Lithium Metal Anodes and Rechargeable Lithium Metal Batteries

Lithium Metal Anodes and Rechargeable Lithium Metal Batteries PDF Author: Ji-Guang Zhang
Publisher: Springer
ISBN: 3319440543
Category : Technology & Engineering
Languages : en
Pages : 206

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Book Description
This book provides comprehensive coverage of Lithium (Li) metal anodes for rechargeable batteries. Li is an ideal anode material for rechargeable batteries due to its extremely high theoretical specific capacity (3860 mAh g-1), low density (0.59 g cm-3), and the lowest negative electrochemical potential (−3.040 V vs. standard hydrogenelectrodes). Unfortunately, uncontrollable dendritic Li growth and limited Coulombic efficiency during Li deposition/stripping inherent in these batteries have prevented their practical applications over the past 40 years. With the emergence of post Liion batteries, safe and efficient operation of Li metal anodes has become an enabling technology which may determine the fate of several promising candidates for the next generation energy storage systems, including rechargeable Li-air batteries, Li-S batteries, and Li metal batteries which utilize intercalation compounds as cathodes. In this work, various factors that affect the morphology and Coulombic efficiency of Li anodes are analyzed. The authors also present the technologies utilized to characterize the morphology of Li deposition and the results obtained by modeling of Li dendrite growth. Finally, recent developments, especially the new approaches that enable safe and efficient operation of Li metal anodes at high current densities are reviewed. The urgent need and perspectives in this field are also discussed. The fundamental understanding and approaches presented in this work will be critical for the applicationof Li metal anodes. The general principles and approaches can also be used in other metal electrodes and general electrochemical deposition of metal films.

Lithium Metal Anodes and Rechargeable Lithium Metal Batteries

Lithium Metal Anodes and Rechargeable Lithium Metal Batteries PDF Author: Ji-Guang Zhang
Publisher: Springer
ISBN: 3319440543
Category : Technology & Engineering
Languages : en
Pages : 206

Get Book Here

Book Description
This book provides comprehensive coverage of Lithium (Li) metal anodes for rechargeable batteries. Li is an ideal anode material for rechargeable batteries due to its extremely high theoretical specific capacity (3860 mAh g-1), low density (0.59 g cm-3), and the lowest negative electrochemical potential (−3.040 V vs. standard hydrogenelectrodes). Unfortunately, uncontrollable dendritic Li growth and limited Coulombic efficiency during Li deposition/stripping inherent in these batteries have prevented their practical applications over the past 40 years. With the emergence of post Liion batteries, safe and efficient operation of Li metal anodes has become an enabling technology which may determine the fate of several promising candidates for the next generation energy storage systems, including rechargeable Li-air batteries, Li-S batteries, and Li metal batteries which utilize intercalation compounds as cathodes. In this work, various factors that affect the morphology and Coulombic efficiency of Li anodes are analyzed. The authors also present the technologies utilized to characterize the morphology of Li deposition and the results obtained by modeling of Li dendrite growth. Finally, recent developments, especially the new approaches that enable safe and efficient operation of Li metal anodes at high current densities are reviewed. The urgent need and perspectives in this field are also discussed. The fundamental understanding and approaches presented in this work will be critical for the applicationof Li metal anodes. The general principles and approaches can also be used in other metal electrodes and general electrochemical deposition of metal films.

Metal-Air Batteries

Metal-Air Batteries PDF Author: Xin-bo Zhang
Publisher: John Wiley & Sons
ISBN: 3527342796
Category : Technology & Engineering
Languages : en
Pages : 432

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Book Description
A comprehensive overview of the research developments in the burgeoning field of metal-air batteries An innovation in battery science and technology is necessary to build better power sources for our modern lifestyle needs. One of the main fields being explored for the possible breakthrough is the development of metal-air batteries. Metal-Air Batteries: Fundamentals and Applications offers a systematic summary of the fundamentals of the technology and explores the most recent advances in the applications of metal-air batteries. Comprehensive in scope, the text explains the basics in electrochemical batteries and introduces various species of metal-air batteries. The author-a noted expert in the field-explores the development of metal-air batteries in the order of Li-air battery, sodium-air battery, zinc-air battery and Mg-O2 battery, with the focus on the Li-air battery. The text also addresses topics such as metallic anode, discharge products, parasitic reactions, electrocatalysts, mediator, and X-ray diffraction study in Li-air battery. Metal-Air Batteries provides a summary of future perspectives in the field of the metal-air batteries. This important resource: -Covers various species of metal-air batteries and their components as well as system designation -Contains groundbreaking content that reviews recent advances in the field of metal-air batteries -Focuses on the battery systems which have the greatest potential for renewable energy storage Written for electrochemists, physical chemists, materials scientists, professionals in the electrotechnical industry, engineers in power technology, Metal-Air Batteries offers a review of the fundamentals and the most recent developments in the area of metal-air batteries.

Next Generation Batteries

Next Generation Batteries PDF Author: Kiyoshi Kanamura
Publisher: Springer Nature
ISBN: 9813366680
Category : Technology & Engineering
Languages : en
Pages : 580

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Book Description
In this book, the development of next-generation batteries is introduced. Included are reports of investigations to realize high energy density batteries: Li-air, Li-sulfur, and all solid-state and metal anode (Mg, Al, Zn) batteries. Sulfide and oxide solid electrolytes are also reviewed.A number of relevant aspects of all solid-state batteries with a carbon anode or Li-metal anode are discussed and described: The formation of the cathode; the interface between the cathode (anode) and electrolyte; the discharge and charge mechanisms of the Li-air battery; the electrolyte system for the Li-air battery; and cell construction. The Li-sulfur battery involves a critical problem, namely, the dissolution of intermediates of sulfur during the discharge process. Here, new electrolyte systems for the suppression of intermediate dissolution are discussed. Li-metal batteries with liquid electrolytes also present a significant problem: the dendrite formation of lithium. New separators and electrolytes are introduced to improve the safety and rechargeability of the Li-metal anode. Mg, Al, and Zn metal anodes have been also applied to rechargeable batteries, and in this book, new metal anode batteries are introduced as the generation-after-next batteries.This volume is a summary of ALCA-SPRING projects, which constitute the most extensive research for next-generation batteries in Japan. The work presented in this book is highly informative and useful not only for battery researchers but also for researchers in the fields of electric vehicles and energy storage.

Nonaqueous Electrochemistry

Nonaqueous Electrochemistry PDF Author: Doron Aurbach
Publisher: CRC Press
ISBN: 9780824741389
Category : Science
Languages : en
Pages : 980

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Book Description
An examination of applications of electrochemical techniques to many organic and inorganic compounds that are either unstable or insoluble in water. It focuses on the continuing drive toward miniaturization in electronics met by designs for high-energy density batteries (based on nonaqueous systems). It addresses applications to nonaqueous batteries, supercapacitators, highly sensitive reagents, and electroorganic and electroinorganic synthesis.

Nanomaterials for Lithium-Ion Batteries

Nanomaterials for Lithium-Ion Batteries PDF Author: Rachid Yazami
Publisher: CRC Press
ISBN: 9814316407
Category : Science
Languages : en
Pages : 464

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Book Description
This book covers the most recent advances in the science and technology of nanostructured materials for lithium-ion application. With contributions from renowned scientists and technologists, the chapters discuss state-of-the-art research on nanostructured anode and cathode materials, some already used in commercial batteries and others still in development. They include nanostructured anode materials based on Si, Ge, Sn, and other metals and metal oxides together with cathode materials of olivine, the hexagonal and spinel crystal structures.

Lithium Ion Rechargeable Batteries

Lithium Ion Rechargeable Batteries PDF Author: Kazunori Ozawa
Publisher: John Wiley & Sons
ISBN: 3527644652
Category : Technology & Engineering
Languages : en
Pages : 338

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Book Description
Starting out with an introduction to the fundamentals of lithium ion batteries, this book begins by describing in detail the new materials for all four major uses as cathodes, anodes, separators, and electrolytes. It then goes on to address such critical issues as self-discharge and passivation effects, highlighting lithium ion diffusion and its profound effect on a battery's power density, life cycle and safety issues. The monograph concludes with a detailed chapter on lithium ion battery use in hybrid electric vehicles. Invaluable reading for materials scientists, electrochemists, physicists, and those working in the automobile and electrotechnical industries, as well as those working in computer hardware and the semiconductor industry.

Lithium-Ion Batteries

Lithium-Ion Batteries PDF Author: Masaki Yoshio
Publisher: Springer Science & Business Media
ISBN: 0387344454
Category : Science
Languages : en
Pages : 460

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Book Description
Here in a single source is an up-to-date description of the technology associated with the Li-Ion battery industry. It will be useful as a text for researchers interested in energy conversion for the direct conversion of chemical energy into electrical energy.

Carbon Nanomaterials

Carbon Nanomaterials PDF Author: Yury Gogotsi
Publisher: CRC Press
ISBN: 1466502428
Category : Science
Languages : en
Pages : 516

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Book Description
This book provides information on synthesis, properties, and applications of carbon nanomaterials. With novel materials, such as graphene (atomically flat carbon) or carbon onions (carbon nanospheres), the family of carbon nanomaterials is rapidly growing. This book provides a state-of-the-art overview and in-depth analysis of the most important ca

Encyclopedia of Electrochemical Power Sources

Encyclopedia of Electrochemical Power Sources PDF Author: Jürgen Garche
Publisher: Newnes
ISBN: 0444527451
Category : Science
Languages : en
Pages : 4532

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Book Description
The Encyclopedia of Electrochemical Power Sources is a truly interdisciplinary reference for those working with batteries, fuel cells, electrolyzers, supercapacitors, and photo-electrochemical cells. With a focus on the environmental and economic impact of electrochemical power sources, this five-volume work consolidates coverage of the field and serves as an entry point to the literature for professionals and students alike. Covers the main types of power sources, including their operating principles, systems, materials, and applications Serves as a primary source of information for electrochemists, materials scientists, energy technologists, and engineers Incorporates nearly 350 articles, with timely coverage of such topics as environmental and sustainability considerations

Functional Materials For Next-generation Rechargeable Batteries

Functional Materials For Next-generation Rechargeable Batteries PDF Author: Jiangfeng Ni
Publisher: World Scientific
ISBN: 9811230684
Category : Science
Languages : en
Pages : 229

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Book Description
Over-consumption of fossil fuels has caused deficiency of limited resources and environmental pollution. Hence, deployment and utilization of renewable energy become an urgent need. The development of next-generation rechargeable batteries that store more energy and last longer has been significantly driven by the utilization of renewable energy.This book starts with principles and fundamentals of lithium rechargeable batteries, followed by their designs and assembly. The book then focuses on the recent progress in the development of advanced functional materials, as both cathode and anode, for next-generation rechargeable batteries such as lithium-sulfur, sodium-ion, and zinc-ion batteries. One of the special features of this book is that both inorganic electrode materials and organic materials are included to meet the requirement of high energy density and high safety of future rechargeable batteries. In addition to traditional non-aqueous rechargeable batteries, detailed information and discussion on aqueous batteries and solid-state batteries are also provided.