Ions and Ion Pairs and Their Role in Chemical Reactions PDF Download
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Author: J. Smid
Publisher: Elsevier
ISBN: 1483284573
Category : Science
Languages : en
Pages : 145
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Book Description
Ions and Ion Pairs and their Role in Chemical Reactions covers a wide spectrum of ion pairing phenomena. This book focuses on the structure, dynamics, and energetics of ions and ion pairs and their complexes with solvent molecules and ion coordinating ligands in the solid, liquid, and gaseous state. Organized into 12 chapters, this book begins with an overview of the theory and complications involved in dipole moment measurements in slightly conductive polar solvents. This text then explores the measurement of gas phase ion-molecule equilibria by special spectrometric methods. Other chapters consider the NMR experiments on potassium biphenyl, sodium biphenyl, and rubidium biphenyl, dissolved in different solvents. This book discusses as well the ion pair formation of some cyclic conjugated carbanions and nitranions. The final chapter deals with the information obtained from relaxation measurements on processes such as ionic dissociation, aggregation, and solvent separation. This book is a valuable resource for chemists, organic chemists, and quantum chemists.
Author: J. Smid
Publisher: Elsevier
ISBN: 1483284573
Category : Science
Languages : en
Pages : 145
Get Book Here
Book Description
Ions and Ion Pairs and their Role in Chemical Reactions covers a wide spectrum of ion pairing phenomena. This book focuses on the structure, dynamics, and energetics of ions and ion pairs and their complexes with solvent molecules and ion coordinating ligands in the solid, liquid, and gaseous state. Organized into 12 chapters, this book begins with an overview of the theory and complications involved in dipole moment measurements in slightly conductive polar solvents. This text then explores the measurement of gas phase ion-molecule equilibria by special spectrometric methods. Other chapters consider the NMR experiments on potassium biphenyl, sodium biphenyl, and rubidium biphenyl, dissolved in different solvents. This book discusses as well the ion pair formation of some cyclic conjugated carbanions and nitranions. The final chapter deals with the information obtained from relaxation measurements on processes such as ionic dissociation, aggregation, and solvent separation. This book is a valuable resource for chemists, organic chemists, and quantum chemists.
Author: A. C. Knipe
Publisher: John Wiley & Sons
ISBN: 0470319690
Category : Science
Languages : en
Pages : 770
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Book Description
The only book series to summarize the latest progress on organic reaction mechanisms, Organic Reaction Mechanisms, 1979 surveys the development in understanding of the main classes of organic reaction mechanisms reported in the primary scientific literature in 1979. The 15th annual volume in this highly successful series highlights mechanisms of stereo-specific reactions. Reviews are compiled by a team of experienced editors and authors, allowing advanced undergraduates, graduate students, postdocs, and chemists to rely on the volume's continuing quality of selection and presentation.
Author: Christian Reichardt
Publisher: John Wiley & Sons
ISBN: 3527642137
Category : Science
Languages : en
Pages : 722
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Book Description
Now in its 4th edition, this book remains the ultimate reference for all questions regarding solvents and solvent effects in organic chemistry. Retaining its proven concept, there is no other book which covers the subject in so much depth, the handbook is completely updated and contains 15% more content, including new chapters on "Solvents and Green chemistry", "Classification of Solvents by their Environmental Impact", and "Ionic Liquids". An essential part of every organic chemist's library.
Author: Andrew Streitwieser
Publisher: John Wiley & Sons
ISBN: 0470172096
Category : Science
Languages : en
Pages : 354
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Book Description
Progress in Physical Organic Chemistry is dedicated to reviewing the latest investigations into organic chemistry that use quantitative and mathematical methods. These reviews help readers understand the importance of individual discoveries and what they mean to the field as a whole. Moreover, the authors, leading experts in their fields, offer unique and thought-provoking perspectives on the current state of the science and its future directions. With so many new findings published in a broad range of journals, Progress in Physical Organic Chemistry fills the need for a central resource that presents, analyzes, and contextualizes the major advances in the field. The articles published in Progress in Physical Organic Chemistry are not only of interest to scientists working in physical organic chemistry, but also scientists working in the many subdisciplines of chemistry in which physical organic chemistry approaches are now applied, such as biochemistry, pharmaceutical chemistry, and materials and polymer science. Among the topics explored in this series are reaction mechanisms; reactive intermediates; combinatorial strategies; novel structures; spectroscopy; chemistry at interfaces; stereochemistry; conformational analysis; quantum chemical studies; structure-reactivity relationships; solvent, isotope and solid-state effects; long-lived charged, sextet or open-shell species; magnetic, non-linear optical and conducting molecules; and molecular recognition.
Author: National Science Foundation (U.S.)
Publisher:
ISBN:
Category : Engineering
Languages : en
Pages : 728
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Book Description
Author: A. Giraud
Publisher: Springer Science & Business Media
ISBN: 9400997639
Category : Science
Languages : en
Pages : 281
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Book Description
If our eyes were radio rather than optical wide-band detectors it is well known that for us the brightest object in the sky would still be the Sun; that planets, stars and the Milky Way would still shine feebly (and that we would still occasionally be blinded by man-made sources). What is less well known is that quite a different earthbound overcast would hover about us, with its climatic zones, its seasonal changes, its unpredictable storms and scintillating transparence. To be sure, we can get a sort of glimpse of this peculiar type of weather when we tune our receiver to radio broad casting from some remote spot, or photograph the Earth from space at certain specific wavelengths. Nevertheless no one has ever looked at the ionized shroud of the Earth without the help of sophisticated apparatus, and this is one of the reasons why in this domain the phenomena are not easily abstracted from the use of specific techniques. For generations, the study of the ionosphere has been deeply interwoven with the practice of radio communication and detection. Today however, ionospheric physics is best thought of as a branch of space physics; that part of physics which deals with processes at work in the solar system and methods developed for its exploration.
Author:
Publisher:
ISBN:
Category : Engineering
Languages : en
Pages : 718
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Book Description
Author: Felix A. Carroll
Publisher: John Wiley & Sons
ISBN: 1119808642
Category : Science
Languages : en
Pages : 869
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Book Description
PERSPECTIVES ON STRUCTURE AND MECHANISM IN ORGANIC CHEMISTRY “Beyond the basics” physical organic chemistry textbook, written for advanced undergraduates and beginning graduate students Based on the author’s first-hand classroom experience, Perspectives on Structure and Mechanism in Organic Chemistry uses complementary conceptual models to give new perspectives on the structures and reactions of organic compounds, with the overarching goal of helping students think beyond the simple models of introductory organic chemistry courses. Through this approach, the text better prepares readers to develop new ideas in the future. In the 3rd Edition, the author thoroughly updates the topics covered and reorders the contents to introduce computational chemistry earlier and to provide a more natural flow of topics, proceeding from substitution, to elimination, to addition. About 20% of the 438 problems have been either replaced or updated, with answers available in the companion solutions manual. To remind students of the human aspect of science, the text uses the names of investigators throughout the text and references material to original (or accessible secondary or tertiary) literature as a guide for students interested in further reading. Sample topics covered in Perspectives on Structure and Mechanism in Organic Chemistry include: Fundamental concepts of organic chemistry, covering atoms and molecules, heats of formation and reaction, bonding models, and double bonds Density functional theory, quantum theory of atoms in molecules, Marcus Theory, and molecular simulations Asymmetric induction in nucleophilic additions to carbonyl compounds and dynamic effects on reaction pathways Reactive intermediates, covering reaction coordinate diagrams, radicals, carbenes, carbocations, and carbanions Methods of studying organic reactions, including applications of kinetics in studying reaction mechanisms and Arrhenius theory and transition state theory A comprehensive yet accessible reference on the subject, Perspectives on Structure and Mechanism in Organic Chemistry is an excellent learning resource for students of organic chemistry, medicine, and biochemistry. The text is ideal as a primary text for courses entitled Advanced Organic Chemistry at the upper undergraduate and graduate levels.
Author: National Research Council
Publisher: National Academies Press
ISBN: 0309179564
Category : Science
Languages : en
Pages : 116
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Book Description
The search for life in the solar system and beyond has to date been governed by a model based on what we know about life on Earth (terran life). Most of NASA's mission planning is focused on locations where liquid water is possible and emphasizes searches for structures that resemble cells in terran organisms. It is possible, however, that life exists that is based on chemical reactions that do not involve carbon compounds, that occurs in solvents other than water, or that involves oxidation-reduction reactions without oxygen gas. To assist NASA incorporate this possibility in its efforts to search for life, the NRC was asked to carry out a study to evaluate whether nonstandard biochemistry might support life in solar system and conceivable extrasolar environments, and to define areas to guide research in this area. This book presents an exploration of a limited set of hypothetical chemistries of life, a review of current knowledge concerning key questions or hypotheses about nonterran life, and suggestions for future research.
Author: B. Capon
Publisher: John Wiley & Sons
ISBN: 0470318961
Category : Science
Languages : en
Pages : 691
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Book Description
The only book series to summarize the latest progress on organic reaction mechanisms, Organic Reaction Mechanisms, 1972 surveys the development in understanding of the main classes of organic reaction mechanisms reported in the primary scientific literature in 1972. The 8th annual volume in this highly successful series highlights mechanisms of stereo-specific reactions. Reviews are compiled by a team of experienced editors and authors, allowing advanced undergraduates, graduate students, postdocs, and chemists to rely on the volume's continuing quality of selection and presentation.
