Novel Tertiary Amine Solid Adsorbents Used for the Capture of Carbon Dioxide PDF Download
Are you looking for read ebook online? Search for your book and save it on your Kindle device, PC, phones or tablets. Download Novel Tertiary Amine Solid Adsorbents Used for the Capture of Carbon Dioxide PDF full book. Access full book title Novel Tertiary Amine Solid Adsorbents Used for the Capture of Carbon Dioxide by M. L. Gray. Download full books in PDF and EPUB format.
Author: M. L. Gray
Publisher:
ISBN:
Category :
Languages : en
Pages :
Get Book Here
Book Description
Author: M. L. Gray
Publisher:
ISBN:
Category :
Languages : en
Pages :
Get Book Here
Book Description
Author: Seyed Mehdi Kamali Shahri
Publisher:
ISBN:
Category :
Languages : en
Pages :
Get Book Here
Book Description
The global demand for energy has increased continuously since the industrial revolution.Fossil fuels such as coal, natural gas, and oil are the primary sources that satisfy this demand. Asa result, the irrefutable influence of anthropogenic CO2 released into the environment hasconsiderably intensified global warming. Coal- and gas-fired power plants are considered one ofthe major source points of fossil fuel consumption. Although renewable energy (i.e., solar, wind,and others) is considered as the ideal alternative to satisfy the future energy demand, in theinterim an actual solution is essential to remove the CO2 produced before its emission into theatmosphere. Among various capturing processes, post-combustion capture is highly promisingdue to the flexibility of CO2 removal via liquid or solid materials. The captured CO2 is thensequestered or converted into new chemical compounds. The capturing process is the mostimportant and energy-intensive step. A major advantage of liquid phase adsorbents is their highcapacity; however, they suffer significantly from a high energy penalty. Solid phase adsorption,which has a lower energy requirement for regeneration, has therefore attracted much attention. Inthe operating conditions of power plants, amine-impregnated support (Type I) sorbents are themost promising among various solid sorbents, due to the high density of nitrogen-active sites, butsuffer from low capacity and efficiency compared to liquid phase absorption process. In order toapproach the problem and understand the origin of this low efficiency, a scientific understandingof the interaction between CO2 and amine-impregnated supports and the influential parametersinvolved is necessary to further develop new and high-efficiency amine-based adsorbents.Novel experimental techniques have been utilized in this research to assess the kineticsand thermodynamics of CO2 adsorption. The influence of structure (linear vs. branch), aminedensity, amine type (primary, secondary, and tertiary), support surface functionalization, andoperating conditions on the thermodynamics and kinetics of CO2 adsorption have been studied. Aivcombination of volumetric adsorption (VA) and differential scanning calorimetry (DSC) havebeen used to study the equilibrium capacity and thermodynamic parameters. The kinetic study hasbeen conducted through a breakthrough reactor (BTR) coupled with a DSC to evaluate CO2adsorption kinetics.At the equilibrium, linear amines, compared to branched amines, indicate a larger CO2adsorption capacity and lower apparent heat of adsorption. For example, the capacity and heat ofadsorption for 40 wt% linear and branch polyethylenimine (PEI) measured to be 3.68 and 2.36mmolCO2/g, along with 68 and 71 kJ/molCO2 at 60oC and 1 bar CO2, respectively. The apparentheat of CO2 adsorption on amine sorbents consists of the intrinsic heat of adsorption, the energyrequirement for diffusion, and amine reorganization, which then approached the intrinsic heat ofadsorption when the necessary energy was provided for CO2 diffusion and amine conformation.Augmenting the amine weight loading also increased the capacity and heat of adsorption. Forinstance, TETA/SiO2 samples showed adsorption capacity enhancements from 0.34 to 1.87mmolCO2/g and heat of adsorption from 45 to 77 kJ/molCO2 as the weight loading increasedfrom 5 to 40 wt% at 60oC and 1 bar CO2. Increasing the secondary amine in the linear structurealso assisted in enhancing capacity and decreasing heat of adsorption. For example, the CO2uptake for TETA and PEI423 increased from 1.87 to 3.68 mmolCO2/g and the heat of adsorptiondeclined from 77 to 68 kJ/molCO2 at 60oC and 1 bar CO2. Polyethylenimine therefore presenteda better performance than molecular amines, which makes PEI more suitable for industrialapplications. The criteria defined by the National Energy and Technology (NETL) for industrialutilization requires 3-6 mmolCO2/g adsorbent capacity to compete with current for carbon captureand sequestration (CCS) technologies. As yet, the criteria have been met; nevertheless, theadsorption efficiency displayed much lower values compared to the theoretical expectationsbased on the proposed mechanism. For example, in theory, the efficiency for dry conditions isexpected to be 0.5, while reports in the literature revealed values of less than 0.3 in experiments.vEfficiency increases directly enhance on total capacity. Moreover, a decrease in heat ofadsorption also provides a more appealing situation for real application in view of the fact that theenergy penalty for regeneration is reduced.The kinetic investigation on the BTR/DSC combination showed similar results in termsof capacity, heat of adsorption, temperature variation, and secondary amine addition. High amine-OH interaction and low CO2 diffusivity into multilayer amines were found as the major issues forthe reduction in amine capacity and efficiency. For instance, the efficiencies for 10 wt% TETAimpregnated on silica and silica-modified surfaces (with octyl groups) at 60oC increasedsignificantly from 0.16 to 0.35, respectively, indicative of reduced amine-OH interaction. Inaddition, efficiency was enhanced from 0.17 to 0.26 for 40 wt% TETA/SiO2 as the temperatureascended from 25oC to 80oC, revealing the effect of facilitated diffusion. Increasing the numberof secondary amines decreased the optimum heat of adsorption for the highest overall rates andalso increased the overall rates. For example, as the 2o/1o ratio increased from 1 to 2 for 40 wt%amine-impregnated silica at 40oC, the optimum heat of adsorption was reduced from 85 to 69kJ/molCO2 and the overall rates were enhanced from 0.013 to 0.015 mmolCO2/g.s. This indicatesthat an increase in the secondary amine ratio offers several benefits for CO2 adsorption. Surfacefunctionalization toward hydrophobicity could also assist to improve capacity, efficiency, andCO2 adsorption kinetics as exemplified above for efficiency. For example, the overall adsorptionrate for 10 wt% TETA/SiO2 at 25oC increased from 0.0075 to 0.0122 mmolCO2/g.s as thehydroxyl groups on the support were replaced with methyl groups. A rigorous spatiotemporalmodeling was applied to the BTR/DSC data to estimate the kinetics and thermodynamicparameters at isothermal conditions. This unique mathematical model predicted the adsorptionand desorption rate constant as well as the heat of adsorption. The model circumventedunphysical simplifications, such as linear driving force and uniform adsorption rates, byconsidering dispersion and convection phenomena.
Author: Elliot A. Roth
Publisher:
ISBN:
Category : Carbon dioxide
Languages : en
Pages :
Get Book Here
Book Description
Author: Shin-ichi Nakao
Publisher: Springer
ISBN: 3030188582
Category : Technology & Engineering
Languages : en
Pages : 83
Get Book Here
Book Description
This book summarises the advanced CO2 capture technologies that can be used to reduce greenhouse gas emissions, especially those from large-scale sources, such as power-generation and steel-making plants. Focusing on the fundamental chemistry and chemical processes, as well as advanced technologies, including absorption and adsorption, it also discusses other aspects of the major CO2 capture methods: membrane separation; the basic chemistry and process for CO2 capture; the development of materials and processes; and practical applications, based on the authors’ R&D experience. This book serves as a valuable reference resource for researchers, teachers and students interested in CO2 problems, providing essential information on how to capture CO2 from various types of gases efficiently. It is also of interest to practitioners and academics, as it discusses the performance of the latest technologies applied in large-scale emission sources.
Author: Wei-Yin Chen
Publisher: Springer
ISBN: 9781441979926
Category : Science
Languages : en
Pages : 2130
Get Book Here
Book Description
There is a mounting consensus that human behavior is changing the global climate and its consequence could be catastrophic. Reducing the 24 billion metric tons of carbon dioxide emissions from stationary and mobile sources is a gigantic task involving both technological challenges and monumental financial and societal costs. The pursuit of sustainable energy resources, environment, and economy has become a complex issue of global scale that affects the daily life of every citizen of the world. The present mitigation activities range from energy conservation, carbon-neutral energy conversions, carbon advanced combustion process that produce no greenhouse gases and that enable carbon capture and sequestion, to other advanced technologies. From its causes and impacts to its solutions, the issues surrounding climate change involve multidisciplinary science and technology. This handbook will provide a single source of this information. The book will be divided into the following sections: Scientific Evidence of Climate Change and Societal Issues, Impacts of Climate Change, Energy Conservation, Alternative Energies, Advanced Combustion, Advanced Technologies, and Education and Outreach.
Author: Nikhil Mittal
Publisher:
ISBN:
Category : Amines
Languages : en
Pages : 146
Get Book Here
Book Description
This work is divided into two parts: (1) Synthesis of amine functionalized adsorbents using grafting technique for post-combustion CO[subscript 2] capture, (2) Performance evaluation of structured bed configuration with straight gas flow channels using amine impregnated adsorbent for post-combustion CO[subscript 2] capture. Brief description of each part is given below: (1)N-(3-trimethoxysilylpropyl)diethylenetriamine (DAEAPTS) grafted SBA-15 adsorbents were synthesized for CO[subscript 2] capture. The adsorption of CO[subscript 2] on the amine-grafted sorbents was measured by thermogravimetric method over a CO[subscript 2] partial pressure range of 8-101.3 kPa and a temperature range of 25-105 °C under atmospheric pressure. The optimal amine loaded SBA-15 adsorbent was examined for multi-cycle stability and adsorption/desorption kinetics. (2)The performance of structured bed and packed bed configurations for post-combustion CO[subscript 2] capture was evaluated using PEI impregnated SBA-15 adsorbent. The effect of adsorption temperature (25-90 °C), adsorption /desorption kinetics and multi-cycle stability was studied in both structured and packed bed configurations.
Author: Hui Jiang
Publisher:
ISBN:
Category : Amines
Languages : en
Pages : 52
Get Book Here
Book Description
Amine-functionalized solid adsorbents have gained attention within the last decade for their application in carbon dioxide capture, due to their many advantages such as low energy cost for regeneration, tunable structure, elimination of corrosion problems, and additional advantages. However, one of the challenges facing this technology is to accomplish both high CO2 capture capacity along with high CO2 diffusion rates concurrently. Current amine-based solid sorbents such as porous materials similar to SBA-15 have large pores diffusion entering molecules; however, the pores become clogged upon amine inclusion. To meet this challenge, our group's solution involves the creation of a new type of material which we are calling-amino-pillared nanosheet (APN) adsorbents which are generated from layered nanosheet precursors. These materials are being proposed because of their unique lamellar structure which exhibits ability to be modified by organic or inorganic pillars through consecutive swelling and pillaring steps to form large mesoporous interlayer spaces. After the expansion of the layer space through swelling and pillaring, the large pore space can be functionalized with amine groups. This selective functionalization is possible by the choice of amine group introduced. Our choice, large amine molecules, do not access the micropore within each layer; however, either physically or chemically immobilized onto the surface of the mesoporous interlayer space between each layer. The final goal of the research is to investigate the ability to prepare APN adsorbents from a model nanoporous layered materials including nanosheets precursor material MCM-22(P) and nanoporous layered silicate material AMH-3. MCM-22(P) contains 2-dimensional porous channels, 6 membered rings (MB) openings perpendicular to the layers and 10 MB channels in the plane of the layers.1 However, the transport limiting openings (6 MB) to the layers is smaller than CO2 gas molecules.2,3 In contrast, AMH-3 has 3D microporous layers with 8 MB openings in the plane of the layers, as well as perpendicular to the layers, which are larger than CO2 molecules. Based on the structure differences between nanosheets precursor material MCM-22(P) and nanoporous layered silicate material AMH-3, the latter might be more suitable for CO2 capturer application as an APN candidate material. However, none of the assumptions above have been approved experimentally. In this study, the influence of the amine loading on adsorption capacity and kinetics of adsorption for the mixed porosity material pillared MCM-22 (P) (also called MCM-36) is studied systematically, in order to determine a potential route to achieve a final material with both high amine loading and high adsorption capacity. We first synthesized MCM-22(P), followed by swelling and pillaring to create MCM-36. Polymeric amines such as polyethylenimine (PEI) are used as an organic component of the supported amine adsorbents, with varying polymer loadings within the adsorbents used. The kinetics and diffusion properties of carbon dioxide capture on a MCM-36 pillared material impregnated with amine containing Polyethylenimine polymers has been investigated. It was determined that the introduction of amine polymer cannot be used to improve the capture capacity of the support over that of the bare material, due to the fact that with the addition of a high loading of amine polymer the large pore diffusion channels become impossible for carbon dioxide molecules to diffuse through. This sets an upper limit to the capture capacity of polymer impregnated MCM-36 for carbon dioxide which does not surpass that for the initial bare material, and greatly reduces the utility of using this sort of amine-solid adsorbent for carbon capture plans in the future.
Author: Mohammad Reza Rahimpour
Publisher: Woodhead Publishing
ISBN: 0128227583
Category : Science
Languages : en
Pages : 574
Get Book Here
Book Description
Advances in Carbon Capture reviews major implementations of CO2 capture, including absorption, adsorption, permeation and biological techniques. For each approach, key benefits and drawbacks of separation methods and technologies, perspectives on CO2 reuse and conversion, and pathways for future CO2 capture research are explored in depth. The work presents a comprehensive comparison of capture technologies. In addition, the alternatives for CO2 separation from various feeds are investigated based on process economics, flexibility, industrial aspects, purification level and environmental viewpoints. - Explores key CO2 separation and compare technologies in terms of provable advantages and limitations - Analyzes all critical CO2 capture methods in tandem with related technologies - Introduces a panorama of various applications of CO2 capture
Author: Cyril Sunday Ume
Publisher:
ISBN: 9783659195471
Category :
Languages : de
Pages : 0
Get Book Here
Book Description
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 10
Get Book Here
Book Description
