Author: Theodore A. Brabbs
Publisher:
ISBN:
Category : Aerodynamics
Languages : en
Pages : 28
Book Description
Recombination of Carbon Monoxide and Atomic Oxygen at High Temperatures
Author: Theodore A. Brabbs
Publisher:
ISBN:
Category : Aerodynamics
Languages : en
Pages : 28
Book Description
Publisher:
ISBN:
Category : Aerodynamics
Languages : en
Pages : 28
Book Description
Recombination Between Carbon Monoxide and Excited Oxygen Atoms
Author: Atomic Energy Research Establishment (Harwell, England)
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ISBN:
Category :
Languages : en
Pages : 12
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 12
Book Description
The Carbon Monoxide Atomic Oxygen Reaction
Author: Richard Bruce Solo
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ISBN:
Category : Carbon monoxide
Languages : en
Pages : 216
Book Description
Publisher:
ISBN:
Category : Carbon monoxide
Languages : en
Pages : 216
Book Description
NASA Technical Note
Author:
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ISBN:
Category :
Languages : en
Pages : 458
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 458
Book Description
THE RECOMBINATION OF OXYGEN ATOMS AT HIGH TEMPERATURES AS MEASURED BY SHOCK TUBE DENSITOMETRY.
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
Kinetics of Recombination of Atomic Oxygen at Room Temperature
Author: H. L. PETERSEN
Publisher:
ISBN:
Category :
Languages : en
Pages : 1
Book Description
OXYGEN WAS PARTLY DISSOCIATED BY A MICROWAVE DISCHARGE IN STATIC EXPERIMENTS, AND THE ABSOLUTE CONCENTRATION OF ATOMS WAS DETERMINED WITH A Wrede gage. The rate of recombination was measured by observing the radiation emitted as a result of the reaction of O atoms with a trace of NO2. An upper limit of 2.5 x 10 to the 14th power cc sq./mole sq. sec was established for the rate constant at 350 K of the reaction O + O + O2 yields O2 + O2. Since this upper limit is 1/3 to 1/2 times the value found in shocktube experiments for the same rate constant at 3500 K, it is concluded that the rate constant increases slowly with temperature instead of varying as an inverse power of absolute temperature, as has conventionally been assumed. In the same experiments, the rate constant for the reaction O + O2 + O2 yields O3 + O2 was found to be 1.1 x 10 to the 14th power cc sq./mole sq. sec at 350 K, in excellent agreement with other recent determinations. Recombination was strongly catalyzed by OH radicals in accordance with the mechanism O + OH + O2 yields HO2 + O2 and O + HO2 yields OH + O2. The rates of these reactions are reported. (Author).
Publisher:
ISBN:
Category :
Languages : en
Pages : 1
Book Description
OXYGEN WAS PARTLY DISSOCIATED BY A MICROWAVE DISCHARGE IN STATIC EXPERIMENTS, AND THE ABSOLUTE CONCENTRATION OF ATOMS WAS DETERMINED WITH A Wrede gage. The rate of recombination was measured by observing the radiation emitted as a result of the reaction of O atoms with a trace of NO2. An upper limit of 2.5 x 10 to the 14th power cc sq./mole sq. sec was established for the rate constant at 350 K of the reaction O + O + O2 yields O2 + O2. Since this upper limit is 1/3 to 1/2 times the value found in shocktube experiments for the same rate constant at 3500 K, it is concluded that the rate constant increases slowly with temperature instead of varying as an inverse power of absolute temperature, as has conventionally been assumed. In the same experiments, the rate constant for the reaction O + O2 + O2 yields O3 + O2 was found to be 1.1 x 10 to the 14th power cc sq./mole sq. sec at 350 K, in excellent agreement with other recent determinations. Recombination was strongly catalyzed by OH radicals in accordance with the mechanism O + OH + O2 yields HO2 + O2 and O + HO2 yields OH + O2. The rates of these reactions are reported. (Author).
A Shock Tube Study of the Recombination of Carbon Monoxide and Oxygen Atoms
Author: Anthony M. Dean
Publisher:
ISBN:
Category :
Languages : en
Pages : 27
Book Description
For some time now this laboratory has been utilizing nitrous oxide as a high temperature source of oxygen atoms. Recently, an independent technique has been used to calibrate the detector system for oxygen atoms. With this calibration factor known, more refined experiments have been performed in which the absolute oxygen atom concentration can be monitored as a function of time. It was found that only slight modifications of earlier rate constant assignments were required to quantitatively explain these new results. In this light it is now felt that the dissociation kinetics of N2O are reasonably well understood. Thus the CO2 production rate in N2O/CO mixtures has been measured in an attempt to determine k sub r. It is shown that small amount of impurities can drastically affect the CO2 production rate. Analysis of this impurity effect has yielded estimates of the actual recombination rate constant between 2100 and 3200 K. The value of k sub r determined in this way is shown to be consistent with the recent measurements of k sub d reported by Wagner, and Kiefer, which yielded normal activation energies for CO2 dissociation.
Publisher:
ISBN:
Category :
Languages : en
Pages : 27
Book Description
For some time now this laboratory has been utilizing nitrous oxide as a high temperature source of oxygen atoms. Recently, an independent technique has been used to calibrate the detector system for oxygen atoms. With this calibration factor known, more refined experiments have been performed in which the absolute oxygen atom concentration can be monitored as a function of time. It was found that only slight modifications of earlier rate constant assignments were required to quantitatively explain these new results. In this light it is now felt that the dissociation kinetics of N2O are reasonably well understood. Thus the CO2 production rate in N2O/CO mixtures has been measured in an attempt to determine k sub r. It is shown that small amount of impurities can drastically affect the CO2 production rate. Analysis of this impurity effect has yielded estimates of the actual recombination rate constant between 2100 and 3200 K. The value of k sub r determined in this way is shown to be consistent with the recent measurements of k sub d reported by Wagner, and Kiefer, which yielded normal activation energies for CO2 dissociation.
The Recombination Between Carbon Monoxide and Excited Oxygen Atoms
Author: J. H. Tait
Publisher:
ISBN:
Category :
Languages : en
Pages : 12
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 12
Book Description
Reaction Rates for High-temperature Air with Carbon and Sodium Impurities
Author: Mina L. Carnicom
Publisher:
ISBN:
Category : Gases at high temperatures
Languages : en
Pages : 156
Book Description
The values used by a number of investigators for the rate constants of high-temperature ([greater than or equal to]1000©K) homogeneous gaseous reactions involving species of the elements nitrogen, oxygen, carbon, and sodium have been compiled and are presented in tabular form. Included are reactions involving neutral species, charged species, free electrons, some species in excited electronic or vibrational states, and radiative processes.
Publisher:
ISBN:
Category : Gases at high temperatures
Languages : en
Pages : 156
Book Description
The values used by a number of investigators for the rate constants of high-temperature ([greater than or equal to]1000©K) homogeneous gaseous reactions involving species of the elements nitrogen, oxygen, carbon, and sodium have been compiled and are presented in tabular form. Included are reactions involving neutral species, charged species, free electrons, some species in excited electronic or vibrational states, and radiative processes.
Recombination of oxygen atoms on surface at high temperature
Author: Miran Mozetič
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description