+x)\dot x+x-a=0$ is studied. For sufficiently small $\epsilon >0$ and for decreasing $a$, the limit cycle created in a Hopf bifurcation at $a = 0$ stays of ``small size'' for a while before it very rapidly changes to ``big size'', representing the typical relaxation oscillation. The authors give a geometric explanation and proof of this phenomenon using foliations by center manifolds and blow-up of unfoldings as essential techniques. The method is general enough to be useful in the study of other singular perturbation problems.
Author: Carlos Andradas
Publisher: American Mathematical Soc.
ISBN: 0821826123
Category : Mathematics
Languages : en
Pages : 130
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Book Description
A set which can be defined by systems of polynomial inequalities is called semialgebraic. When such a description is possible locally around every point, by means of analytic inequalities varying with the point, the set is called semianalytic. If one single system of strict inequalities is enough, either globally or locally at every point, the set is called basic. The topic of this work is the relationship between these two notions. Namely, Andradas and Ruiz describe and characterize, both algebraically and geometrically, the obstructions for a basic semianalytic set to be basic semialgebraic. Then they describe a special family of obstructions that suffices to recognize whether or not a basic semianalytic set is basic semialgebraic. Finally, they use the preceding results to discuss the effect on basicness of birational transformations.
Author: Dihua Jiang
Publisher: American Mathematical Soc.
ISBN: 0821804766
Category : Mathematics
Languages : en
Pages : 210
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Book Description
Automorphic L-functions, introduced by Robert Langlands in the 1960s, are natural extensions of such classical L-functions as the Riemann zeta function, Hecke L-functions, etc. They form an important part of the Langlands Program, which seeks to establish connections among number theory, representation theory, and geometry. This book offers, via the Rankin-Selberg method, a thorough and comprehensive examination of the degree 16 standard L-function of the product of two rank two symplectic similitude groups, which includes the study of the global integral of Rankin-Selberg type and local integrals, analytic properties of certain Eisenstein series of symplectic groups, and the relevant residue representations.
