Author: Michelle Royster Dial
Publisher:
ISBN:
Category : Cobalt
Languages : en
Pages : 304
Book Description
Synthesis, Characterization and Reactivity of Novel Trinuclear Organometallic Cluster Complexes of Iridium, Rhodium, and Cobalt
Iridium Complexes in Organic Synthesis
Author: Luis A. Oro
Publisher: John Wiley & Sons
ISBN: 3527623086
Category : Science
Languages : en
Pages : 424
Book Description
Ranging from hydrogenation to hydroamination, cycloadditions and nanoparticles, this first handbook to comprehensively cover the topic of iridium in synthesis discusses the important advances in iridium-catalyzed reactions, namely the use of iridium complexes in enantioselective catalysis. A must for organic, complex and catalytic chemists, as well as those working with/on organometallics.
Publisher: John Wiley & Sons
ISBN: 3527623086
Category : Science
Languages : en
Pages : 424
Book Description
Ranging from hydrogenation to hydroamination, cycloadditions and nanoparticles, this first handbook to comprehensively cover the topic of iridium in synthesis discusses the important advances in iridium-catalyzed reactions, namely the use of iridium complexes in enantioselective catalysis. A must for organic, complex and catalytic chemists, as well as those working with/on organometallics.
Synthesis, Characterization and Reactivity of Rhodium- and Iridium-iminophosphorane Complexes
Author: Pieter Imhof
Publisher:
ISBN:
Category :
Languages : en
Pages : 153
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 153
Book Description
Synthesis and Characterization of Some Novel Iridium-, Iron-, and Cobalt-monocarborane Complexes
Author: Robin A. McCown
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
Reaction of the fragments {Ir(PEt3)n}+ with the monocarborane anion [closo-1-CB7H8]- causes an oxidative insertion to occur, and the iridium moiety to become a cluster vertex. This reaction provides two distinct, neutral, 9-vertex {IrCB7} products, depending on the ratio of iridium and phosphine reactants used. The iridium centers in these products have differing oxidation states, illustrating the exceptional ability of the smaller anionic monocarborane ligands to stabilize metals in higher oxidation states. Although salts of the 11-vertex anionic species [1,1,1-(CO)3-closo-1,2-FeCB9H10]- have resisted synthesis in the past, its analogue [1,1,1-(CO)3-2-Ph-closo-1,2-FeCB9H9]- has now been prepared. Moreover, two reactions demonstrating the derivative chemistry of this compound have been discovered. Previously, 10- and 12-vertex dicobalt monocarboranes were prepared and studied by treating monocarboranes with [Co2(CO)8]. This produced several poly-cobalt anions. New derivatives of these anions have been synthesized, using protocols developed since their discovery.
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
Reaction of the fragments {Ir(PEt3)n}+ with the monocarborane anion [closo-1-CB7H8]- causes an oxidative insertion to occur, and the iridium moiety to become a cluster vertex. This reaction provides two distinct, neutral, 9-vertex {IrCB7} products, depending on the ratio of iridium and phosphine reactants used. The iridium centers in these products have differing oxidation states, illustrating the exceptional ability of the smaller anionic monocarborane ligands to stabilize metals in higher oxidation states. Although salts of the 11-vertex anionic species [1,1,1-(CO)3-closo-1,2-FeCB9H10]- have resisted synthesis in the past, its analogue [1,1,1-(CO)3-2-Ph-closo-1,2-FeCB9H9]- has now been prepared. Moreover, two reactions demonstrating the derivative chemistry of this compound have been discovered. Previously, 10- and 12-vertex dicobalt monocarboranes were prepared and studied by treating monocarboranes with [Co2(CO)8]. This produced several poly-cobalt anions. New derivatives of these anions have been synthesized, using protocols developed since their discovery.
Water-soluble Iridium and Rhodium Complexes
Author: Julia Knapp
Publisher:
ISBN:
Category : Iridium compounds
Languages : en
Pages : 61
Book Description
Publisher:
ISBN:
Category : Iridium compounds
Languages : en
Pages : 61
Book Description
Synthesis and Reactions of Cobalt and Rhodium Organometallic Complexes
Author: Jennifer Susan Protopopoff
Publisher:
ISBN:
Category : Organocobalt compounds
Languages : en
Pages :
Book Description
Publisher:
ISBN:
Category : Organocobalt compounds
Languages : en
Pages :
Book Description
Synthesis, Characterization and Reactivity of Electron Rich Transition Metal Organometallic Complexes
Author: James Joseph Welter
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
Synthesis and Reactivity of Organometallic Complexes of Iridium and Iron in Aqueous and Basic Media
Author: Michael S. Webster-Gardiner
Publisher:
ISBN:
Category : Chemical reaction, Conditions and laws of
Languages : en
Pages : 64
Book Description
Publisher:
ISBN:
Category : Chemical reaction, Conditions and laws of
Languages : en
Pages : 64
Book Description
Organo-iridium Compounds
Author: Joy Faith Frazier
Publisher:
ISBN:
Category : Organometallic compounds
Languages : en
Pages : 174
Book Description
Publisher:
ISBN:
Category : Organometallic compounds
Languages : en
Pages : 174
Book Description
Tris(guanidinato) Complexes of Iridium and Rhodium in the Oxidation States +III and +IV
Author: Wei-Tsung Lee
Publisher:
ISBN:
Category : Guanidines
Languages : en
Pages : 144
Book Description
Chemical oxidation by [FeCp2]PF6 afforded thermally unstable, paramagnetic Rh IV compounds, [Rh{ArNC(NR 2)NAr} 3]PF6, which were characterized by mass spectrometry and electronic absorption spectroscopy. Furthermore, two FeII complexes of tetradentate tripodal ligands, [Fe(L1)(OTf) 2] and [Fe(L2)(OTf) 2]; where L1 = N, N-bis(2-benzimidazolylmethyl)-N-(2-pyridylmethyl) amine and L2 = N, N-bis[(1-methylbenzimidazol-2-yl)methyl]-N-[(pyridin-2-yl)methyl] amine; were synthesized and characterized. The 1 H NMR spectra for [Fe(L1)(NCMe) 2](OTf) 2 and [Fe(L2)(NCMe) 2](OTf) 2 in CD3 CN solution at ambient temperature exhibit paramagnetically shifted peaks typical of high-spin FeII complexes, while variable-temperature 1 H NMR spectroscopy showed that the Fe center in [Fe(L1)(NCMe) 2](OTf) 2 is in a spin equilibrium and that in [Fe(L2)(NCMe) 2](OTf) 2 in the high-spin state (at 25° C). Highly reactive oxoiron(IV) complexes were obtained by reaction of the FeII complexes with an excess of m-CPBA at -40° C.
Publisher:
ISBN:
Category : Guanidines
Languages : en
Pages : 144
Book Description
Chemical oxidation by [FeCp2]PF6 afforded thermally unstable, paramagnetic Rh IV compounds, [Rh{ArNC(NR 2)NAr} 3]PF6, which were characterized by mass spectrometry and electronic absorption spectroscopy. Furthermore, two FeII complexes of tetradentate tripodal ligands, [Fe(L1)(OTf) 2] and [Fe(L2)(OTf) 2]; where L1 = N, N-bis(2-benzimidazolylmethyl)-N-(2-pyridylmethyl) amine and L2 = N, N-bis[(1-methylbenzimidazol-2-yl)methyl]-N-[(pyridin-2-yl)methyl] amine; were synthesized and characterized. The 1 H NMR spectra for [Fe(L1)(NCMe) 2](OTf) 2 and [Fe(L2)(NCMe) 2](OTf) 2 in CD3 CN solution at ambient temperature exhibit paramagnetically shifted peaks typical of high-spin FeII complexes, while variable-temperature 1 H NMR spectroscopy showed that the Fe center in [Fe(L1)(NCMe) 2](OTf) 2 is in a spin equilibrium and that in [Fe(L2)(NCMe) 2](OTf) 2 in the high-spin state (at 25° C). Highly reactive oxoiron(IV) complexes were obtained by reaction of the FeII complexes with an excess of m-CPBA at -40° C.