Synthesis, Characterization and Reactivity of Electron Rich Transition Metal Organometallic Complexes PDF Download
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Author: James Joseph Welter
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Author: James Joseph Welter
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Author: John C. Linehan
Publisher:
ISBN:
Category :
Languages : en
Pages : 514
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Book Description
Author: Dakeshwar Kumar Verma
Publisher: John Wiley & Sons
ISBN: 3527351787
Category : Science
Languages : en
Pages : 453
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Book Description
Organometallic Compounds An up-to-date overview of the fundamentals, synthesis, and applications of organometallic compounds Organometallic Compounds: Synthesis, Reactions, and Applications delivers an accessible and robust introduction to the fundamentals of organometallic compounds, including their reactions, catalytic mechanisms, and modern applications, including carbon-dioxide fixation, reduction, gas adsorption and purification, drug delivery, renewable energy, and wastewater treatment. The book also covers toxicological and computational studies. The authors address the current challenges confronting researchers seeking to sustainably synthesize and process organometallic compounds and offer complete coverage on the most recent advancements in applications relating to the fields of environmental science, electronics, fossil fuels, and more. Readers will also find: Introduces to fundamentals, nomenclature, properties, and classification of organometallic compounds Discusses methods of synthesis of organometallic compounds Practical discussions of organometallic complexes of the lanthanoids and actinoids, as well as bio-organometallic chemistry Includes characterization techniques of organometallic compounds Perfect for organic, environmental, inorganic, water, and catalytic chemists, Organometallic Compounds: Synthesis, Reactions, and Applications will also benefit chemical engineers and industrial chemists.
Author: Roland Malcolm Charles III
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
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Book Description
The investigation and development of heterobimetallic systems has seen a meteoric surge over the past decade. Generally, these heterobimetallic systems involve two transition metals with distinct properties used together to activate chemical bonds. Many heterobimetallics consist of a soft, low-valent metal and a harder, high-valent metal. The unique electronics afforded by heterobimetallics of this sort can be exploited, yielding access to novel reactivities that may be otherwise inaccessible to a single transition metal. Less studied are heterobimetallic complexes composed of one late transition metal (LTM) and one Lewis-acidic p-block (Group 13) metal. Due to its electropositivity being the highest among Group 13 metals as well as its high earth-abundance, aluminum holds particular interest to the Brewster laboratory. In contrast to their exhaustively investigated boron analogues, the field of aluminum-containing heterobimetallics is relatively uncultivated due to the high reactivity and synthetic difficulty of aluminum species, making isolation and characterization quite challenging. One of the aims of the Brewster lab is to develop heterobimetallic systems comprised of an electron-rich, low-valent transition metal and aluminum to investigate potential synergistic reactivity between both metal centers. In this dissertation, I report the successful synthesis and electronic characterization of myriad novel mono- and heterobimetallic complexes of either iridium or rhodium and aluminumover 35 new complexes in total. Moreover, I detail the ability of selected heterobimetallic complexes to facilitate activation of molecular hydrogen as well as hydrogenolysis, thereby generating alkane gas..
Author: Louis S. Hegedus
Publisher: University Science Books
ISBN: 9781891389047
Category : Science
Languages : en
Pages : 358
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Book Description
This second edition offers easy access to the field of organotransition metal chemistry. The book covers the basics of transition metal chemistry, giving a practical introduction to organotransition reaction mechanisms.
Author: David Morris Hamilton
Publisher:
ISBN:
Category :
Languages : en
Pages : 206
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Author: Robert H. Crabtree
Publisher: Wiley-Interscience
ISBN:
Category : Science
Languages : en
Pages : 520
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Book Description
Later chapters discuss applications of organometallics such as: catalytic uses of transition metals; activation of small molecules; applications to organic synthesis; and carbenes, metathesis, and polymerization. Also discussed are the role of organometallics in biochemical areas, clusters, metal-metal bonds, and high-oxidation-state complexes.
Author: Lori Anne Watson
Publisher:
ISBN:
Category :
Languages : en
Pages : 504
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Book Description
Author: S. G. Davies
Publisher: Elsevier
ISBN: 1483285847
Category : Science
Languages : en
Pages : 430
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Book Description
Although organotransition metal chemistry has been developing rapidly over the past 20 years, it is only recently that applications of transition metal complexes to organic synthesis have started to be exploited. This unique book provides an introduction to organometallic chemistry for chemists who have little or no experience in the field, describes the work that has already been done using organotransition metal complexes for synthesis, and indicates to organic and organometallic chemists the type of synthetic problems that can be solved using organometallic compounds. It covers all major advances that have been made in this rapidly expanding area of chemistry, including not only reactions that already have well established applications for synthesis but also many recently discovered potentially useful reactions, providing a survey of recent literature.
Author: Priyabrata Ghana
Publisher: Springer
ISBN: 9783030026240
Category : Science
Languages : en
Pages : 345
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Book Description
This book explores the development of the first open-shell heavier tetrylidyne complexes featuring a tetrel-centered unpaired electron, and unprecedented metallatetrylidynes containing a multiply-bonded, linear-coordinated single heavier tetrel atom embedded between two metal centers. The chemistry of compounds featuring triple bonds of the heavier Group-14 elements Si–Pb with transition metals is a very challenging research area, which combines modern molecular main-group element with transition-metal chemistry, and is of fundamental importance for the understanding of chemical bonding. During the last 15 years, the research in this area has witnessed considerable progress in isolating a series of closed-shell tetrylidyne complexes. However, despite numerous attempts, open-shell tetrylidyne complexes and heavier group 14 element congeners of metallacarbynes and carbide complexes remained inaccessible. In this book, readers will find more about the reactivity studies of these novel complexes that uncovered a plethora of exceptional products, including a novel m3-silicido complex, the first dimetallasilacumulene with a linear, two-coordinated single silicon atom and the first compounds of planar tetracoordinated silicon (ptSi) (Anti-van’t Hoff-Le Bell Silicon). Readers will also learn about the isolation and full characterization of the first room-temperature stable disilavinylidene, a silicon analogue of the very reactive vinylidenes (R2C=C:), and the first intermetallic plumbylidyne ligand transfer reactions.
