Structural and Physical Properties of Chalcogenide Materials for Thermoelectric Applications

Structural and Physical Properties of Chalcogenide Materials for Thermoelectric Applications PDF Author: Panagiotis Mangelis
Publisher:
ISBN:
Category :
Languages : en
Pages :

Get Book Here

Book Description

Structural and Physical Properties of Chalcogenide Materials for Thermoelectric Applications

Structural and Physical Properties of Chalcogenide Materials for Thermoelectric Applications PDF Author: Panagiotis Mangelis
Publisher:
ISBN:
Category :
Languages : en
Pages :

Get Book Here

Book Description


Structural and Chemical Features of Chalcogenides

Structural and Chemical Features of Chalcogenides PDF Author: Suresh Sagadevan
Publisher: BoD – Books on Demand
ISBN: 0854661859
Category : Science
Languages : en
Pages : 112

Get Book Here

Book Description
Investigate the chalcogenides with this comprehensive consideration of their structural and chemical characteristics. This book provides a deep dive for researchers, material scientists, and inquisitive minds. • Explore the bonding patterns and atomic arrangements that define chalcogenides. • Unravel the unique crystal structures of various chalcogenide families, from layered wonders to complex networks. • Gain a thorough understanding of the factors governing chalcogenide formation and composition. • Have an impact on structural and chemical features by the electrical, optical, and other properties of chalcogenides. • Implement the vast applications of chalcogenides in fields ranging from photonics and electronics to energy storage and catalysis. • Learn the structural and chemical features of chalcogenides to provide a rich understanding of these versatile materials, positioning you to unlock their potential for groundbreaking advancements.

Inorganic Thermoelectric Materials

Inorganic Thermoelectric Materials PDF Author: Anthony V Powell
Publisher: Royal Society of Chemistry
ISBN: 1788019601
Category : Science
Languages : en
Pages : 256

Get Book Here

Book Description
Thermoelectric devices convert a heat flux directly into electrical power. They afford opportunities to achieve efficiency savings in a variety of applications, through the conversion of otherwise waste heat into useful electrical energy. Operated in reverse mode, they provide effective thermal management in areas ranging from cooling of electronic components to battery conditioning in electric vehicles. Implementation of thermoelectric technology requires materials with improved performance and stability, containing readily-available and inexpensive elements. A range of thermoelectric materials for use in different temperature regimes has emerged. Knowledge of the complex relationship between composition, structure and physical properties is central to understanding the performance of these advanced materials. This book provides both an introduction to the field of thermoelectrics and a survey of the state-of-the-art. Chapters review the important new families of advanced materials that have emerged and taken the field beyond traditional thermoelectric materials such as Bi2Te3, PbTe and SiGe. The emphasis is on the relationship between chemical composition, structure over a range of length scales and the physical properties that underlie performance. Edited by a leader in the field, and with contributions from global experts, Inorganic Thermoelectric Materials serves as an introduction to thermoelectric materials and is accessible to advanced undergraduates and postgraduates, as well as experienced researchers

Chalcogenide

Chalcogenide PDF Author: Xinyu Liu
Publisher: Woodhead Publishing
ISBN: 0081027362
Category : Technology & Engineering
Languages : en
Pages : 398

Get Book Here

Book Description
Chalcogenide: From 3D to 2D and Beyond reviews graphene-like 2D chalcogenide systems that include topological insulators, interesting thermoelectric structures, and structures that exhibit a host of spin phenomena that are unique to 2D and lower-dimensional geometries. The book describes state-of-the-art materials in growth and fabrication, magnetic, electronic and optical characterization, as well as the experimental and theoretical aspects of this family of materials. Bulk chalcogenides, chalcogenide films, their heterostructures and low-dimensional chalcogenide-based quantum structures are discussed. Particular attention is paid to findings that are relevant to the continued search for new physical phenomena and new functionalities. Finally, the book covers the enormous opportunities that have emerged as it has become possible to achieve lower-dimensional chalcogenide structures by epitaxial techniques. Provides readers with foundational information on the materials growth, fabrication, magnetic, electronic and optical characterization of chalcogenide materials Discusses not only bulk chalcogenides and chalcogenide thin films, but also two-dimensional chalcogenide materials systems Reviews the most important applications in optoelectronics, photovoltaics and thermoelectrics

Novel Chalcogenides for Thermoelectric Conversion

Novel Chalcogenides for Thermoelectric Conversion PDF Author: Raghavendra Nunna
Publisher:
ISBN:
Category :
Languages : en
Pages : 145

Get Book Here

Book Description
The focus of this thesis work is the exploratory preparation of novel chalcogenides as potential thermoelectric materials and the analyses of their physical properties. A thermoelectric material is capable of converting heat to electricity or vice versa. Usually, narrow band gap semiconductors are good candidates for thermoelectric applications, because such materials have large Seebeck coefficient, reasonably high electrical conductivity and low thermal conductivity. In this work, two different systems were studied, intermetallic pseudo hollandite structures and layered CdI2 type structures. In the large family of pseudo hollandite systems, we mainly focused on thallium systems in which the solid solution TlxCr5Se8 and TlCr5Se8-xTex have been synthesized. In CdI2 structures, we focused our investigation on transition metal selenides for their rather semiconducting properties. Therefore we embarked on the systematic study of AgCrSe2, TiS2 and TiSe2. In addition, the effect on physical properties using different intercalated elements (Ag and Cu) in TiSe2 chalcogenides were studied. All these samples are prepared by the solid state reaction. The purity of the samples was confirmed by powder X-ray diffraction data, physical and thermal properties were measured on Spark Plasma Sintered (SPS) samples. Low thermal conductivity as well as competitive power factors was observed in these chalcogenides. The highest zT of 0.54 is achieved in titanium dichalcogenides for the composition of Cu0.05TiS1.5Se0.5 at 700K. Our results show that these structures are potential for future thermoelectric materials research.

First-principles Study of the Electronic Structure, Bonding, Optical, Mechanical, and Thermoelectric Properties of Bulk Chalcogenide Crystals

First-principles Study of the Electronic Structure, Bonding, Optical, Mechanical, and Thermoelectric Properties of Bulk Chalcogenide Crystals PDF Author: Sahib Hasan
Publisher:
ISBN:
Category : Chalcogenides
Languages : en
Pages : 196

Get Book Here

Book Description
Chalcogenide crystals are a unique class of materials very different from semiconductors or metallic alloys. They have many practical applications in the civil and military fields, especially in relation to their electronic, optical, and mechanical properties for energy conversion as thermoelectric materials and in environmental materials. Thermoelectric materials can be used to generate electricity from the temperature gradient based on the Seebeck effect and based on the Peltier effect they can be used in cooling applications. However, the fundamental understanding of the electronic structure and other physical properties of the chalcogenides is rather scattered and incomplete because they are much less systemically studied. This work provides a comprehensive study of many physical properties for large number of chalcogenide crystals. This work is mainly divided into two main parts: chapter 3 and chapter 4. In the first part of this work (chapter 3), we present a detailed study using first-principles calculations on the electronic structure, interatomic bonding, optical, and mechanical properties for 131 chalcogenide crystals. This part itself is divided into two main sections: section 3.1 and section 3.2 in chapter 3. Section 3.1 is for the first 32 crystals of 131 crystals, while section 3.2 is for the remaining 99 crystals. Based on this large database, we are able to identify some new and conspicuous observations to reach some useful conclusions related to the chemical composition of the chalcogenide compounds and their complex interatomic interactions. Moreover, the total bond order density (TBOD) is used as a single quantum mechanical metric to characterize the internal cohesion of these crystals enabling us to correlate them with the calculated properties, especially their mechanical properties. Finally, generalization of the observed trends and empirical rules can be extended to much larger classes of ternary and quaternary chalcogenide crystals and glasses so far unexplored. In the second part of this work (chapter 4), using density functional theory and semiclassical Boltzmann theory, we have computed the Seebeck coefficient, electrical conductivity, electronic thermal conductivity, power factor, and figure of merit of 30 chalcogenide crystals. VASP and Quantum Espresso packages are used to relax the crystal structures, calculate the electronic properties, and locate the Fermi level. The transport properties are then calculated using the BoltTraP code. The 30 crystals are divided into two groups. The first group has four crystals with quaternary composition (A2BCQ4) (A = Tl; B = Cd, Hg; C = Si, Ge, Sn; Q = S, Se, Te). The second group contains 26 crystals with the ternary composition (A'B'Q2) (A' = Ag, Cu, Au, Na; B' = B, Al, Ga, In; Q = S, Se, Te). Among these 30 chalcogenide crystals, the results for 11 crystals: Tl2CdGeSe4, Tl2CdSnSe4, Tl2HgSiSe4, Tl2HgSnS4, AuBSe2, AuBTe2, AuAlTe2, AuGaTe2, AuInTe2, AgAlSe2, and AgAlTe2 are revealed for the first time. In addition, temperature dependent transport properties of pure and doped AgSbSe2 and AgSbTe2 crystals with dopant compositions of AgSb0.94Cd0.06Te2 and AgSbTe1.85Se0.15 were explored. These results provide a large database for bulk chalcogenides crucial for a wide range of potential applications in renewable energy fields.

Synthesis and Optimization of Chalcogenides Quantum Dots Thermoelectric Materials

Synthesis and Optimization of Chalcogenides Quantum Dots Thermoelectric Materials PDF Author: Chong Xiao
Publisher: Springer
ISBN: 3662496178
Category : Technology & Engineering
Languages : en
Pages : 124

Get Book Here

Book Description
This thesis focuses on chalcogenide compound quantum dots with special crystal structures and behaviors in an effort to achieve the synergistic optimization of electrical and thermal transport for high-efficiency thermoelectric materials. The controllability and large-scale synthesis of chalcogenide quantum dots are realized through simple colloid synthesis, and the synergistic optimization of the materials’ electrical and thermal transport properties is successfully achieved. Furthermore, the book explores the mechanism involved in the integration of high thermoelectric performance and reversible p-n semiconducting switching in bimetal chalcogenide semiconductors. As such, the thesis will be of interest to university researchers and graduate students in the materials science, chemistry and physics.

Lead Chalcogenides

Lead Chalcogenides PDF Author: D. Khokhlov
Publisher: Routledge
ISBN: 1351435566
Category : Technology & Engineering
Languages : en
Pages : 720

Get Book Here

Book Description
Lead Chalcogenides remain one of the basic materials of modern infrared optoelectronics. This volume presents the properties of lead chalcogenides, including the basic physical features, the bulk and epitaxial growth technique, and the 2-D physics of lead chalcogenide-based structures. In addition, the theoretical appraoches for band structure and impurity state calculations are reviewed.

Applications of Chalcogenides: S, Se, and Te

Applications of Chalcogenides: S, Se, and Te PDF Author: Gurinder Kaur Ahluwalia
Publisher: Springer
ISBN: 9783319822891
Category : Technology & Engineering
Languages : en
Pages : 0

Get Book Here

Book Description
This book introduces readers to a wide range of applications for elements in Group 16 of the periodic table, such as, optical fibers for communication and sensing, X-ray imaging, electrochemical sensors, data storage devices, biomedical applications, photovoltaics and IR detectors, the rationale for these uses, the future scope of their applications, and expected improvements to existing technologies. Following an introductory section, the book is broadly divided into three parts—dealing with Sulfur, Selenium, and Tellurium. The sections cover the basic structure of the elements and their compounds in bulk and nanostructured forms; properties that make these useful for various applications, followed by applications and commercial products. As the global technology revolution necessitates the search for new materials and more efficient devices in the electronics and semiconductor industry, Applications of Chalcogenides: S, Se, and Te is an ideal book for a wide range of readers in industry, government and academic research facilities looking beyond silicon for materials used in the electronic and optoelectronic industry as well as biomedical applications.

Chalcogenide-Based Nanomaterials as Photocatalysts

Chalcogenide-Based Nanomaterials as Photocatalysts PDF Author: Mohammad Mansoob Khan
Publisher: Elsevier
ISBN: 0128209178
Category : Technology & Engineering
Languages : en
Pages : 378

Get Book Here

Book Description
Chalcogenide-Based Nanomaterials as Photocatalysts deals with the different types of chalcogenide-based photocatalytic reactions, covering the fundamental concepts of photocatalytic reactions involving chalcogenides for a range of energy and environmental applications. Sections focus on nanostructure control, synthesis methods, activity enhancement strategies, environmental applications, and perspectives of chalcogenide-based nanomaterials. The book offers guidelines for designing new chalcogenide-based nanoscale photocatalysts at low cost and high efficiency for efficient utilization of solar energy in the areas of energy production and environment remediation. Provides information on the development of novel chalcogenide-based nanomaterials Outlines the fundamentals of chalcogenides-based photocatalysis Includes techniques for heterogeneous catalysis based on chalcogenide-based nanomaterials