Author: Daniel J. Graham
Publisher: CRC Press
ISBN: 1439820880
Category : Science
Languages : en
Pages : 236
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Book Description
Thermodynamics and information touch theory every facet of chemistry. However, the physical chemistry curriculum digested by students worldwide is still heavily skewed toward heat/work principles established more than a century ago. Rectifying this situation, Chemical Thermodynamics and Information Theory with Applications explores applications dra
Author: W.J. Rankin
Publisher: CRC Press
ISBN: 1000703169
Category : Science
Languages : en
Pages : 345
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Book Description
This book develops the theory of chemical thermodynamics from first principles, demonstrates its relevance across scientific and engineering disciplines, and shows how thermodynamics can be used as a practical tool for understanding natural phenomena and developing and improving technologies and products. Concepts such as internal energy, enthalpy, entropy, and Gibbs energy are explained using ideas and experiences familiar to students, and realistic examples are given so the usefulness and pervasiveness of thermodynamics becomes apparent. The worked examples illustrate key ideas and demonstrate important types of calculations, and the problems at the end of chapters are designed to reinforce important concepts and show the broad range of applications. Most can be solved using digitized data from open access databases and a spreadsheet. Answers are provided for the numerical problems. A particular theme of the book is the calculation of the equilibrium composition of systems, both reactive and non-reactive, and this includes the principles of Gibbs energy minimization. The overall approach leads to the intelligent use of thermodynamic software packages but, while these are discussed and their use demonstrated, they are not the focus of the book, the aim being to provide the necessary foundations. Another unique aspect is the inclusion of three applications chapters: heat and energy aspects of processing; the thermodynamics of metal production and recycling; and applications of electrochemistry. This book is aimed primarily at students of chemistry, chemical engineering, applied science, materials science, and metallurgy, though it will be also useful for students undertaking courses in geology and environmental science. A solutions manual is available for instructors.
Author: Roman F Nalewajski
Publisher: Elsevier
ISBN: 0080459749
Category : Science
Languages : en
Pages : 463
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Book Description
As well as providing a unified outlook on physics, Information Theory (IT) has numerous applications in chemistry and biology owing to its ability to provide a measure of the entropy/information contained within probability distributions and criteria of their information "distance" (similarity) and independence. Information Theory of Molecular Systems applies standard IT to classical problems in the theory of electronic structure and chemical reactivity. The book starts by introducing the basic concepts of modern electronic structure/reactivity theory based upon the Density Functional Theory (DFT), followed by an outline of the main ideas and techniques of IT, including several illustrative applications to molecular systems. Coverage includes information origins of the chemical bond, unbiased definition of molecular fragments, adequate entropic measures of their internal (intra-fragment) and external (inter-fragment) bond-orders and valence-numbers, descriptors of their chemical reactivity, and information criteria of their similarity and independence. Information Theory of Molecular Systems is recommended to graduate students and researchers interested in fresh ideas in the theory of electronic structure and chemical reactivity. ·Provides powerful tools for tackling both classical and new problems in the theory of the molecular electronic structure and chemical reactivity·Introduces basic concepts of the modern electronic structure/reactivity theory based upon the Density Functional Theory (DFT)·Outlines main ideas and techniques of Information Theory
Author: Antonio Saggion
Publisher: Springer Nature
ISBN: 3030269760
Category : Science
Languages : en
Pages : 432
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Book Description
This book offers a comprehensive overview of thermodynamics. It is divided into four parts, the first of which equips readers with a deeper understanding of the fundamental principles of thermodynamics of equilibrium states and of their evolution. The second part applies these principles to a series of generalized situations, presenting applications that are of interest both in their own right and in terms of demonstrating how thermodynamics, as a theory of principle, relates to different fields. In turn, the third part focuses on non-equilibrium configurations and the dynamics of natural processes. It discusses both discontinuous and continuous systems, highlighting the interference among non-equilibrium processes, and the nature of stationary states and of fluctuations in isolated systems. Lastly, part four introduces the relation between physics and information theory, which constitutes a new frontier in fundamental research. The book includes step-by-step exercises, with solutions, to help readers to gain a fuller understanding of the subjects, and also features a series of appendices providing useful mathematical formulae. Reflecting the content of modern university courses on thermodynamics, it is a valuable resource for students and young scientists in the fields of physics, chemistry, and engineering.
Author: Arieh Ben-Naim
Publisher: Springer Nature
ISBN: 3031212762
Category : Computers
Languages : en
Pages : 242
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Book Description
This book focuses on analysing the applications of the Shannon Measure of Information (SMI). The book introduces the concept of frustration and discusses the question of the quantification of this concept within information theory (IT), while it also focuses on the interpretation of the entropy of systems of interacting particles in terms of the SMI and of mutual information. The author examines the question of the possibility of measuring the extent of frustration using mutual information and discusses some classical examples of processes of mixing and assimilation for which the entropy changes are interpreted in terms of SMI. A description of a few binding systems and the interpretation of cooperativity phenomena in terms of mutual information are also presented, along with a detailed discussion on the general method of using maximum SMI in order to find the “best-guess” probability distribution. This book is a valuable contribution to the field of information theory and will be of great interest to any scientist who is interested in IT and in its potential applications.
Author: Iwao Teraoka
Publisher: John Wiley & Sons
ISBN: 1118305116
Category : Science
Languages : en
Pages : 352
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Book Description
This textbook introduces chemistry and chemical engineering students to molecular descriptions of thermodynamics, chemical systems, and biomolecules. Equips students with the ability to apply the method to their own systems, as today's research is microscopic and molecular and articles are written in that language Provides ample illustrations and tables to describe rather difficult concepts Makes use of plots (charts) to help students understand the mathematics necessary for the contents Includes practice problems and answers
Author: Arieh Ben-Naim
Publisher: World Scientific Publishing Company Incorporated
ISBN: 9789814578202
Category : Science
Languages : en
Pages : 414
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Book Description
The book presents a clear and unique approach to statistical thermodynamics based on Shannon's measure of information, and provides applications to problems of interest in the life sciences. There is no other book which presents the fundamentals of statistical thermodynamics on Information theory, yet also includes many applications which usually do not feature in such textbooks.
Author: Harold J. Morowitz
Publisher: Elsevier
ISBN: 1483263169
Category : Science
Languages : en
Pages : 212
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Book Description
Entropy for Biologists: An Introduction to Thermodynamics is an introductory book for people in the life sciences who wish to master the concepts of thermal physics without being forced to a degree and rate of symbol manipulation which is foreign to their patterns of thought. The book opens with a chapter on temperature, followed by separate chapters that discuss the concepts of energy, kinetic theory, total energy, the second law of thermodynamics, entropy, and probability and information theory. Subsequent chapters deal with statistical mechanics and its relation to thermodynamics, free-energy functions, applications of the Gibbs free energy and the Gibbs chemical potential, and measurement in thermal physics. The book is primarily directed at those graduate and advanced undergraduate students of biology and biochemistry who wish to develop a sense of confidence about their understanding of the thermal physics which will be useful in pursuing their work. It may also prove useful to professionals who wish to bolster their knowledge in this area.
Author: Bruce H. Mahan
Publisher: Courier Corporation
ISBN: 0486151239
Category : Science
Languages : en
Pages : 178
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Book Description
This straightforward presentation emphasizes chemical applications of thermodynamics as well as physical interpretations, offering students an introduction that's both interesting and coherent. It considers chemical behavior in terms of energy and entropy, and it explains the ways in which the magnitude of energy and entropy changes are dictated by atomic properties. All concepts are presented in a simplified mathematical context, making this an ideal text for a beginning course in thermodynamics. The author considers the first and second laws of thermodynamics in turn, after which he proceeds to applications of thermodynamic principles. He devotes considerable attention to the concept of entropy, emphasizing the interpretation of entropy changes and chemical behavior in terms of qualitative molecular properties. Students gain a familiarity with the entropy concept that will form a solid foundation for later courses and more formal thermodynamic treatments.
Author: W.J. Rankin
Publisher: CRC Press
ISBN: 100070470X
Category : Technology & Engineering
Languages : en
Pages : 335
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Book Description
This book develops the theory of chemical thermodynamics from first principles, demonstrates its relevance across scientific and engineering disciplines, and shows how thermodynamics can be used as a practical tool for understanding natural phenomena and developing and improving technologies and products. Concepts such as internal energy, enthalpy, entropy, and Gibbs energy are explained using ideas and experiences familiar to students, and realistic examples are given so the usefulness and pervasiveness of thermodynamics becomes apparent. The worked examples illustrate key ideas and demonstrate important types of calculations, and the problems at the end of chapters are designed to reinforce important concepts and show the broad range of applications. Most can be solved using digitized data from open access databases and a spreadsheet. Answers are provided for the numerical problems. A particular theme of the book is the calculation of the equilibrium composition of systems, both reactive and non-reactive, and this includes the principles of Gibbs energy minimization. The overall approach leads to the intelligent use of thermodynamic software packages but, while these are discussed and their use demonstrated, they are not the focus of the book, the aim being to provide the necessary foundations. Another unique aspect is the inclusion of three applications chapters: heat and energy aspects of processing; the thermodynamics of metal production and recycling; and applications of electrochemistry. This book is aimed primarily at students of chemistry, chemical engineering, applied science, materials science, and metallurgy, though it will be also useful for students undertaking courses in geology and environmental science. A solutions manual is available for instructors.
