Synthesis, Structure and Properties of Carboxylate Coordination Polymers PDF Download
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Author: Rebecca Clulow
Publisher:
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Languages : en
Pages :
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Author: Rebecca Clulow
Publisher:
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Category :
Languages : en
Pages :
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Author: 張妙寧
Publisher:
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Category :
Languages : en
Pages :
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Author: Matthew Hurlock
Publisher:
ISBN:
Category : Coordination polymers
Languages : en
Pages : 0
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Book Description
Important issues such as the capture of greenhouse gases, the detection of hazardous chemicals, and the storage of energy require materials with tunable properties. Coordination polymers are a type of hybrid polymeric crystalline material formed from the connection of organic ligands and metal ions or clusters through coordination bonds. The wide array of building blocks that can be used enables coordination polymers to be rationally designed and tuned to possess specific properties. Amongst coordination polymers, Metal-Organic Frameworks (MOFs) stand out due to their porosity, large internal surface areas, and diversity of structures. These features can be achieved through direct synthesis as well as through directed modification of the framework post-synthetically. The study of the structures of MOFs and how they relate to the properties of the material, such as luminescence, is important to help gain a deeper understanding and to facilitate the development of new materials with desired functionality. Luminescent MOFs are of particular interest due to their potential as selective chemical sensors. Ligand-based fluorescence is one of the most common forms of luminescence in MOFs. Ligands built from the molecule tetraphenylethene (TPE) are ideal candidates for these systems. The aggregation-induced emission properties of TPE molecules can be enhanced through rigidification within a coordination network. This work seeks to further understand how the structures of TPE MOFs relate to the properties of the framework. To accomplish this, a variety of new coordination polymers were synthesized using TPE ligands with carboxylate functionalization at the para- and meta-positions. The fluorescent properties of coordination polymers constructed from para-functionalized TPE ligands was controlled through post-synthetic insertion of additional ligands. Coordination polymers formed from meta-functionalized TPE ligands tended to form dense, non-porous structures but the properties of these materials could be controlled through mixed ligand synthesis. This approach allowed for the control of the fluorescence emission as well as the porosity of the frameworks. Through this work, a better understanding of how TPE ligands and their conformations influence the structure and properties of coordination polymers is gained, which will aid in the rational design of these types of materials.
Author: Ali Morsali
Publisher: John Wiley & Sons
ISBN: 1119370752
Category : Science
Languages : en
Pages : 262
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Book Description
Coordination polymer is a general term used to indicate an infinite array composed of metal ions which are bridged by certain ligands among them. This incorporates a wide range of architectures including simple one-dimensional chains with small ligands to large mesoporous frameworks. Generally, the formation process proceeds automatically and, therefore, is called a self-assembly process. In general, the type and topology of the product generated from the self-assembly of inorganic metal nodes and organic spacers depend on the functionality of the ligand and valences and the geometric needs of the metal ions used. In this book the authors explain main group metal coordination polymer in bulk and nano size with some of their application, synthesis method and etc, The properties of these efficient materials are described at length including magnetism (long-range ordering, spin crossover), porosity (gas storage, ion and guest exchange), non-linear optical activity, chiral networks, reactive networks, heterogeneous catalysis, luminescence, multifunctional materials and other properties.
Author: George E. Kostakis
Publisher: MDPI
ISBN: 3038428019
Category : Science
Languages : en
Pages : 131
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Book Description
This book is a printed edition of the Special Issue "Structural Design and Properties of Coordination Polymers" that was published in Crystals
Author: Maged S. Al-Fakeh
Publisher: LAP Lambert Academic Publishing
ISBN: 9783846521311
Category :
Languages : en
Pages : 300
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Book Description
1,4-Benzenedicarboxylate(BDC), 1,1'-ferrocenedicarboxylate(FDC) and their metal complexes are of considerable interest due to their chemical and biological importance. Thiazoles represent a very interesting class of compounds because of their pharmaceutical, analytical and industrial applications. The aim of this work is therefore to synthesize and characterize a series of transition and non-transition metal coordination polymers derived from 1,4-benzenedicarboxylate and / or 1,1'-ferrocenedicarboxylate and thiazoles, to explore their structures and biological activities. A study of the thermal behaviour of these complexes is important to elucidate the kinetic and mechanistic aspects of their thermolysis as well as their stabilities. It is also aimed to study the voltammetric behaviour of these complexes to gain more understanding about the chemistry of these compounds.
Author: 陳冠廷
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Author: Stuart R. Batten
Publisher: Royal Society of Chemistry
ISBN: 0854048375
Category : Science
Languages : en
Pages : 440
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Book Description
The field of coordination polymer research is now vast, & one of the fastest growing areas of chemistry in recent times, with important work being done on a variety of different aspects. This book provides a broad overview of all the major facets of modern coordination polymer science in the one place.
Author: B.I. Kharisov
Publisher: Elsevier
ISBN: 0128110627
Category : Science
Languages : en
Pages : 470
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Book Description
Direct Synthesis of Metal Complexes provides in-depth coverage of the direct synthesis of coordination and organometallic compounds. The work is primarily organized by methods, but also covers highly relevant complexes, such as metal-polymer coordination compounds. This updated reference discusses recent developments in cryosynthesis, electrosynthesis, and tribosynthesis (popular as it doesn’t require organic solvents), with special attention paid to ‘greener’ methodologies and approaches. Additionally, the book describes physical methods of zero-valent metal interaction with organic matter, including sputtering, ultrasonic treatment and synthesis in ionic liquids. The book presents completely new content as a follow-up to the 1999 Elsevier Science publication Direct Synthesis of Coordination and Organometallic Compounds that was edited by Dr. Garnovskii and Dr. Kharisov. Covers current methods and techniques of metal interactions with organic media leading to metal chelates, adducts, di- and polymetallic complexes, metal-containing macrocycles, supported coordination compounds (i.e., metal complexes on carbon nanotubes), and more Describes reactivities of distinct forms of elemental metals (powders, sheets, nanoparticles (including a host of less-common metal nanostructures) with organic phase (liquid, solid and gaseous) and water Includes experimental procedures, with examples of direct synthesis, at the end of each chapter
Author: J. A. McCleverty
Publisher: Elsevier Science
ISBN: 9780080437484
Category : Science
Languages : en
Pages : 880
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Book Description
Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.
