Kinetics and Dynamics of Oxidation Reactions Involving an Adsorbed CO Species on Bulk and Supported Platinum and Copper-oxide PDF Download
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Author: Michael P. Harold
Publisher:
ISBN:
Category : Carbon monoxide
Languages : en
Pages : 6
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Author: Michael P. Harold
Publisher:
ISBN:
Category : Carbon monoxide
Languages : en
Pages : 6
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Book Description
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 8
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Book Description
The proposed research is an integrated experimental and modeling study of oxidation reactions involving CO as a key player -- be it a reactant, adsorbed intermediate, and/or partial oxidation product -- in the catalytic sequence and chemistry. The reaction systems of interest in the project include CO, formaldehyde, and methanol oxidation by O2 and CO oxidation by NO, on both Pt and copper oxide catalysts. These reactions are of importance in automobile exhaust catalysis. There is a paucity of rate data in the literature for these important environmental control reactions. The goal of this research is to better understand the catalytic chemistry and kinetics of oxidations reactions involving CO as an adsorbed intermediate. Successfully meeting this goal requires an integration of basic kinetic measurements, in situ catalyst surface monitoring, kinetic modeling, and nonlinear mathematical tools.
Author:
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ISBN:
Category :
Languages : en
Pages : 8
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Book Description
The proposed research is an integrated experimental and modeling study of oxidation reactions involving CO as a key player -- be it a reactant, adsorbed intermediate, and/or partial oxidation product -- in the catalytic sequence and chemistry. The reaction systems of interest in the project include CO, formaldehyde, and methanol oxidation by O2 and CO oxidation by NO, on both Pt and copper oxide catalysts. These reactions are of importance in automobile exhaust catalysis. There is a paucity of rate data in the literature for these important environmental control reactions. The goal of this research is to better understand the catalytic chemistry and kinetics of oxidations reactions involving CO as an adsorbed intermediate. Successfully meeting this goal requires an integration of basic kinetic measurements, in situ catalyst surface monitoring, kinetic modeling, and nonlinear mathematical tools.
Author:
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Category :
Languages : en
Pages :
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Author:
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Category : Power resources
Languages : en
Pages : 754
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Author:
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ISBN:
Category :
Languages : en
Pages : 8
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Objectives were to formulate kinetic models/mechanistic sequences, and to develop bifunctional catalysts for selective oxidation of hdyrocarbons. Efforts are reported this year on 3 items: development of Fourier transform infrared emission spectroscopy to monitor near infrared (ir) under reaction conditions (ethylene oxidation on V2O5); kinetics study of methanol oxidation on supported Pt catalysts (methanol-rich feed the CO2 yield exhibits a maximum at an intermediate temperature); and comparative kinetics study of CO oxidation on Pt, Pd, and Rh. The ir spectra of V2O5 show a correlation between the ir features and the degree of surface oxidation. 4 figs. (DLC).
Author:
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ISBN:
Category :
Languages : en
Pages : 8
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Book Description
Objectives were to formulate kinetic models/mechanistic sequences, and to develop bifunctional catalysts for selective oxidation of hdyrocarbons. Efforts are reported this year on 3 items: development of Fourier transform infrared emission spectroscopy to monitor near infrared (ir) under reaction conditions (ethylene oxidation on V2O5); kinetics study of methanol oxidation on supported Pt catalysts (methanol-rich feed the CO2 yield exhibits a maximum at an intermediate temperature); and comparative kinetics study of CO oxidation on Pt, Pd, and Rh. The ir spectra of V2O5 show a correlation between the ir features and the degree of surface oxidation. 4 figs. (DLC).
Author:
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ISBN:
Category : Aeronautics
Languages : en
Pages : 694
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Author:
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ISBN:
Category : Science
Languages : en
Pages : 688
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Author:
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ISBN:
Category : Government publications
Languages : en
Pages : 1400
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