Author: Justin McMain
Publisher:
ISBN:
Category :
Languages : en
Pages : 19
Book Description
Synthesis and Characterization of Ruthenium(II) Phosphine Azide Complexes
Author: Justin McMain
Publisher:
ISBN:
Category :
Languages : en
Pages : 19
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 19
Book Description
Synthesis, Characterization and Catalytic Application of Polysiloxane- and Poly(alumosiloxane)-bound (ether- Phosphine)ruthenium(II) Complexes
Author: Andreas Jäger
Publisher:
ISBN:
Category :
Languages : en
Pages : 112
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 112
Book Description
Synthesis and Characterization of Bis-phosphine Complexes with Transition Metals
Author: Alicia L. McDaniel
Publisher:
ISBN:
Category : Chemistry
Languages : en
Pages : 136
Book Description
Publisher:
ISBN:
Category : Chemistry
Languages : en
Pages : 136
Book Description
Synthesis and Characterization of New Nickel (0) Phosphine Complexes
Author: Jason R. Condrey
Publisher:
ISBN:
Category : Transition metal complexes
Languages : en
Pages : 112
Book Description
Publisher:
ISBN:
Category : Transition metal complexes
Languages : en
Pages : 112
Book Description
Synthesis, Characterization, and Reactivity of Rhodium and Iridium Phosphine Complexes Containing Sulfur Ligands Resulting from Reactions with H2S
Author: Ann Marie Mueting
Publisher:
ISBN:
Category :
Languages : en
Pages : 586
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 586
Book Description
Ruthenium in Organic Synthesis
Author: Shun-Ichi Murahashi
Publisher: John Wiley & Sons
ISBN: 3527605797
Category : Science
Languages : en
Pages : 398
Book Description
In this comprehensive book, one of the leading experts, Shun-Ichi Murahashi, presents all the important facets of modern synthetic chemistry using Ruthenium, ranging from hydrogenation to metathesis. In 14 contributions, written by an international authorship, readers will find all the information they need about this fascinating and extraordinary chemistry. The result is a high quality information source and a indispensable reading for everyone working in organometallic chemistry. From the contents: Introduction (S.-I. Murahashi) Hydrogenation and Transfer Hydrogenation (M. Kitamura and R. Noyori) Oxidations (S.-I. Murahashi and N. Komiya) Carbon-Carbon Bond Formations via Ruthenacycle Intermediates (K. Itoh) Carbon-Carbon Bond Formation via pi-Allylruthenium Intermediates (T. Mitsudo) Olefin Metathesis (R. H. Grubbs) Cyclopropanation (H. Nishiyama) Nucleophilic Addition to Alkynes and Reactions via Vinylidene Intermediates (P. Dixneuf) Reactions via C-H Activation (N. Chatani) Lewis Acid Reactions (E. P. Kundig) Reactions with CO and CO2 (T. Mitsudo) Isomerization of Organic Substrates Catalyzed by Ruthenium Complexes (H. Suzuki) Radical Reactions (H. Nagashima) Bond Cleavage Reactions (S. Komiya)
Publisher: John Wiley & Sons
ISBN: 3527605797
Category : Science
Languages : en
Pages : 398
Book Description
In this comprehensive book, one of the leading experts, Shun-Ichi Murahashi, presents all the important facets of modern synthetic chemistry using Ruthenium, ranging from hydrogenation to metathesis. In 14 contributions, written by an international authorship, readers will find all the information they need about this fascinating and extraordinary chemistry. The result is a high quality information source and a indispensable reading for everyone working in organometallic chemistry. From the contents: Introduction (S.-I. Murahashi) Hydrogenation and Transfer Hydrogenation (M. Kitamura and R. Noyori) Oxidations (S.-I. Murahashi and N. Komiya) Carbon-Carbon Bond Formations via Ruthenacycle Intermediates (K. Itoh) Carbon-Carbon Bond Formation via pi-Allylruthenium Intermediates (T. Mitsudo) Olefin Metathesis (R. H. Grubbs) Cyclopropanation (H. Nishiyama) Nucleophilic Addition to Alkynes and Reactions via Vinylidene Intermediates (P. Dixneuf) Reactions via C-H Activation (N. Chatani) Lewis Acid Reactions (E. P. Kundig) Reactions with CO and CO2 (T. Mitsudo) Isomerization of Organic Substrates Catalyzed by Ruthenium Complexes (H. Suzuki) Radical Reactions (H. Nagashima) Bond Cleavage Reactions (S. Komiya)
Synthesis and Characterization of Phosphine and Halide Complexes Containing the Bis-(diimine)-carbonyl-osmium(II) Moiety
Author: Pantea Menhaji
Publisher:
ISBN:
Category :
Languages : en
Pages : 578
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 578
Book Description
Metallocenyl Phosphine Complexes of Ruthenium and Group 10 Metals-synthesis, Characterisation and Catalytic Debromination of Polybrominated Aromatics
Author: Bing Wei
Publisher:
ISBN:
Category : Phosphine
Languages : en
Pages : 398
Book Description
Publisher:
ISBN:
Category : Phosphine
Languages : en
Pages : 398
Book Description
The Reaction of Phosphine with a Ruthenium (II) Porphyrin Synthesis of a Potential Precursor to a Phosphinidene Complex
Author: Marie-Pierre Jasinski
Publisher:
ISBN:
Category :
Languages : en
Pages : 156
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 156
Book Description
Synthesis, Characterization, and Reactivity of Low Valent Technetium Phosphine Complexes
Author: Evan Freiberg
Publisher:
ISBN:
Category :
Languages : en
Pages : 446
Book Description
Chapter 1. The chemistry of the metal-metal multiply bonded Tc2(II, II) core has been investigated with bis(diphenylphosphino)methane (dppm). The parent complex, Tc2Cl4(dppm)2, has been prepared from the reaction of Tc2C14(PEt3)4 with dppm. The reactivity of Tc2Cl4(dppm)2 with tert-butyl isocyanide has been studied and a neutral 1:1 adduct, Tc2Cl4(dppm)2CNBut, a cationic 1:2 adduct, [Tc2Cl3(dppm)4(CNBut)2](PF6), and a [mu]-iminyl complex, [Tc2Cl3(dppm)2(CNBut)2CNHBul(PF6), have been prepared. The parent compound and its reaction products have been characterized via a combination of spectroscopic techniques and single crystal X-ray crystallography. The metal-metal bonded ditechnetium bis(dppm) motif is retained in the reaction products. Chapter 2. The reduction of ammonium pertechnetate with bis(diphenylphosphino)methane (dppm), and with diphenyl-2-pyridyl phosphine (Ph2Ppy), has been investigated. The neutral Tc(II) complex, TcCl2(dppm)2, has been isolated from the reaction of (NH4)[TcO4] with excess dppm in refluxing EtOH/HCl. Chemical oxidation with ferricinium hexafluorophosphate results in formation of the cationic Tc(III) analogue, [TcCl2(dppm)2](PF6). The dppm ligands adopt the chelating bonding mode in both complexes, resulting in strained four member metallocycles. With excess PhPpy, the reduction of (NH4)[TcO4] in refluxing EtOH/HCl yields a complex with one chelating Ph2Ppy ligand and one unidentate Ph2Ppy ligand, TcCl3(Ph2Ppy-P, N)(Ph2Ppy-P).
Publisher:
ISBN:
Category :
Languages : en
Pages : 446
Book Description
Chapter 1. The chemistry of the metal-metal multiply bonded Tc2(II, II) core has been investigated with bis(diphenylphosphino)methane (dppm). The parent complex, Tc2Cl4(dppm)2, has been prepared from the reaction of Tc2C14(PEt3)4 with dppm. The reactivity of Tc2Cl4(dppm)2 with tert-butyl isocyanide has been studied and a neutral 1:1 adduct, Tc2Cl4(dppm)2CNBut, a cationic 1:2 adduct, [Tc2Cl3(dppm)4(CNBut)2](PF6), and a [mu]-iminyl complex, [Tc2Cl3(dppm)2(CNBut)2CNHBul(PF6), have been prepared. The parent compound and its reaction products have been characterized via a combination of spectroscopic techniques and single crystal X-ray crystallography. The metal-metal bonded ditechnetium bis(dppm) motif is retained in the reaction products. Chapter 2. The reduction of ammonium pertechnetate with bis(diphenylphosphino)methane (dppm), and with diphenyl-2-pyridyl phosphine (Ph2Ppy), has been investigated. The neutral Tc(II) complex, TcCl2(dppm)2, has been isolated from the reaction of (NH4)[TcO4] with excess dppm in refluxing EtOH/HCl. Chemical oxidation with ferricinium hexafluorophosphate results in formation of the cationic Tc(III) analogue, [TcCl2(dppm)2](PF6). The dppm ligands adopt the chelating bonding mode in both complexes, resulting in strained four member metallocycles. With excess PhPpy, the reduction of (NH4)[TcO4] in refluxing EtOH/HCl yields a complex with one chelating Ph2Ppy ligand and one unidentate Ph2Ppy ligand, TcCl3(Ph2Ppy-P, N)(Ph2Ppy-P).