Synthetic, Spectroscopic and Mechanistic Studies of Some Organometallic Derivatives of the Platinum Group PDF Download
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Author: David Thomas Hardy
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Languages : en
Pages :
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Author: David Thomas Hardy
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Languages : en
Pages :
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Author: Ewan Blyth McAslan
Publisher:
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Category : Complex compounds
Languages : en
Pages :
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Author: Ewan Blyth McAslan
Publisher:
ISBN:
Category : Complex compounds
Languages : en
Pages : 0
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Author:
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ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 140
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Category : Dissertation abstracts
Languages : en
Pages : 724
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Author: Alan Bright
Publisher:
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Category :
Languages : en
Pages :
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Author: Y.Z. Voloshin
Publisher: Elsevier
ISBN: 0080529178
Category : Science
Languages : en
Pages : 433
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Clathrochelates are compounds which contain a metal ion encapsulated within a three dimensional cage of macrobicyclic ligand atoms. Within this cage the metal has unique properties and is to a great extent isolated from environmental factors. Such complexes are suitable as models of the most essential biological systems, membrane transport, electron carriers, highly selective and sensitive analytical reagents, catalysts for photochemical and redox processes, cation and anion receptors, etc. The aim of this monograph is to generalize and analyze experimental and theoretical data on clathrochelates in order to promote further research in this promising field of chemistry.Chapter 1 gives general concepts of complexes with encapsulated metal ions, discusses basic specific features of these compounds, considers and characterizes the main types of compounds with encapsulated metal ions and the main classes of clathrochelates, and includes the current nomenclature. Chapter 2 deals with the pathways of clathrochelate synthesis and the general procedures for the synthesis of macrobicyclic tris-dioximates, phosphorus-containing tris-diiminates, sepulchrates, sarcophagi-nates, and polyene and other types of clathrochelate complexes. Chapter 3 concerns studies of the electronic and spatial structure of clathrochelate complexes. In Chapter 4, the kinetics and mechanism of synthesis and decomposition reactions of macrobicyclic tris-dioximates, sarcophaginates, and sepulchrates in solution and gas phases are discussed. Chapter 5 considers the electrochemical, photochemical, and some other characteristics of clathrochelates and their applications associated with these characteristics. Finally, the practical applications of the unique properties of clathrochelates and perspectives on the synthesis of new clathrochelates are described in Chapters 6 and 7, respectively.
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Category : Dissertations, Academic
Languages : en
Pages : 712
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Author: Hannah Gay
Publisher: World Scientific
ISBN: 1783269758
Category : Science
Languages : en
Pages : 582
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This is the first comprehensive history of the chemistry department at Imperial College London. Based on archival records, oral testimony, published papers, published and unpublished memoirs, the book tells the story of this world-famous department from its foundation as the Royal College of Chemistry in 1845 to the large department it had become by the year 2000.The book covers research, teaching, departmental governance, students and social life. It also highlights the extraordinary contributions made to the war effort in both the first and second world wars. From its first professors, A. Wilhelm Hofmann and Edward Frankland, the department has been home to many eminent chemists, including, in the later twentieth century, the Nobel laureates Derek Barton and Geoffrey Wilkinson. New information on these and many others is presented in a lively narrative that places both people and events in the larger historical contexts of chemistry, politics, culture and the economy. The book will interest not only those connected with Imperial College, but anyone interested in chemistry and its history, or in higher
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Category : Dissertations, Academic
Languages : en
Pages : 760
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