Synthesis, Characterization, and Reactivity Studies of Iridium Complexes Bearing the Ligand Diphenylphosphidoboratabenzene

Synthesis, Characterization, and Reactivity Studies of Iridium Complexes Bearing the Ligand Diphenylphosphidoboratabenzene PDF Author: Luis Alfredo Arizpe
Publisher:
ISBN:
Category :
Languages : en
Pages : 60

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Book Description
The synthesis, structure, and reactivity properties of three iridium square planar complexes bearing the anionic phosphine ligand diphenylphosphidoboratabenzene (DPB) are described. Reactivity studies show a rate enhancement for the oxidative addition of a substituted benzyl bromide and Me3SnBr with DPB as a ligand in place of triphenylphosphine. Two products from the oxidative addition of p-chlorobenzyl bromide have been isolated and structurally characterized.

Synthesis, Characterization, and Reactivity Studies of Iridium Complexes Bearing the Ligand Diphenylphosphidoboratabenzene

Synthesis, Characterization, and Reactivity Studies of Iridium Complexes Bearing the Ligand Diphenylphosphidoboratabenzene PDF Author: Luis Alfredo Arizpe
Publisher:
ISBN:
Category :
Languages : en
Pages : 60

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Book Description
The synthesis, structure, and reactivity properties of three iridium square planar complexes bearing the anionic phosphine ligand diphenylphosphidoboratabenzene (DPB) are described. Reactivity studies show a rate enhancement for the oxidative addition of a substituted benzyl bromide and Me3SnBr with DPB as a ligand in place of triphenylphosphine. Two products from the oxidative addition of p-chlorobenzyl bromide have been isolated and structurally characterized.

Synthesis and Reactivity Studies of Iridium Complexes with Tridentate Ligands

Synthesis and Reactivity Studies of Iridium Complexes with Tridentate Ligands PDF Author: Sara K. Buzak
Publisher:
ISBN:
Category : Iridium catalysts
Languages : en
Pages : 100

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Book Description


Syntheses, Characterization, and Reactivity Studies of Iridium(III)-hydride and Iridium(I) Complexes with Tertiary Triphosphine Ligands

Syntheses, Characterization, and Reactivity Studies of Iridium(III)-hydride and Iridium(I) Complexes with Tertiary Triphosphine Ligands PDF Author: Chihae Yang
Publisher:
ISBN:
Category : Iridium
Languages : en
Pages : 502

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Book Description


Selectivities in Lewis Acid Promoted Reactions

Selectivities in Lewis Acid Promoted Reactions PDF Author: Dieter Schinzer
Publisher: Springer Science & Business Media
ISBN: 940092464X
Category : Science
Languages : en
Pages : 326

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Book Description
The ASI workshop on "Selectivities in Lewis Acid Promoted Reactions" held in the Emmantina-Hotel in Athens-Glyfada, Greece, October 2-7, 1988 was held to bring some light into the darkness of Lewis acid induced processes. As such the workshop reflects some current trends in organic synthesis, where Lewis acids are becoming a powerful tool in many different modern reactions, e.g. Diels-Alder reactions, Ene reactions, Sakurai reactions, and in general silicon and tin chemistry. The objective of this meeting was to bring together most of the world experts in the field to discuss the major reactions promoted by Lewis acids. Organic synthesis will play a major role in this book connected with some fundamental mechanistic work on allylsilane and -tin chemistry. Both natural product synthesis and unnatural molecules are presented in the chapters. The book presents all the 15 invited lectures and the contributions of 15 posters. I am confident that the material presented in this book will stimulate the chemistry, which has been discussed on our meeting, around the world. The meeting and the book were only possible through a grant of the NATO Scientific Affairs Devision and financial support by the following companies: Kali Chemie (Hannover, W-Germany), E. Merck (Darmstadt, W-Germany), Sandoz (Basel, Switzerland), Schering (Berlin, W-Germany).