The Peierls Ground State, Solitons and Polarons in Ring-Containing Polymers PDF Download
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Category :
Languages : en
Pages : 12
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Book Description
The report of doping of polyacetylene to form a highly conducting polymer opened the question concerning the nature of the electronic states of the polymer backbone that are formed upon charge transfer between the polymer and dopant backbone. Extensive study of polyacetylene has demonstrated that this system is a degenerate Peierls semiconductor with a bandgap introduced through bond alternation. Pernigraniline is a semiconductor analogous to trans- polyacetylene. However, it differs from polyacetylene in that the overlap between adjacent sites can be modulated by both changes in bond length and changes in ring torsion angle. It is shown that as a result of these two independent order parameters there are differing types of charge excitation possible on pernigraniline backbone, with both bond order excitations such as bond order solitons and ring torsion excitations such as ring torsion polarons possible. Recent photoexcitation spectroscopy studies have confirmed the presence of both bond order solitons and ring rotation polarons.
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Category :
Languages : en
Pages : 12
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Book Description
The report of doping of polyacetylene to form a highly conducting polymer opened the question concerning the nature of the electronic states of the polymer backbone that are formed upon charge transfer between the polymer and dopant backbone. Extensive study of polyacetylene has demonstrated that this system is a degenerate Peierls semiconductor with a bandgap introduced through bond alternation. Pernigraniline is a semiconductor analogous to trans- polyacetylene. However, it differs from polyacetylene in that the overlap between adjacent sites can be modulated by both changes in bond length and changes in ring torsion angle. It is shown that as a result of these two independent order parameters there are differing types of charge excitation possible on pernigraniline backbone, with both bond order excitations such as bond order solitons and ring torsion excitations such as ring torsion polarons possible. Recent photoexcitation spectroscopy studies have confirmed the presence of both bond order solitons and ring rotation polarons.
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ISBN:
Category : Aeronautics
Languages : en
Pages : 484
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Book Description
Author: Lu Yu
Publisher: World Scientific
ISBN: 9789971500542
Category : Science
Languages : en
Pages : 774
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Book Description
Polyacetylence, (CH)x is the simplest conjugated polymer. Prestine polyacetylence is a good insulator, whereas its highly doped version exhibits metal-like electrical conductivity. This book gives a detailed introduction to this rapidly-developing field is given along with a collection of original papers. The main purpose is to help chemists and physicists grasp the main ideas and most important facts; an expert may also find it useful as a reference volume.
Author: Lu Yu
Publisher: World Scientific
ISBN: 981459685X
Category : Science
Languages : en
Pages : 772
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Book Description
Polyacetylence, (CH)x is the simplest conjugated polymer. Prestine polyacetylence is a good insulator, whereas its highly doped version exhibits metal-like electrical conductivity. This book gives a detailed introduction to this rapidly-developing field is given along with a collection of original papers. The main purpose is to help chemists and physicists grasp the main ideas and most important facts; an expert may also find it useful as a reference volume.
Author: W. R. Salaneck
Publisher: Oxford University Press, USA
ISBN:
Category : History
Languages : en
Pages : 526
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Book Description
The results of a Nobel Symposium on conducting polymers are presented in this volume, which explores the state of the art in electrically conducting organic polymer materials.
Author: Tetsuo Ogawa
Publisher: World Scientific
ISBN: 9814497754
Category : Science
Languages : en
Pages : 470
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Book Description
This book surveys recent theoretical and experimental studies of optical properties of low-dimensional materials. As an extended version of Optical Properties of Low-Dimensional Materials (Volume 1, published in 1995 by World Scientific), Volume 2 covers a wide range of interesting low-dimensional materials including both inorganic and organic systems, such as disordered polymers, deformable molecular crystals, dilute magnetic semiconductors, SiGe/Si short-period superlattices, GaAs quantum wires, semiconductor microcavities, and photonic crystals. There are excellent review articles by promising researchers in each field. All the materials introduced in this book yield new optical phenomena originating from their mesoscopic and low-dimensional electronic characters and electron-lattice couplings, which offer a new research field of materials science as well as condensed-matter and optical physics. Volumes 1 and 2 are interrelated but can be read independently. They are pitched at the level of graduate students and are useful to both students and scientists.
Author: Tetsuo Ogawa
Publisher: World Scientific
ISBN: 9789810230487
Category : Science
Languages : en
Pages : 478
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Book Description
This book surveys recent theoretical and experimental studies of optical properties of low-dimensional materials. As an extended version of Optical Properties of Low-Dimensional Materials (Volume 1, published in 1995 by World Scientific), Volume 2 covers a wide range of interesting low-dimensional materials including both inorganic and organic systems, such as disordered polymers, deformable molecular crystals, dilute magnetic semiconductors, SiGe/Si short-period superlattices, GaAs quantum wires, semiconductor microcavities, and photonic crystals. There are excellent review articles by promising researchers in each field. All the materials introduced in this book yield new optical phenomena originating from their mesoscopic and low-dimensional electronic characters and electron-lattice couplings, which offer a new research field of materials science as well as condensed-matter and optical physics. Volumes 1 and 2 are interrelated but can be read independently. They are pitched at the level of graduate students and are useful to both students and scientists.
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Publisher:
ISBN:
Category : Physics
Languages : en
Pages : 634
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Book Description
General physics, atomic physics, molecular physics, and solid state physics.
Author: Anna Köhler
Publisher: John Wiley & Sons
ISBN: 3527685146
Category : Technology & Engineering
Languages : en
Pages : 424
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Book Description
The first advanced textbook to provide a useful introduction in a brief, coherent and comprehensive way, with a focus on the fundamentals. After having read this book, students will be prepared to understand any of the many multi-authored books available in this field that discuss a particular aspect in more detail, and should also benefit from any of the textbooks in photochemistry or spectroscopy that concentrate on a particular mechanism. Based on a successful and well-proven lecture course given by one of the authors for many years, the book is clearly structured into four sections: electronic structure of organic semiconductors, charged and excited states in organic semiconductors, electronic and optical properties of organic semiconductors, and fundamentals of organic semiconductor devices.
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ISBN:
Category : Government reports announcements & index
Languages : en
Pages : 1400
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Book Description
