Author: Sergey I. Panov
Publisher:
ISBN:
Category :
Languages : en
Pages : 292
Book Description
Moderate and High Resolution Spectroscopy of Transient Molecular Ions
Author: Sergey I. Panov
Publisher:
ISBN:
Category :
Languages : en
Pages : 292
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 292
Book Description
High-resolution Spectroscopy of Some Transient Molecules
Author: Duck-Lae Joo
Publisher:
ISBN:
Category :
Languages : en
Pages : 678
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 678
Book Description
High Resolution Spectroscopy of Transient Metal-containing Diatomic Molecules
Author: Jamie Jerome Gengler
Publisher:
ISBN: 9781109960365
Category : Diatomic molecules
Languages : en
Pages : 329
Book Description
The near-infrared and visible band systems of the diatomic molecules CaH, FeO, ScS, MnH, RhO, and RhN have been studied utilizing high resolution spectroscopy. Most of these metal-containing species are free radicals and as such provide edifying spectra from which information regarding electronic structure can be gleaned. Directly accessible phenomena modeled by effective Hamiltonian methods are molecular rotation, spin-orbit, spin-spin, spin-rotation, lambda-doubling, magnetic hyperfine interactions, and electric quadrupole interactions. In the case of CaH a deperturbation analysis was performed and in the case of RhN isotopic substitution was analyzed. For CaH, FeO, RhO, and RhN, the application of an external static electric field i.e. Stark effect) allowed determination of permanent electric dipole moments of the ground and excited states probed. For CaH and MnH, the application of an external static magnetic field (i.e. Zeeman effect) allowed determination of effective g-factors. Parameters obtained from the data indirectly allow a description of the molecular orbitals involved, and were also compared to ab initio calculations. Due to the transient nature of these gas phase molecules, production was accomplished via laser ablation of a metal sample and introduction of an appropriate reagent gas. Subsequent supersonic expansion and molecular beam formation then allowed probing of the molecules by Laser Induced Fluorescence (LIF). High-resolution spectra were facilitated by a Continuous-Wave (CW) ring laser. Complementary to this, low or medium resolution spectra were obtained with a pulsed-dye laser (controlled via a homemade Visual Basic 6.0 computer program). Several previously unobserved band systems have been detected as part of a project involving survey scans of Rh metal plus various gas reagents including CH4, SF6, NH3, and D2.
Publisher:
ISBN: 9781109960365
Category : Diatomic molecules
Languages : en
Pages : 329
Book Description
The near-infrared and visible band systems of the diatomic molecules CaH, FeO, ScS, MnH, RhO, and RhN have been studied utilizing high resolution spectroscopy. Most of these metal-containing species are free radicals and as such provide edifying spectra from which information regarding electronic structure can be gleaned. Directly accessible phenomena modeled by effective Hamiltonian methods are molecular rotation, spin-orbit, spin-spin, spin-rotation, lambda-doubling, magnetic hyperfine interactions, and electric quadrupole interactions. In the case of CaH a deperturbation analysis was performed and in the case of RhN isotopic substitution was analyzed. For CaH, FeO, RhO, and RhN, the application of an external static electric field i.e. Stark effect) allowed determination of permanent electric dipole moments of the ground and excited states probed. For CaH and MnH, the application of an external static magnetic field (i.e. Zeeman effect) allowed determination of effective g-factors. Parameters obtained from the data indirectly allow a description of the molecular orbitals involved, and were also compared to ab initio calculations. Due to the transient nature of these gas phase molecules, production was accomplished via laser ablation of a metal sample and introduction of an appropriate reagent gas. Subsequent supersonic expansion and molecular beam formation then allowed probing of the molecules by Laser Induced Fluorescence (LIF). High-resolution spectra were facilitated by a Continuous-Wave (CW) ring laser. Complementary to this, low or medium resolution spectra were obtained with a pulsed-dye laser (controlled via a homemade Visual Basic 6.0 computer program). Several previously unobserved band systems have been detected as part of a project involving survey scans of Rh metal plus various gas reagents including CH4, SF6, NH3, and D2.
High Resolution Electronic Spectroscopy of Small Molecules
Author: Geoffrey Duxbury
Publisher: CRC Press
ISBN: 1482245612
Category : Science
Languages : en
Pages : 310
Book Description
Over recent years electronic spectroscopy has developed significantly, with key applications in atmospheric chemistry, astrophysics and astrochemistry. High Resolution Electronic Spectroscopy of Small Molecules explores both theoretical and experimental approaches to understanding the electronic spectra of small molecules, and explains how this information translates to practice. Professors Geoffrey Duxbury and Alexander Alijah present the links between spectroscopy and photochemistry, and discuss theoretical treatments of the interaction between different electronic states. They provide a thorough discussion of experimental techniques, and explore practical applications. This book will be an indispensable reference for graduate students and researchers in physics and chemistry working on theoretical and practical aspects of electronic spectra, as well as atmospheric scientists, photochemists, kineticists and professional spectroscopists.
Publisher: CRC Press
ISBN: 1482245612
Category : Science
Languages : en
Pages : 310
Book Description
Over recent years electronic spectroscopy has developed significantly, with key applications in atmospheric chemistry, astrophysics and astrochemistry. High Resolution Electronic Spectroscopy of Small Molecules explores both theoretical and experimental approaches to understanding the electronic spectra of small molecules, and explains how this information translates to practice. Professors Geoffrey Duxbury and Alexander Alijah present the links between spectroscopy and photochemistry, and discuss theoretical treatments of the interaction between different electronic states. They provide a thorough discussion of experimental techniques, and explore practical applications. This book will be an indispensable reference for graduate students and researchers in physics and chemistry working on theoretical and practical aspects of electronic spectra, as well as atmospheric scientists, photochemists, kineticists and professional spectroscopists.
Dissertation Abstracts International
Author:
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 824
Book Description
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 824
Book Description
High-resolution Laboratory Spectroscopy of Transient Metal-containing Molecules
Author: Shanshan Yu
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
Handbook of High-resolution Spectroscopy
Author: Martin Quack
Publisher: John Wiley & Sons
ISBN: 0470066539
Category : Science
Languages : en
Pages : 2236
Book Description
The field of High-Resolution Spectroscopy has been considerably extended and even redefined in some areas. Combining the knowledge of spectroscopy, laser technology, chemical computation, and experiments, Handbook of High-Resolution Spectroscopy provides a comprehensive survey of the whole field as it presents itself today, with emphasis on the recent developments. This essential handbook for advanced research students, graduate students, and researchers takes a systematic approach through the range of wavelengths and includes the latest advances in experiment and theory that will help and guide future applications. The first comprehensive survey in high-resolution molecular spectroscopy for over 15 years Brings together the knowledge of spectroscopy, laser technology, chemical computation and experiments Brings the reader up-to-date with the many advances that have been made in recent times Takes the reader through the range of wavelengths, covering all possible techniques such as Microwave Spectroscopy, Infrared Spectroscopy, Raman Spectroscopy, VIS, UV and VUV Combines theoretical, computational and experimental aspects Has numerous applications in a wide range of scientific domains Edited by two leaders in this field Provides an overview of rotational, vibration, electronic and photoelectron spectroscopy Volume 1 - Introduction: Fundamentals of Molecular Spectroscopy Volume 2 - High-Resolution Molecular Spectroscopy: Methods and Results Volume 3 - Special Methods & Applications
Publisher: John Wiley & Sons
ISBN: 0470066539
Category : Science
Languages : en
Pages : 2236
Book Description
The field of High-Resolution Spectroscopy has been considerably extended and even redefined in some areas. Combining the knowledge of spectroscopy, laser technology, chemical computation, and experiments, Handbook of High-Resolution Spectroscopy provides a comprehensive survey of the whole field as it presents itself today, with emphasis on the recent developments. This essential handbook for advanced research students, graduate students, and researchers takes a systematic approach through the range of wavelengths and includes the latest advances in experiment and theory that will help and guide future applications. The first comprehensive survey in high-resolution molecular spectroscopy for over 15 years Brings together the knowledge of spectroscopy, laser technology, chemical computation and experiments Brings the reader up-to-date with the many advances that have been made in recent times Takes the reader through the range of wavelengths, covering all possible techniques such as Microwave Spectroscopy, Infrared Spectroscopy, Raman Spectroscopy, VIS, UV and VUV Combines theoretical, computational and experimental aspects Has numerous applications in a wide range of scientific domains Edited by two leaders in this field Provides an overview of rotational, vibration, electronic and photoelectron spectroscopy Volume 1 - Introduction: Fundamentals of Molecular Spectroscopy Volume 2 - High-Resolution Molecular Spectroscopy: Methods and Results Volume 3 - Special Methods & Applications
Rotational Spectroscopy of Transient Molecular Species
Author: Barrie Ann Shaffer
Publisher:
ISBN:
Category :
Languages : en
Pages : 372
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 372
Book Description
Experimental and Theoretical Investigations of Molecular Ions by Spectroscopy as Well as Ion Mobility and Mass Spectrometry
Author: Daniel Riebe
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
The aim of this thesis was the elucidation of different ionization methods (resonance-enhanced multiphoton ionization - REMPI, electrospray ionization - ESI, atmospheric pressure chemical ionization - APCI) in ion mobility (IM) spectrometry. In order to gain a better understanding of the ionization processes, several spectroscopic, mass spectrometric and theoretical methods were also used. Another focus was the development of experimental techniques, including a high resolution spectrograph and various combinations of IM and mass spectrometry.The novel high resolution 2D spectrograph facilitates spectroscopic resolutions in the range of commercial echelle spectrographs. The lowest full width at half maximum of a peak achieved was 25 pm. The 2D spectrograph is based on the wavelength separation of light by the combination of a prism and a grating in one dimension, and an etalon in the second dimension. This instrument was successfully employed for the acquisition of Raman and laser-induced breakdown spectra.Different spectroscopic ...
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
The aim of this thesis was the elucidation of different ionization methods (resonance-enhanced multiphoton ionization - REMPI, electrospray ionization - ESI, atmospheric pressure chemical ionization - APCI) in ion mobility (IM) spectrometry. In order to gain a better understanding of the ionization processes, several spectroscopic, mass spectrometric and theoretical methods were also used. Another focus was the development of experimental techniques, including a high resolution spectrograph and various combinations of IM and mass spectrometry.The novel high resolution 2D spectrograph facilitates spectroscopic resolutions in the range of commercial echelle spectrographs. The lowest full width at half maximum of a peak achieved was 25 pm. The 2D spectrograph is based on the wavelength separation of light by the combination of a prism and a grating in one dimension, and an etalon in the second dimension. This instrument was successfully employed for the acquisition of Raman and laser-induced breakdown spectra.Different spectroscopic ...
Journal of the Chemical Society
Author:
Publisher:
ISBN:
Category : Chemistry, Physical and theoretical
Languages : en
Pages : 942
Book Description
Publisher:
ISBN:
Category : Chemistry, Physical and theoretical
Languages : en
Pages : 942
Book Description