Flat Flame Burner Studies on Coal Nitrogen Release PDF Download
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Author: D. G. Wardle
Publisher:
ISBN:
Category : Air
Languages : en
Pages : 15
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Book Description
Author: D. G. Wardle
Publisher:
ISBN:
Category : Air
Languages : en
Pages : 15
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Book Description
Author: Harwell Laboratory. Coal R & D Programme
Publisher:
ISBN:
Category : Air
Languages : en
Pages : 0
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Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 492
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Author: John M. Sowa
Publisher:
ISBN:
Category : Electronic dissertations
Languages : en
Pages : 130
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Book Description
Pollution is one of the greatest concerns with pulverized coal combustion. With tightening standards on pollution emissions, more information is needed to create better design models. Burner modifications are the most efficient changes that can be made to assure sufficient carbon burnout and low NOx emissions.
Author:
Publisher:
ISBN:
Category : Power resources
Languages : en
Pages : 972
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Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 353
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The focus of this program is to provide insight into the formation and minimization of NO(subscript x) in multi-burner arrays, such as those that would be found in a typical utility boiler. Most detailed studies are performed in single-burner test facilities, and may not capture significant burner-to-burner interactions that could influence NO(subscript x) emissions. Thus, investigations of such interactions were made by performing a combination of single and multiple burner experiments in a pilot-scale coal-fired test facility at the University of Utah, and by the use of computational combustion simulations to evaluate full-scale utility boilers. In addition, fundamental studies on nitrogen release from coal were performed to develop greater understanding of the physical processes that control NO formation in pulverized coal flames--particularly under low NO(subscript x) conditions. A CO/H2/O2/N2 flame was operated under fuel-rich conditions in a flat flame reactor to provide a high temperature, oxygen-free post-flame environment to study secondary reactions of coal volatiles. Effects of temperature, residence time and coal rank on nitrogen evolution and soot formation were examined. Elemental compositions of the char, tar and soot were determined by elemental analysis, gas species distributions were determined using FTIR, and the chemical structure of the tar and soot was analyzed by solid-state 13C NMR spectroscopy. A laminar flow drop tube furnace was used to study char nitrogen conversion to NO. The experimental evidence and simulation results indicated that some of the nitrogen present in the char is converted to nitric oxide after direct attack of oxygen on the particle, while another portion of the nitrogen, present in more labile functionalities, is released as HCN and further reacts in the bulk gas. The reaction of HCN with NO in the bulk gas has a strong influence on the overall conversion of char-nitrogen to nitric oxide; therefore, any model that aims to predict the conversion of char-nitrogen to nitric oxide should allow for the conversion of char-nitrogen to HCN. The extent of the HCN conversion to NO or N2 will depend on the composition of the atmosphere surrounding the particle. A pilot-scale testing campaign was carried out to evaluate the impact of multiburner firing on NO(subscript x) emissions using a three-burner vertical array. In general, the results indicated that multiburner firing yielded higher NO(subscript x) emissions than single burner firing at the same fuel rate and excess air. Mismatched burner operation, due to increases in the firing rate of the middle burner, generally demonstrated an increase in NO(subscript x) over uniform firing. Biased firing, operating the middle burner fuel rich with the upper and lower burners fuel lean, demonstrated an overall reduction in NO(subscript x) emissions; particularly when the middle burner was operated highly fuel rich. Computational modeling indicated that operating the three burner array with the center burner swirl in a direction opposite to the other two resulted in a slight reduction in NO(subscript x).
Author:
Publisher:
ISBN:
Category : Power resources
Languages : en
Pages : 806
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Book Description
Semiannual, with semiannual and annual indexes. References to all scientific and technical literature coming from DOE, its laboratories, energy centers, and contractors. Includes all works deriving from DOE, other related government-sponsored information, and foreign nonnuclear information. Arranged under 39 categories, e.g., Biomedical sciences, basic studies; Biomedical sciences, applied studies; Health and safety; and Fusion energy. Entry gives bibliographical information and abstract. Corporate, author, subject, report number indexes.
Author: J.A. Pajares
Publisher: Elsevier
ISBN: 0080544630
Category : Science
Languages : en
Pages : 875
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Book Description
This volume contains papers presented at the 8th International Conference on Coal Science, held in Oviedo, Spain, September 10-15, 1995. Volume I contains papers dealing with Fundamentals and General Aspects, Combustion and Gasification and Pyrolysis and Carbonization. Volume II covers papers discussing Liquefaction and Hydropyrolysis and Coal and the Environment.The scope of topics covered will give the reader a state-of-the-art impression of coal characterization and depolymerization, coal-derived carbons, coal carbonization and liquefaction, and the progress towards making coal an environmentally acceptable fuel during its combustion in electricity production. The use of modern physicochemical characterization techniques has advanced knowledge of coal composition and structure enormously in the last twenty years, and it is hoped that coal will enter into the next millenium as a clean and efficient fuel.
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Category :
Languages : en
Pages :
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A premixed, staged, down-fired, pulverized coal reactor and a flat flame burner were used to study the evolution of nitrogen in coal contrasting differences in air and oxy-combustion. In the premixed reactor, the oxidizer was staged to produce a fuel rich zone followed by a burnout zone. The initial nominal fuel rich zone stoichiometric ratio (S.R.) of 0.85 selected produced higher NO reductions in the fuel rich region under oxy-combustion conditions. Air was found to be capable of similar NO reductions when the fuel rich zone was at a much lower S.R. of 0.65. At a S.R. of 0.85, oxy-combustion was measured to have higher CO, unburned hydrocarbons, HCN and NH3 in the fuel rich region than air at the same S.R. There was no measured difference in the initial formation of NO. The data suggest devolatilization and initial NO formation is similar for the two oxidizers when flame temperatures are the same, but the higher CO2 leads to higher concentrations of CO and nitrogen reducing intermediates at a given equivalence ratio which increases the ability of the gas phase to reduce NO. These results are supported by flat flame burner experiments which show devolatilization of nitrogen from the coal and char to be similar for air and oxy-flame conditions at a given temperature. A model of premixed combustion containing devolatilization, char oxidation and detailed kinetics captures most of the trends seen in the data. The model suggests CO is high in oxy-combustion because of dissociation of CO2. The model also predicts a fraction (up to 20%, dependent on S.R.) of NO in air combustion can be formed via thermal processes with the source being nitrogen from the air while in oxy-combustion equilibrium drives a reduction in NO of similar magnitude. The data confirm oxy-combustion is a superior oxidizer to air for NO control because NO reduction can be achieved at higher S.R. producing better char burnout in addition to NO from recirculated flue gas being reduced as it passes back through the flame.
Author: Jim Williamson
Publisher: Taylor & Francis
ISBN: 135141027X
Category : Technology & Engineering
Languages : en
Pages : 812
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Book Description
Coal provides almost 40% of the world's electricity, and despite the understandable concern with respect to the environmental impact associated with coal use, forecasts from the International Energy Agency predict, that worldwide coal use will increase by up to 2% per annum until the year 2OlO. Faced with this increase, it is clearly important that the most efficient and environmentally acceptable clean coal technologies are available. This book is comprised of the proceedings of the Engineering Foundation Conference held in June 1993 in England. The objective of the conference was to present ideas on methods of predicting and reducing the effects of ash deposition in coal conversion systems, highlighting the problems experienced in industry, considering both utilities and industrial plants, and providing a view of the technology of coal ash deposition and its impact. Better techniques are needed to reduce the impact of ash deposition in coal fired plants, and these proceedings should form a reference document for anyone either experiencing slagging or actively engaged in trying to understand or eliminate the phenomenon.
