The Polymerization of Functionalized Α-olefins Via Homogeneous Ziegler-Natta Catalysts PDF Download
Are you looking for read ebook online? Search for your book and save it on your Kindle device, PC, phones or tablets. Download The Polymerization of Functionalized Α-olefins Via Homogeneous Ziegler-Natta Catalysts PDF full book. Access full book title The Polymerization of Functionalized Α-olefins Via Homogeneous Ziegler-Natta Catalysts by Kevin Michael Stein. Download full books in PDF and EPUB format.
Author: Kevin Michael Stein
Publisher:
ISBN:
Category :
Languages : en
Pages : 300
Get Book Here
Book Description
Author: Kevin Michael Stein
Publisher:
ISBN:
Category :
Languages : en
Pages : 300
Get Book Here
Book Description
Author: T. Keii
Publisher: Elsevier
ISBN: 0080887546
Category : Technology & Engineering
Languages : en
Pages : 597
Get Book Here
Book Description
Recent development of a new generation of Ziegler-Natta Catalysts using either magnesium dichloride as carrier or methylaluminoxane as cocatalyst has markedly stimulated the research activity in the field of olefin polymerization. These discoveries have not only yielded economical processes for polyolefin production but also opened the way to a new generation of novel polymers. Moreover, the nature of active species is being clarified well by the effort to simplify catalyst systems. The present volume includes 38 papers from the 31 lectures and 18 posters presented at the symposium on `Recent Developments in Olefin Polymerization Catalysts', which covered the following topics: Overview of super-active homogeneous and heterogeneous catalysts, kinetic profile of olefin polymerization including copolymerization, characterization of catalysts and polymers, methods for the determination of active center concentration, role of Lewis bases on the catalysts isospecificity, polymerization mechanisms, and synthetic pathways for functionalized polyolefins. The contents are well balanced between fundamental research and application as well as between homogeneous and heterogeneous catalyst systems.
Author: T. Keii
Publisher: Elsevier
ISBN: 0080960596
Category : Technology & Engineering
Languages : en
Pages : 505
Get Book Here
Book Description
This book covers the proceedings of a symposium which was attended by researchers from all over the world who reported on and discussed recent advances in the field of catalytic polymerization of olefins. Over two decades have elapsed since the discovery of the Ziegler-Natta catalyst. Tremendous research effort has been aimed at improving this marvelous catalyst. In twenty-five years since the first publication, more than 15,000 papers and patents on the subject and on related subjects have appeared. This effort has yielded new generations of Ziegler-Natta catalysts with superior activity and stereospecificity. The complexities arising from the heterogeneity of the catalyst, however, have hindered understanding of the catalytic processes which take place on the catalyst surface. Nevertheless, many fundamental features of the catalyst system have now been clarified reasonably well. Recently a highly active homogeneous catalytic system has been developed, which is capable of catalyzing even isotactic polymerization of propene. There is no doubt that this finding will not only contribute to our understanding of the detailed mechanism of polymerization but also stimulate the development of various kinds of tailored polymers. Thus this subject will remain of paramount importance in the development of chemistry and polymer science for a long time to come.
Author: Y.V. Kissin
Publisher: Springer Science & Business Media
ISBN: 1461250846
Category : Science
Languages : en
Pages : 450
Get Book Here
Book Description
The discoveries of organometallic catalysts for olefin polymerization by Karl Ziegler and that of stereoregular olefin polymers by Giulio Natta are probably the two most important achievements in the areas of catalysis and polymer chemistry in the second half of this century. They led to the development of a new branch of chemical industry, and to a large volume production of high-density and linear low-density polyethylene, isotactic polypropylene, ethylene-propylene rubbers, isotactic poly I-butene, and poly-4-methyl-l-pentene. These discoveries merited the Nobel prize, which was awarded to K. Ziegler and G. Natta in 1963. The initial works of Ziegler and Natta were followed by an "explosion" of scientific papers and patents covering all aspects of polymerization chemistry, catalyst synthesis, and polymerization kinetics as well as the structural, chemical, physical, and technological characteristics of stereo regular polyolefins, polydienes, and olefin copolymers. It is sufficient to say that in the twenty-five years after the first publications more than 15,000 papers and patents appeared on subjects related to the area. . The development brought about the establishment of several prominent groups of scientists occupied with the study of olefin polymerization. The most important of these were scientific schools in Italy, Germany, England, the United States, Japan, the Soviet Union, Czechoslovakia, and Venezuela. In addition, many major chemical and petrochemical corporations throughout the world established labora tories devoted to the development of the technology of catalyst synthesis and olefin polymerization.
![Dynamic Mathematical Modelling of Polymerization of Olefins Using Heterogeneous and Homogeneous Ziegler-Natta Catalysts [microform] PDF](https://books.google.com/books/content/images/frontcover/dKXbGwAACAAJ?fife=w80-h100)
Author: João B. P. Soares
Publisher: National Library of Canada = Bibliothèque nationale du Canada
ISBN: 9780612026087
Category : Polymerization
Languages : en
Pages : 349
Get Book Here
Book Description
Author: Tominaga Keii
Publisher:
ISBN: 9780444418012
Category : Alkenes
Languages : en
Pages :
Get Book Here
Book Description
This book covers the proceedings of a symposium which was attended by researchers from all over the world who reported on and discussed recent advances in the field of catalytic polymerization of olefins. Over two decades have elapsed since the discovery of the Ziegler-Natta catalyst. Tremendous research effort has been aimed at improving this marvelous catalyst. In twenty-five years since the first publication, more than 15,000 papers and patents on the subject and on related subjects have appeared. This effort has yielded new generations of Ziegler-Natta catalysts with superior activity and stereospecificity. The complexities arising from the heterogeneity of the catalyst, however, have hindered understanding of the catalytic processes which take place on the catalyst surface. Nevertheless, many fundamental features of the catalyst system have now been clarified reasonably well. Recently a highly active homogeneous catalytic system has been developed, which is capable of catalyzing even isotactic polymerization of propene. There is no doubt that this finding will not only contribute to our understanding of the detailed mechanism of polymerization but also stimulate the development of various kinds of tailored polymers. Thus this subject will remain of paramount importance in the development of chemistry and polymer science for a long time to come
Author: Andrew Leland McKnight
Publisher:
ISBN:
Category :
Languages : en
Pages : 328
Get Book Here
Book Description
Author: Giuliano Giambastiani
Publisher: Springer Science & Business Media
ISBN: 9048138159
Category : Science
Languages : en
Pages : 296
Get Book Here
Book Description
This book highlights key advances that have occurred in the field of olefin conversion in recent years. The role of homogenous transition metal catalysts which contain an imine functionality is emphasized; their potential applications in the processing and upgrade of olefins to a wide variety of commodity products of very high industrial value is also explored. On the threshold of the fiftieth anniversary of the Noble Prize to Ziegler and Natta, this book gives a critical summary of the state of the art developments in the fascinating and rapidly developing field of the olefin polymerization, oligomerization, and co-polymerization catalysis.
Author: Todd Ross Younkin
Publisher:
ISBN:
Category : Electronic dissertations
Languages : en
Pages : 780
Get Book Here
Book Description
Author: Tominaga Keii
Publisher:
ISBN: 9784062022651
Category : Alkenes
Languages : en
Pages : 489
Get Book Here
Book Description
