Author: V. S. Letokhov
Publisher: Springer
ISBN: 9783662134870
Category : Technology & Engineering
Languages : en
Pages : 466
Book Description
The laser as a source of coherent optical radiation has made it possible to investigate nonlinear interaction of optical radiation with atoms and mole cules. Its availability has given rise to new research fields, such as non linear optics, laser spectroscopy, laser photochemistry, that lie at the boundary between quantum electronics and physical optics, optical spectros copy and photochemistry, respectively. The use of coherent optical radiation in each of these fields has led to the discovery of qualitatively ne\~ effects and possibilities; in particular, some rather subtle effects of interaction between highly monochromatic light and atoms and molecules, in optical spec troscopy, have formed the bases for certain methods of so-called nonlinear, laser Doppler-free spectroscopy. These methods have made it possible to in 5 6 crease the resolution of spectroscopic studies from between 10 and 10 , lim 11 ited by Doppl er 1 i ne broadeni ng up, to about 10 ; at present some 1 abor atories are developing new techniques that have even higher resolution. The discovery and elaboration of the methods of nonlinear laser spectroscopy have resulted largely from contributions by scientists from many countries, in particular from the USA (Massachusetts Institute of Technology, Stanford Uni versity, National Bureau of Standards in Boulder, Harvard University, etc. ), the USSR (P. N. Levedev Institute of Physics, Institute of Semiconductor Phys ics in Novosibirsk, Institute of Spectroscopy, etc.
Photoionization and Photo-Induced Processes in Mass Spectrometry
Author: Ralf Zimmermann
Publisher: John Wiley & Sons
ISBN: 3527335102
Category : Science
Languages : en
Pages : 448
Book Description
Provides comprehensive coverage of laser-induced ionization processes for mass spectrometry analysis Drawing on the expertise of the leading academic and industrial research groups involved in the development of photoionization methods for mass spectrometry, this reference for analytical scientists covers both the theory and current applications of photo-induced ionization processes. It places widely used techniques such as MALDI side by side with more specialist approaches such as REMPI and RIMS, and discusses leading edge developments in ultrashort laser pulse desorption, to give readers a complete picture of the state of the technology. Photoionization and Photo-Induced Processes in Mass Spectrometry: Fundamentals and Applications starts with a complete overview of the fundamentals of the technique, covering the basics of the gas phase ionization as well as those of laser desorption and ablation, pulse photoionization, and single particle ionization. Numerous application examples from different analytical fields are described that showcase the power and the wide scope of photo ionization in mass spectrometry. The first general reference book on photoionization techniques for mass spectrometry Examines technologies and applications of gas phase resonance-enhanced multiphoton ionization mass spectrometry (REMPI-MS) and gas phase resonance ionization mass spectrometry (RIMS) Provides complete coverage of popular techniques like MALDI Discusses the current and potential applications of each technology, focusing on process and environmental analysis Photoionization and Photo-Induced Processes in Mass Spectrometry: Fundamentals and Applications is an excellent book for spectroscopists, analytical chemists, photochemists, physical chemists, and laser specialists.
Publisher: John Wiley & Sons
ISBN: 3527335102
Category : Science
Languages : en
Pages : 448
Book Description
Provides comprehensive coverage of laser-induced ionization processes for mass spectrometry analysis Drawing on the expertise of the leading academic and industrial research groups involved in the development of photoionization methods for mass spectrometry, this reference for analytical scientists covers both the theory and current applications of photo-induced ionization processes. It places widely used techniques such as MALDI side by side with more specialist approaches such as REMPI and RIMS, and discusses leading edge developments in ultrashort laser pulse desorption, to give readers a complete picture of the state of the technology. Photoionization and Photo-Induced Processes in Mass Spectrometry: Fundamentals and Applications starts with a complete overview of the fundamentals of the technique, covering the basics of the gas phase ionization as well as those of laser desorption and ablation, pulse photoionization, and single particle ionization. Numerous application examples from different analytical fields are described that showcase the power and the wide scope of photo ionization in mass spectrometry. The first general reference book on photoionization techniques for mass spectrometry Examines technologies and applications of gas phase resonance-enhanced multiphoton ionization mass spectrometry (REMPI-MS) and gas phase resonance ionization mass spectrometry (RIMS) Provides complete coverage of popular techniques like MALDI Discusses the current and potential applications of each technology, focusing on process and environmental analysis Photoionization and Photo-Induced Processes in Mass Spectrometry: Fundamentals and Applications is an excellent book for spectroscopists, analytical chemists, photochemists, physical chemists, and laser specialists.
Nonlinear Laser Spectroscopy
Author: V. S. Letokhov
Publisher: Springer
ISBN: 9783662134870
Category : Technology & Engineering
Languages : en
Pages : 466
Book Description
The laser as a source of coherent optical radiation has made it possible to investigate nonlinear interaction of optical radiation with atoms and mole cules. Its availability has given rise to new research fields, such as non linear optics, laser spectroscopy, laser photochemistry, that lie at the boundary between quantum electronics and physical optics, optical spectros copy and photochemistry, respectively. The use of coherent optical radiation in each of these fields has led to the discovery of qualitatively ne\~ effects and possibilities; in particular, some rather subtle effects of interaction between highly monochromatic light and atoms and molecules, in optical spec troscopy, have formed the bases for certain methods of so-called nonlinear, laser Doppler-free spectroscopy. These methods have made it possible to in 5 6 crease the resolution of spectroscopic studies from between 10 and 10 , lim 11 ited by Doppl er 1 i ne broadeni ng up, to about 10 ; at present some 1 abor atories are developing new techniques that have even higher resolution. The discovery and elaboration of the methods of nonlinear laser spectroscopy have resulted largely from contributions by scientists from many countries, in particular from the USA (Massachusetts Institute of Technology, Stanford Uni versity, National Bureau of Standards in Boulder, Harvard University, etc. ), the USSR (P. N. Levedev Institute of Physics, Institute of Semiconductor Phys ics in Novosibirsk, Institute of Spectroscopy, etc.
Publisher: Springer
ISBN: 9783662134870
Category : Technology & Engineering
Languages : en
Pages : 466
Book Description
The laser as a source of coherent optical radiation has made it possible to investigate nonlinear interaction of optical radiation with atoms and mole cules. Its availability has given rise to new research fields, such as non linear optics, laser spectroscopy, laser photochemistry, that lie at the boundary between quantum electronics and physical optics, optical spectros copy and photochemistry, respectively. The use of coherent optical radiation in each of these fields has led to the discovery of qualitatively ne\~ effects and possibilities; in particular, some rather subtle effects of interaction between highly monochromatic light and atoms and molecules, in optical spec troscopy, have formed the bases for certain methods of so-called nonlinear, laser Doppler-free spectroscopy. These methods have made it possible to in 5 6 crease the resolution of spectroscopic studies from between 10 and 10 , lim 11 ited by Doppl er 1 i ne broadeni ng up, to about 10 ; at present some 1 abor atories are developing new techniques that have even higher resolution. The discovery and elaboration of the methods of nonlinear laser spectroscopy have resulted largely from contributions by scientists from many countries, in particular from the USA (Massachusetts Institute of Technology, Stanford Uni versity, National Bureau of Standards in Boulder, Harvard University, etc. ), the USSR (P. N. Levedev Institute of Physics, Institute of Semiconductor Phys ics in Novosibirsk, Institute of Spectroscopy, etc.
Atomic and Molecular Photoabsorption
Author: Joseph Berkowitz
Publisher: Academic Press
ISBN: 0128019581
Category : Science
Languages : en
Pages : 533
Book Description
Atomic and Molecular Photoabsorption: Partial Cross Sections is a companion work to Joseph Berkowitz's earlier work, Atomic and Molecular Photoabsorption: Absolute Total Cross Sections, published with Academic Press in 2002. In this work Joseph Berkowitz selected the "best" absolute partial cross sections for the same species as included in the companion work. A contrast, however, is that photoabsorption measurements, being of order I/Io, do not require the most intense light sources, whereas acquiring data on the products of light interactions with gaseous matter (ions, electrons, various coincidence measurements) has benefited significantly with the arrival of second- and third-generation synchrotrons. The newer devices have also extended the energy range of the light sources to include the K-shells of the species discussed here. The newer light sources encouraged experimentalists to develop improved instrumentation. Thus, the determination of partial cross sections continues to be an active field, with more recent results in some cases superseding earlier ones. Where the accuracy of the absolute partial cross sections is deemed sufficient (less than five percent), numerical tables are included in this new work. In other cases, the available data are presented graphically. - Includes data on atoms, diatomic molecules, triatomic molecules, and polyatomic molecules - Written by world-leading pioneer in the field of photoionization mass spectrometry - Very clear presentation of the useful, quantitative information in both tables and graphs
Publisher: Academic Press
ISBN: 0128019581
Category : Science
Languages : en
Pages : 533
Book Description
Atomic and Molecular Photoabsorption: Partial Cross Sections is a companion work to Joseph Berkowitz's earlier work, Atomic and Molecular Photoabsorption: Absolute Total Cross Sections, published with Academic Press in 2002. In this work Joseph Berkowitz selected the "best" absolute partial cross sections for the same species as included in the companion work. A contrast, however, is that photoabsorption measurements, being of order I/Io, do not require the most intense light sources, whereas acquiring data on the products of light interactions with gaseous matter (ions, electrons, various coincidence measurements) has benefited significantly with the arrival of second- and third-generation synchrotrons. The newer devices have also extended the energy range of the light sources to include the K-shells of the species discussed here. The newer light sources encouraged experimentalists to develop improved instrumentation. Thus, the determination of partial cross sections continues to be an active field, with more recent results in some cases superseding earlier ones. Where the accuracy of the absolute partial cross sections is deemed sufficient (less than five percent), numerical tables are included in this new work. In other cases, the available data are presented graphically. - Includes data on atoms, diatomic molecules, triatomic molecules, and polyatomic molecules - Written by world-leading pioneer in the field of photoionization mass spectrometry - Very clear presentation of the useful, quantitative information in both tables and graphs
Laser Control of Atoms and Molecules
Author: V. S. Letokhov
Publisher: Oxford University Press on Demand
ISBN: 0198528167
Category : Science
Languages : en
Pages : 323
Book Description
This text treats laser light as a universal tool to control matter at the atomic and molecular level, one of the most exciting applications of lasers. Lasers can heat matter, cool atoms to ultra-low temperatures where they show quantum collective behaviour, and can act selectively on specific atoms and molecules for their detection and separation.
Publisher: Oxford University Press on Demand
ISBN: 0198528167
Category : Science
Languages : en
Pages : 323
Book Description
This text treats laser light as a universal tool to control matter at the atomic and molecular level, one of the most exciting applications of lasers. Lasers can heat matter, cool atoms to ultra-low temperatures where they show quantum collective behaviour, and can act selectively on specific atoms and molecules for their detection and separation.
Photoabsorption, Photoionization, and Photoelectron Spectroscopy
Author: Joseph Berkowitz
Publisher: Academic Press
ISBN: 032314828X
Category : Science
Languages : en
Pages : 490
Book Description
Photoabsorption, Photoionization, and Photoelectron Spectroscopy explores photoabsorption processes involving individual, isolated molecules in the wavelength or photon energy range from the ionization thresholds of molecules (usually in the vacuum ultraviolet region) through the soft and hard X-ray region and beyond the ""K edge."" The interaction between electromagnetic radiation and isolated molecules based on photoabsorption, photoionization, and photoelectron spectroscopy studies is described, along with the techniques for measurement of total and partial cross sections. This book is comprised of eight chapters and examines the decomposition of molecules and molecular ions as well as mildly excited (valence shell excitation) and highly excited (inner shell excitation) molecules. After providing a general theoretical background, it discusses certain classes of atoms and molecules and considers electromagnetic interactions with gases. The following chapters focus on photoabsorption below the first ionization limit; quasi-discrete states above the first ionization potential; and the ionization continuum. Total photoabsorption and photoionization cross sections for selected molecules are also considered, and the angular distribution of photoelectrons is analyzed. The various measurement techniques are described in the last chapter. This monograph will be of interest to radiation chemists, radiation physicists, photochemists, mass spectrometrists, and perhaps radiation biologists.
Publisher: Academic Press
ISBN: 032314828X
Category : Science
Languages : en
Pages : 490
Book Description
Photoabsorption, Photoionization, and Photoelectron Spectroscopy explores photoabsorption processes involving individual, isolated molecules in the wavelength or photon energy range from the ionization thresholds of molecules (usually in the vacuum ultraviolet region) through the soft and hard X-ray region and beyond the ""K edge."" The interaction between electromagnetic radiation and isolated molecules based on photoabsorption, photoionization, and photoelectron spectroscopy studies is described, along with the techniques for measurement of total and partial cross sections. This book is comprised of eight chapters and examines the decomposition of molecules and molecular ions as well as mildly excited (valence shell excitation) and highly excited (inner shell excitation) molecules. After providing a general theoretical background, it discusses certain classes of atoms and molecules and considers electromagnetic interactions with gases. The following chapters focus on photoabsorption below the first ionization limit; quasi-discrete states above the first ionization potential; and the ionization continuum. Total photoabsorption and photoionization cross sections for selected molecules are also considered, and the angular distribution of photoelectrons is analyzed. The various measurement techniques are described in the last chapter. This monograph will be of interest to radiation chemists, radiation physicists, photochemists, mass spectrometrists, and perhaps radiation biologists.
Many-body Theory of Atomic Structure and Photoionization
Author: Tu-nan Chang
Publisher: World Scientific
ISBN: 9789810208776
Category : Science
Languages : en
Pages : 434
Book Description
Detailed discussions on many of the recent advances in the many-body theory of atomic structure are presented by the leading experts around the world on their respective specialized approaches. Emphasis is given to the photoionization dominated by the resonance structures, which reveals the effect of the multi-electron interaction in atomic transitions involving highly correlated atomic systems. Recent experimental developments, stimulated by the more advanced applications of intense lasers and short wavelength synchrotron radiation, are also reviewed. This book brings together a comprehensive theoretical and experimental survey of the current understanding of the basic physical processes involved in atomic processes.
Publisher: World Scientific
ISBN: 9789810208776
Category : Science
Languages : en
Pages : 434
Book Description
Detailed discussions on many of the recent advances in the many-body theory of atomic structure are presented by the leading experts around the world on their respective specialized approaches. Emphasis is given to the photoionization dominated by the resonance structures, which reveals the effect of the multi-electron interaction in atomic transitions involving highly correlated atomic systems. Recent experimental developments, stimulated by the more advanced applications of intense lasers and short wavelength synchrotron radiation, are also reviewed. This book brings together a comprehensive theoretical and experimental survey of the current understanding of the basic physical processes involved in atomic processes.
Photoionization And Photodetachment (In 2 Parts)
Author: Cheuk-yiu Ng
Publisher: World Scientific
ISBN: 9814494739
Category : Science
Languages : en
Pages : 684
Book Description
Owing to the advances of vacuum ultraviolet and ultrafast lasers and third generation synchrotron sources, the research on photoionization, photoelectrons, and photodetachment has gained much vitality in recent years. These new light sources, together with ingenious experimental techniques, such as the coincidence imaging, molecular beam, pulsed field ionization photoelectron, mass-analyzed threshold ion, and pulsed field ion pair schemes, have allowed spectroscopic, dynamic, and energetic studies of gaseous species to a new level of detail and accuracy. Profitable applications of these methods to liquids are emerging.This invaluable two-volume review consists of twenty-two chapters, focusing on recent developments in photoionization and photodetachment studies of atoms; molecules, transient species, clusters, and liquids.
Publisher: World Scientific
ISBN: 9814494739
Category : Science
Languages : en
Pages : 684
Book Description
Owing to the advances of vacuum ultraviolet and ultrafast lasers and third generation synchrotron sources, the research on photoionization, photoelectrons, and photodetachment has gained much vitality in recent years. These new light sources, together with ingenious experimental techniques, such as the coincidence imaging, molecular beam, pulsed field ionization photoelectron, mass-analyzed threshold ion, and pulsed field ion pair schemes, have allowed spectroscopic, dynamic, and energetic studies of gaseous species to a new level of detail and accuracy. Profitable applications of these methods to liquids are emerging.This invaluable two-volume review consists of twenty-two chapters, focusing on recent developments in photoionization and photodetachment studies of atoms; molecules, transient species, clusters, and liquids.
VUV and Soft X-Ray Photoionization
Author: Uwe Becker
Publisher: Springer Science & Business Media
ISBN: 146130315X
Category : Science
Languages : en
Pages : 678
Book Description
Leading investigators offer the first comprehensive study of gas phase photoionization research in the VUV and soft X-ray regime since the massive employment of synchrotron radiation as a spectroscopic tool. Chapters cover all aspects of photoionization phenomena from total cross sections to highly differentiated measurements such as coincidence experiments and spin-resolved electron spectroscopy. This work is abundant with illustrations.
Publisher: Springer Science & Business Media
ISBN: 146130315X
Category : Science
Languages : en
Pages : 678
Book Description
Leading investigators offer the first comprehensive study of gas phase photoionization research in the VUV and soft X-ray regime since the massive employment of synchrotron radiation as a spectroscopic tool. Chapters cover all aspects of photoionization phenomena from total cross sections to highly differentiated measurements such as coincidence experiments and spin-resolved electron spectroscopy. This work is abundant with illustrations.
Electron Spectrometry of Atoms using Synchrotron Radiation
Author: Volker Schmidt
Publisher: Cambridge University Press
ISBN: 9780521675611
Category : Science
Languages : en
Pages : 448
Book Description
This book describes the theory and practice of electron spectrometry using synchrotron radiation. After a short review of background theory, neon is used to elucidate the principles of the photoelectron and Auger spectra. The second part of the book looks at experimental aspects, including characteristic features of electrostatic analyzers, detectors, lenses, disturbances, and optimization, and then illustrates theory and experiment with details of recent experiments. The third part provides useful reference data, including wavefunctions, special theory, polarization and special aspects of instrumentation. A detailed reference list completes the volume. The study of electron spectrometry using synchrotron radiation is a growing field of research driven by the increasing availability of advanced synchrotron radiation light sources and improved theoretical methods for solving the many-electron problem in atoms. This balanced account will be of value to both theorists and experimentalists working in this area.
Publisher: Cambridge University Press
ISBN: 9780521675611
Category : Science
Languages : en
Pages : 448
Book Description
This book describes the theory and practice of electron spectrometry using synchrotron radiation. After a short review of background theory, neon is used to elucidate the principles of the photoelectron and Auger spectra. The second part of the book looks at experimental aspects, including characteristic features of electrostatic analyzers, detectors, lenses, disturbances, and optimization, and then illustrates theory and experiment with details of recent experiments. The third part provides useful reference data, including wavefunctions, special theory, polarization and special aspects of instrumentation. A detailed reference list completes the volume. The study of electron spectrometry using synchrotron radiation is a growing field of research driven by the increasing availability of advanced synchrotron radiation light sources and improved theoretical methods for solving the many-electron problem in atoms. This balanced account will be of value to both theorists and experimentalists working in this area.
Multiphoton Processes in Atoms
Author: Nikolai B. Delone
Publisher: Springer Science & Business Media
ISBN: 3642975097
Category : Science
Languages : en
Pages : 332
Book Description
Multiphoton ionization of atoms in intense laser-light fields is gaining ground as a spectroscopic diagnostic tool. In this volume, Delone and Krainov present their and others' theoretical description of the process occurring in atoms under conditions of multi-photon impacts, in particular, the shift, broadening, and mixing of electronic states which complicate the interpretation of spectra. The topics of individual chapters include tunneling ionization, above-threshold ionization, ionization of multiply charged ions, resonance-enhenced ionization, super-intense radiation fields, and properties of Rydberg states in strong fields.
Publisher: Springer Science & Business Media
ISBN: 3642975097
Category : Science
Languages : en
Pages : 332
Book Description
Multiphoton ionization of atoms in intense laser-light fields is gaining ground as a spectroscopic diagnostic tool. In this volume, Delone and Krainov present their and others' theoretical description of the process occurring in atoms under conditions of multi-photon impacts, in particular, the shift, broadening, and mixing of electronic states which complicate the interpretation of spectra. The topics of individual chapters include tunneling ionization, above-threshold ionization, ionization of multiply charged ions, resonance-enhenced ionization, super-intense radiation fields, and properties of Rydberg states in strong fields.