Sorption Equilibrium and Desorption Kinetics of Hydrophobic Pollutants in Porous Media

Sorption Equilibrium and Desorption Kinetics of Hydrophobic Pollutants in Porous Media PDF Author: Karen Elizabeth Gardner
Publisher:
ISBN:
Category :
Languages : en
Pages : 262

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Sorption Equilibrium and Desorption Kinetics of Hydrophobic Pollutants in Porous Media

Sorption Equilibrium and Desorption Kinetics of Hydrophobic Pollutants in Porous Media PDF Author: Karen Elizabeth Gardner
Publisher:
ISBN:
Category :
Languages : en
Pages : 262

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Diffusion in Natural Porous Media

Diffusion in Natural Porous Media PDF Author: Peter Grathwohl
Publisher: Springer Science & Business Media
ISBN: 146155683X
Category : Science
Languages : en
Pages : 198

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Book Description
Diffusion in Natural Porous Media: Contaminant Transport, Sorption/Desorption and Dissolution Kinetics introduces the general principles of diffusion in the subsurface environment and discusses the implications for the fate and transport of contaminants in soils and groundwater. Emphasis is placed on sorption/desorption and the dissolution kinetics of organic contaminants, both of which are limited by the slow speed of molecular diffusion. Diffusion in Natural Porous Media: Contaminant Transport, Sorption/Desorption and Dissolution Kinetics compiles methods for calculating the diffusion coefficients of organic compounds (in aqueous solution or vapor phase) in natural porous media. The author uses analytical solutions of Fick's 2nd law and some simple numerical models to model diffusive transport under various initial and boundary conditions. A number of these models may be solved using spreadsheets. The book examines sorption/desorption rates of organic compounds in various soils and aquifer materials, and also examines the dissolution kinetics of nonaqueous phase liquids in aquifers, in both the trapped residual phase and in pools. Diffusion in Natural Porous Media: Contaminant Transport, Sorption/Desorption and Dissolution Kinetics concludes with a discussion of the impact of slow diffusion processes on soil and groundwater decontamination and the implications of these processes for groundwater risk assessment.

Sediment Dynamics and Pollutant Mobility in Rivers

Sediment Dynamics and Pollutant Mobility in Rivers PDF Author: Bernd Westrich
Publisher: Springer Science & Business Media
ISBN: 3540347852
Category : Science
Languages : en
Pages : 463

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Book Description
This is the first interdisciplinary book on the mobilization of nutrients and pollutants in the water phase due to hydrodynamic processes. Coverage includes the formation of aggregates in turbulent water; flocks and biofilms from organic reactions; and the formation of new surfaces for re-adsorption of dissolved pollutants. The book gathers papers resulting from an International Symposium on Sediment Dynamics and Pollutant Mobility in River Basins in Hamburg, Germany, March, 2006.

Substituent Constants for Correlation Analysis in Chemistry and Biology

Substituent Constants for Correlation Analysis in Chemistry and Biology PDF Author: Corwin Hansch
Publisher: John Wiley & Sons
ISBN:
Category : Science
Languages : en
Pages : 360

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Soil Physical Chemistry

Soil Physical Chemistry PDF Author: Donald L. Sparks
Publisher: CRC Press
ISBN: 1351415794
Category : Technology & Engineering
Languages : en
Pages : 432

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Book Description
Soil Physical Chemistry, Second Edition takes up where the last edition left off. With comprehensive and contemporary discussions on equilibrium and kinetic aspects of major soil chemical process and reactions this excellent text/reference presents new chapters on precipitation/dissolution, modeling of adsorption reactions at the mineral/water interface, and the chemistry of humic substances. An emphasis is placed on understanding soil chemical reactions from a microscopic point of view and rigorous theoretical developments such as the use of modern in situ surface chemical probes such as x-ray adsorption fine structure (XAFS), Fournier transform infrared (FTIR) spectroscopies, and scanning probe microscopies (SPM) are discussed.

Contaminated Soil’93

Contaminated Soil’93 PDF Author: F. Arendt
Publisher: Springer Science & Business Media
ISBN: 9401120188
Category : Science
Languages : en
Pages : 1045

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Book Description
F. Arendt, XxX (Conference chairman) w. Harder, TNO (Conference co-chairman) The 1993 Berlin conference on contaminated sites is the fourth in a series of meetings initiated by the Netherlands Organization of Applied Scientific Research (TNO) in 1985 and later continued with the Karlsruhe Nuclear Research center (KfK) of Germany. The present economic stagnation or recession in many countries is leading to various proposals to reduce the level of costly environmental activities: restricted funds are used for really urgent cases rather than precautionary measures. The level of soil contamination caused by the former centrally planned economies adds to this tendency. The Conference tries to broach this controversy by discussing once more the targets and strategies of soil remediation with follow-up use of the site as an important parameter. Both new regulations and modifications of existing lists for a tolerable level of contamination are reviewed alike. Immobilization and enclosure of pollutants are often less expensive than complete remediat ion and, consequently, may grow in significance. We consider the conference of great significance for demonstrating the experiences gained with management and remediation of contaminated sites internationally, among others to avoid mistakes and excessive costs. Two new types of soil contamination became apparent after the end of the cold war. Many military sites, airfields and train ing grorinds are being abandoned. After decades of use, large sections and hot spots of these sites are polluted to a high average level.

Handbook of Soil Sciences (Two Volume Set)

Handbook of Soil Sciences (Two Volume Set) PDF Author: Pan Ming Huang
Publisher: CRC Press
ISBN: 1439803048
Category : Science
Languages : en
Pages : 2272

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Book Description
An evolving, living organic/inorganic covering, soil is in dynamic equilibrium with the atmosphere above, the biosphere within, and the geology below. It acts as an anchor for roots, a purveyor of water and nutrients, a residence for a vast community of microorganisms and animals, a sanitizer of the environment, and a source of raw materials for co

Significance and Treatment of Volatile Organic Compounds in Water Supplies

Significance and Treatment of Volatile Organic Compounds in Water Supplies PDF Author: Neil M. Ram
Publisher: CRC Press
ISBN: 9780873711234
Category : Technology & Engineering
Languages : en
Pages : 578

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Book Description
Significance and Treatment of Volatile Organic Compounds in Water Supplies reviews EPA-approved analytical methods for VOC analysis, QA/QC, data quality objectives and limits of detection. It covers current methods for the assessment of health effects, including toxicity and carcinogenicity. If you only purchase one book on VOCs-this should be it. Leading authorities present the latest essential information on VOCs in drinking water. This book will be a valuable resource to personnel involved with VOC contamination, treatment, costs, and regulation.

Toxic Organic Chemicals in Porous Media

Toxic Organic Chemicals in Porous Media PDF Author: Zev Gerstl
Publisher: Springer Science & Business Media
ISBN: 3642744680
Category : Science
Languages : en
Pages : 354

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Book Description
In March, 1983 a workshop on Pollutants in Porous Media was hosted by the Institute of Soils and Water of the Agricultural Research Organi zation in Bet Dagan, Israel. At this workshop, the unsaturated zone be tween the soil surface and groundwater was the focal point of discus sions for scientists from various disciplines such as soil chemists, physicists, biologists and environmental engineers. Since then, the prob lem of soil and water pollution has only worsened as more and more cases of pollution caused by human activities including agriculture and industry have been revealed. A great deal of work has been carried out by environmental scientists since 1983 in elucidating the behavior of the many classes of pollutants and the complex physical, chemical, and bio logical transformations which they undergo as they move through the soil to the vadose zone and, in many cases, the groundwater. In light of this, it was felt that another meeting of specialists from the many disciplines which deal with this subject was necessary and so a Second International Workshop on the Behavior of Pollutants in Porous Media, sponsored by IUPAC (the International Union of Pure and Applied Chemistry) and IAHS (the International Association of Hydrological Sciences), was organized and held in the Institute of Soils and Water of the Agricultural Research Organization in Bet Dagan, Israel during 1987. June, The present volume is a selection of the talks presented at this second workshop and deals only with toxic organic chemicals in porous media.

Partition and Adsorption of Organic Contaminants in Environmental Systems

Partition and Adsorption of Organic Contaminants in Environmental Systems PDF Author: Cary T. Chiou
Publisher: John Wiley & Sons
ISBN: 0471463019
Category : Science
Languages : en
Pages : 269

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Book Description
Given the presence of a wide variety of contaminants in the environment, it is important to understand what drives a contaminant from one medium to another, as well as the manner and extent to which a contaminant associates with the different media or phases within a local environmental system. Partition and Adsorption of Organic Contaminants in Environmental Systems forms a comprehensive resource on the behavioral characteristics of contaminants so that appropriate strategies can be adopted to either prevent or minimize their adverse impacts on human welfare and natural resources. Cary Chiou’s far-reaching text depicts the processes by which nonionic organic contaminants are sorbed to natural biotic and abiotic substances. This book focuses on physical principles and system parameters that affect the contaminant uptake by soil from water, air, and other media; by fish from water; and by plants from soil and water. As contaminant uptake by natural organic substances is often predominantly a partition interaction, the partition characteristics in several solvent-water model mixtures are treated in detail to elucidate the relevant physicochemical parameters. The account of contaminant sorption to soils, fish, and plants is strengthened by companion chapters on: Fundamentals of solution theory Interphase partition equations Fundamentals of adsorption theory Vapor adsorption on mineral and carbonaceous solids No other single source in the field delivers as compelling a combination of background understanding and "state-of-the-science" comprehension of current issues. Ideally suited for a graduate-level environmental course, Partition and Adsorption of Organic Contaminants in Environmental Systems also serves as a technical guide to current and future research in the field.