Modern Aspects of Electrochemistry No. 7 PDF Download
Are you looking for read ebook online? Search for your book and save it on your Kindle device, PC, phones or tablets. Download Modern Aspects of Electrochemistry No. 7 PDF full book. Access full book title Modern Aspects of Electrochemistry No. 7 by B. E. Conway. Download full books in PDF and EPUB format.
Author: B. E. Conway
Publisher: Springer Science & Business Media
ISBN: 1468430033
Category : Science
Languages : en
Pages : 424
Get Book Here
Book Description
Despite reductions in the level of research activity in most fields which, for reasons of economic decline, have taken place in the U.S. during the last year or two, world progress in the fundamental aspects has continued actively. An important aspect of such recent work has been the use of nonaqueous solvents in studies on the constitution of the double-layer and electrochemical reactions. Interpretation of the behavior of electrode interfaces in such solvents demands more knowledge of the solvation properties of ions in nonaqueous media. Chapter 1 by Pad ova on "Ionic Solvation in Nonaqueous and Mixed Solvents" gives an up to date review of the present state of knowledge in this field, together with tabulations of data that are likely to be of quantitative value in further investigations of both homogeneous and heterogeneous electrochemistry in such media. Electrochemical studies of cathodic processes in nonaqueous solvents have, in recent years, revealed the role of solvated electrons. These are of interest in new approaches to reductive electro-organic synthesis. Similarly, the generation of hydrated electrons in photo cathodic processes is of great interest. In Chapter 2, by Conway, the conditions under which solvated electrons can arise in electrode processes are critically examined and the electro-organic reactions that hwe been investigated are reviewed. The supposed electro generation of hydrated electrons in the water solvent and as inter mediates in cathodic hydrogen evolution is shown to be unlikely.
Author: B. E. Conway
Publisher: Springer Science & Business Media
ISBN: 1468430033
Category : Science
Languages : en
Pages : 424
Get Book Here
Book Description
Despite reductions in the level of research activity in most fields which, for reasons of economic decline, have taken place in the U.S. during the last year or two, world progress in the fundamental aspects has continued actively. An important aspect of such recent work has been the use of nonaqueous solvents in studies on the constitution of the double-layer and electrochemical reactions. Interpretation of the behavior of electrode interfaces in such solvents demands more knowledge of the solvation properties of ions in nonaqueous media. Chapter 1 by Pad ova on "Ionic Solvation in Nonaqueous and Mixed Solvents" gives an up to date review of the present state of knowledge in this field, together with tabulations of data that are likely to be of quantitative value in further investigations of both homogeneous and heterogeneous electrochemistry in such media. Electrochemical studies of cathodic processes in nonaqueous solvents have, in recent years, revealed the role of solvated electrons. These are of interest in new approaches to reductive electro-organic synthesis. Similarly, the generation of hydrated electrons in photo cathodic processes is of great interest. In Chapter 2, by Conway, the conditions under which solvated electrons can arise in electrode processes are critically examined and the electro-organic reactions that hwe been investigated are reviewed. The supposed electro generation of hydrated electrons in the water solvent and as inter mediates in cathodic hydrogen evolution is shown to be unlikely.
Author: J. O'M Bockris
Publisher:
ISBN:
Category : Electrochemistry
Languages : en
Pages : 381
Get Book Here
Book Description
Author: 3Island Press
Publisher:
ISBN: 9781468430042
Category :
Languages : en
Pages : 428
Get Book Here
Book Description
Author: B. E. Conway
Publisher: Springer Science & Business Media
ISBN: 1461574439
Category : Science
Languages : en
Pages : 497
Get Book Here
Book Description
As the subject of electrochemistry moves into the final quarter of the century, a number of developed areas can be assessed in depth while some new areas provide quantitatively and qualitatively novel data and results. The first chapter, by Kebarle, deals with an example of the latter type of field in which new information of the energetics and equilibria of reactions between ions and solvent molecules is studied in the gas phase and provides interesting basic information for treatments of ions in solution, i.e., ionic solvation. Chapter 2, by Hamann, discusses the behavior of electrolyte solutions under high pressures, a matter of intrinsic interest in relation to ion-solvent interaction and the structural aspects of the properties of ionic solutions, especially in water. This topic is also of current interest with regard to the physical chemistry of the marine environment, especially at great depths. In the article by Bloom and Snook (Chapter 3), models for treatments of molten salt systems are examined quantitatively in relation to the structure of molten ionic liquids and to the statistical mechanical approaches that can be meaningfully made to interpret their properties and electrochemical behavior.
Author: Constantinos G. Vayenas
Publisher: Springer Science & Business Media
ISBN: 0387494898
Category : Science
Languages : en
Pages : 434
Get Book Here
Book Description
This volume analyzes and summarizes recent developments in several key interfacial electrochemical systems in the areas of fuel cell electrocatatalysis, electrosynthesis and electrodeposition. The six Chapters are written by internationally recognized experts in these areas and address both fundamental and practical aspects of several existing or emerging key electrochemical technologies. The Chapter by R. Adzic, N. Marinkovic and M. Vukmirovic provides a lucid and authoritative treatment of the electrochemistry and electrocatalysis of Ruthenium, a key element for the devel- ment of efficient electrodes for polymer electrolyte (PEM) fuel cells. Starting from fundamental surface science studies and interfacial considerations, this up-to-date review by some of the pioneers in this field, provides a deep insight in the complex catalytic-electrocatalytic phenomena occurring at the interfaces of PEM fuel cell electrodes and a comprehensive treatment of recent developments in this extremely important field. Several recent breakthroughs in the design of solid oxide fuel cell (SOFC) anodes and cathodes are described in the Chapter of H. Uchida and M. Watanabe. The authors, who have pioneered several of these developments, provide a lucid presentation d- cribing how careful fundamental investigations of interfacial electrocatalytic anode and cathode phenomena lead to novel electrode compositions and microstructures and to significant practical advances of SOFC anode and cathode stability and enhanced electrocatalysis.
Author: John O M. Bockris
Publisher: Springer Science & Business Media
ISBN: 1461574552
Category : Science
Languages : en
Pages : 440
Get Book Here
Book Description
The present volume contains five chapters covering areas of contemporary interest in the fields of electrolyte solutions, the state of solvent molecules at electrode surfaces, charged colloid interfaces, surface chemistry of oxide electrodes and electro chemistry, and bioelectrochemistry of charge transfer complexes. The first chapter, by Barthel, Wachter, and Gores, covers the topic of conductance of nonaqueous pro tic and aprotic electro lyte solutions. This field is not only of intrinsic interest in itself, illustrating the important departures of ion-transport behavior in organic solvents from that, more well known, in water, but the information and extensive new data presented in this chapter will be of interest to those working with nonaqueous alkali-metal batteries where the conductivity and ion-association behavior of electrolytes in various solvents other than water is of great importance. The second chapter is devoted to a very fundamental and ubiquitous aspect of electrochemistry of electrodes: the state of solvent molecules, adsorbed and oriented, at their surfaces. The role of solvent adsorption and orientation in double-layer proper ties, it will be recalled, remained poorly understood until the early 1960s. This chapter, by Trasatti, gives a thorough account of the present state of knowledge of solvent orientation at electrode interfaces and of the unsuspected (until recent years) role it plays in properties of the double layer and in determining the potential profile at charged metal surfaces in solution.
Author: John O'M. Bockris
Publisher:
ISBN: 9780408704328
Category : Electrochemistry
Languages : en
Pages : 347
Get Book Here
Book Description
Author: J. O'M. Bockris
Publisher: Springer Science & Business Media
ISBN: 1468430009
Category : Science
Languages : en
Pages : 393
Get Book Here
Book Description
In the last decade, the evolution of electrochemistry away from concern with the physical chemistry of solutions to its more fruitful goal in the study of the widespread consequences of the transfer of electric charges across interphases has come to fruition. The turning of technology away from an onward rush, regardless, to progress which takes into account repercussions of techno logical activity on the environment, and the consequent need for a reduction and then termination of the injection of CO into 2 the atmosphere (greenhouse effect), together with a reckoning with air and water pollution in general, ensures a long-term need for advances in a basic knowledge of electrochemical systems, an increased technological use of which seems to arise from the environmental necessities. But a mighty change in attitude needs to spread among electro chemists (indeed, among all surface chemists) concerning the terms and level in which their field is discussed. The treatment of charge transfer reactions has often been made too vaguely, in terms, it seemed, of atom transfer, with the electron-transfer step, the essence of electrochemistry, an implied accompaniment to the transfer of ions across electrical double layers. The treatment has been in terms of classical mechanics, only tenable while inadequate questions were asked concerning the behavior of the electron in the interfacial transfer. No process demands a more exclusively quantal discussion than does electron transfer.
Author: B. E. Conway
Publisher: Springer Science & Business Media
ISBN: 0387258388
Category : Science
Languages : en
Pages : 556
Get Book Here
Book Description
This volume comprises six chapters on aspects of fundamental and applied electrochemical science that will be of interest both to researchers in the basic areas of the subject and to those involved in aspects of electrochemical technologies. Chapter 1 is the first part of a 2-part, major contribution by Joachim Maier on Solid State Electrochemistry: Thermodynamics and Kinetics of Charge Carriers in Solids. Part 2 will follow in volume 39 to be published in year 2005. This contribution reviews modern concepts of the equilibria involving charge carriers in solids in terms of concentrations of defects in solids and at grain-boundaries, including doping effects. Complementarily, kinetics of charge transfer and ion transfer are treated in some detail in relation to conductance, kinetics of surface processes and electrode-kinetics involving solid-state processes. This chapter will be of major interest to electrochemists and physicists in the semiconductor field and that involving ionic solids. In the second chapter, Appleby presents a detailed discussion and review in modern terms of a central aspect of electrochemistry: Electron Transfer Reactions With and Without Ion Transfer. Electron transfer is the most fundamental aspect of most processes at electrode interfaces and is also involved intimately with the homogeneous chemistry of redox reactions in solutions.
Author: Brian E. Conway
Publisher: Springer Science & Business Media
ISBN: 1461321336
Category : Science
Languages : en
Pages : 505
Get Book Here
Book Description
It gives us pleasure in writing the Preface to this volume, in which we tried to bring together a number of stimulating and interesting people discussing physical electrochemistry. The first chapter, by Ashok Vijh, gives a remarkable account of electrochemistry as looked at from a physicist's point of view. Among the revelations of the chapter is that in a recent survey of leading areas in Science, two out of fifteen areas chosen were electrochemical and these two were the only chemical subjects chosen. In Mikhail Vorotyntsev's chapter, one finds a very modern study of the double layer, but tenuously connected with the simpler studies made in the safe harbor of mercury. In the pioneering chapter by Pons et al., one is looking at a cutting edge of electrochemistry at this time-the use of IR spectros copy in modes which allow the first practical determinations of the spectra of adsorbed species at the interface-an area pioneered by Pons himself. In Chapter 4, we have reached photoelectrochemistry once more, but now Tributsch speaks about what has rapidly become the major area of that topic, photoelectrocatalysis. Close to this chapter, and indeed intellectually connected with it, is that by Schmickler and Schultze about electron transfer reac tions at oxide-covered metal electrodes in which theories which are still relatively dubious for metal-solution surfaces are applied to complex systems involving oxides.
