Thermodiffusion in Multicomponent Mixtures PDF Download
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Author: Seshasai Srinivasan
Publisher: Springer Science & Business Media
ISBN: 1461455995
Category : Science
Languages : en
Pages : 115
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Book Description
Thermodiffusion in Multicomponent Mixtures presents the computational approaches that are employed in the study of thermodiffusion in various types of mixtures, namely, hydrocarbons, polymers, water-alcohol, molten metals, and so forth. We present a detailed formalism of these methods that are based on non-equilibrium thermodynamics or algebraic correlations or principles of the artificial neural network. The book will serve as single complete reference to understand the theoretical derivations of thermodiffusion models and its application to different types of multi-component mixtures. An exhaustive discussion of these is used to give a complete perspective of the principles and the key factors that govern the thermodiffusion process.
Author: Seshasai Srinivasan
Publisher: Springer Science & Business Media
ISBN: 1461455995
Category : Science
Languages : en
Pages : 115
Get Book Here
Book Description
Thermodiffusion in Multicomponent Mixtures presents the computational approaches that are employed in the study of thermodiffusion in various types of mixtures, namely, hydrocarbons, polymers, water-alcohol, molten metals, and so forth. We present a detailed formalism of these methods that are based on non-equilibrium thermodynamics or algebraic correlations or principles of the artificial neural network. The book will serve as single complete reference to understand the theoretical derivations of thermodiffusion models and its application to different types of multi-component mixtures. An exhaustive discussion of these is used to give a complete perspective of the principles and the key factors that govern the thermodiffusion process.
Author: Abbasi Alireza
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Book Description
Author: Alireza Abbasi
Publisher:
ISBN: 9780494930847
Category :
Languages : en
Pages :
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Book Description
Author: Stefan Klackowski
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Book Description
Author: Diversos autores
Publisher: PUBLICACIONS UNIVERSITAT ROVIRA I VIRGILI
ISBN: 841365081X
Category : Science
Languages : en
Pages : 124
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Book Description
The International Meeting on Thermodiffusion provides a unique opportunity for sharing ideas about theoretical, experimental and numerical results on diffusion- and thermodiffusion related research. The successful series of IMT meetings aims to provide a forum for discussion, face-to-face interaction between scientists and technologists, and a mechanism for developing new collaborations. The IMT15 is aimed to discuss the latest results on transport properties in multicomponent fluids: innovative theoretical approaches, new experimental results and techniques as well as state of the art numerical methods. The most fundamental aspect of the conference will be the discussion amongst scientists, the sharing of ideas and creating new and reinforced existing collaborations.
Author: Simone Wiegand
Publisher: Forschungszentrum Jülich
ISBN: 3893365230
Category :
Languages : en
Pages : 319
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Book Description
Author: Kjetil Braathen Haugen
Publisher:
ISBN: 9780549066569
Category :
Languages : en
Pages : 160
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Book Description
Most naturally occurring fluids are multicomponent mixtures. Nevertheless, measured diffusion coefficients are almost exclusively for binary mixtures. Even for ternary mixtures, data is extremely limited. Molecular diffusion is fundamentally different in multicomponent than in binary mixtures due to cross molecular diffusion. All diffusion coefficients are non-trivial functions of composition, temperature, and pressure. Consequently, ternary diffusion coefficients cannot be obtained from binary data.
Author: W. Köhler
Publisher: Springer
ISBN: 3540457917
Category : Science
Languages : en
Pages : 476
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Book Description
Thermodiffusion describes the coupling between a temperature gradient and a resulting mass flux. Traditionally, the focus has been on simple fluids, and it is now extending to more complex systems such as electrolytes, polymers, colloidal dispersions and magnetic fluids. This book widens the scope even further by including applications in ionic solids. Written as a set of tutorial reviews, it will be useful to experts, nonspecialist researchers and postgraduate students alike.
Author: G. Astarita
Publisher: Elsevier
ISBN: 0444600248
Category : Science
Languages : en
Pages : 367
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Book Description
Information necessary to solve scientific or engineering problems is often so vast, that the need arises to lump information together into a more manageable subset in order to proceed. The idea of lumping is one which is used, more or less consciously, in a large variety of fields. The thermodynamics and kinetic behavior of multicomponent mixtures is an area where the requirements of lumping have been clearly identified and the techniques and results of lumping have been analyzed in considerable detail. This book comprises the proceedings of a Symposium on Kinetic and Thermodynamic Lumping of Multicomponent Mixtures which was held at the American Chemical Society Meeting in Atlanta, GA, in April 1991. Papers presented at the symposium consisted of both invited and contributed papers. Each invited paper was a review of a subfield within the landscape of the symposium while the contributed papers contain detailed analyses of specific problems. The symposium brought together active researchers in this field to report on and discuss the progress which has been made in the lumping of mixtures of very many components for a number of different applications, and to identify the important problem areas which still remain. This volume will serve both as an introduction to anyone entering the field, and as a reference work for more experienced researchers.
Author: Shu Pan
Publisher:
ISBN: 9780494393888
Category :
Languages : en
Pages : 232
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Book Description
Thermodiffusion is a mass diffusion phenomenon induced by a temperature gradient and has attracted increasing interests from theorists and experimentalists. In this work, the modelling of thermodiffusion in fluids is theoretically treated in the framework of non-equilibrium thermodynamics. The method developed in this work for thermodiffusion calculation have been incorporated into a computational fluid dynamics program to study the influence of the thermosolutal convection caused by residual gravity and g-jitter. The results have shown that the influence of microgravity environment would become stronger with an increase in the acceleration level, while at the same acceleration level, the effect would decrease at higher frequencies. For an isopropanol-water mixture under a typical microgravity condition for thermodiffusion measurement, the effect of residual gravity lower than 10--5G or the g-jitter components with an acceleration level of 10--4 G and frequencies higher than 0.0005 Hz may be negligible. The analysis in this work has indicated that under the expected microgravity environment on the International Space Station, the influence of g-jitter on the thermodiffusion measurement may be negligibly small for frequencies lower than 1 Hz. Based on four postulates in non-equilibrium thermodynamics, a non-equilibrium thermodynamic approach has been developed for thermodiffusion in associating fluid mixtures. Using the thermodynamic properties provided by the PC-SAFT Equation of State, this approach was used to evaluate the thermal diffusion factor alphaT in aqueous alkanol solutions, including methanol-water, ethanol-water and isopropanol-water mixtures. Using two adjustable parameters calculated from experimental data, the approach has shown a successful estimation of the sign change in the thermodiffusion factor for these mixtures, which was an unresolved problem in thermodiffusion research. In addition to the new model for thermodiffusion in associating mixtures, the current approaches for thermal diffusion estimation in multicomponent hydrocarbon mixtures have been evaluated by comparisons with recent experimental data. Three equations of state, including Peng-Robinson, volume translated Peng-Robinson and PC-SAFT were used in the calculation. The Firoozabadi model combined with vtPR or PC-SAFT was shown to be applicable to thermal diffusion estimation for hydrocarbon mixtures, while PC-SAFT combined with the Firoozabadi model would be a promising choice for mixtures other than hydrocarbons due to the wide applicability of PC-SAFT.
