Investigation of Modified Speciation for Enhanced Control of Mercury

Investigation of Modified Speciation for Enhanced Control of Mercury PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 10

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Book Description
Mercury was identified as a hazardous air pollutant in Title 3 of the 1990 Clean Air Act Amendments. It has been singled out for particular scrutiny because of its behavior in the environment (bioaccumulation) and its potential for deleterious effects on humans and wildlife. After studying the sources of mercury in the environment, the US Environmental Protection Agency has concluded that coal-fired boilers generate a significant fraction of the total anthropogenic emissions. Therefore, the agency is currently considering whether to impose mercury control requirements on coal-fired boilers in the electric utility industry. However, the costs for potential control measures (such as sorbent injection) can be extremely high. Mercury removal with chloric acid solutions was tested. The presence of NO increased Hg removal. It appeared that both gas-gas and gas-liquids reactions were operating, with the gas-phase reactions involving NO becoming increasingly important as the solute concentration was raised. From these studies, it was concluded that even higher Hg° removals could be obtained if more of the reagent was made available for reaction in the gas phase. For this reason (and also to simulate a more real-world duct-injection process) a new series of tests was initiated in which an ultrasonic atomizer was used to inject small droplets of the oxidizing solutions into a flowing gas stream containing Hg° vapors and other typical flue-gas components. The results of those tests are described in this paper.

Enhanced Control of Mercury Emissions Through Modified Speciation

Enhanced Control of Mercury Emissions Through Modified Speciation PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 14

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Book Description
In anticipation of possible regulations regarding mercury emissions, research efforts sponsored by DOE, EPRI, and others are investigating the risks posed by mercury emissions, improved techniques for measuring those emissions, and possible control measures. The focus in the control research is on techniques that can be used in conjunction with existing flue-gas-cleanup (FGC) systems in order to minimize additional capital costs and operational complexity. Argonne National Laboratory has supported the DOE Fossil Energy Program for over 15 years with research on advanced environmental control technologies. The emphasis in Argonnes̀ work has been on integrated systems that combine control of several pollutants. Specific topics have included spray drying for sulfur dioxide and particulate-matter control with high-sulfur coal, combined sulfur dioxide and nitrogen oxides control technologies, and techniques to enhance mercury control in existing FGC systems. The latter area has focused on low-cost dry sorbents for use with fabric filters or electrostatic precipitators and techniques for improving the capture of mercury in wet flue-gas desulfurization (FGD) systems. This paper presents results from recent work that has studied the effects of several oxidizing agents in combination with typical flue-gas species (e.g., nitrogen oxides and sulfur dioxide) on the oxidation of Hg°.

Proceedings of the American Power Conference

Proceedings of the American Power Conference PDF Author:
Publisher:
ISBN:
Category : Electric power
Languages : en
Pages : 552

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Hazardous and Radioactive Waste Treatment Technologies Handbook

Hazardous and Radioactive Waste Treatment Technologies Handbook PDF Author: Chang H. Oh
Publisher: CRC Press
ISBN: 1420036459
Category : Science
Languages : en
Pages : 790

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Book Description
With detailed photos and schematic system diagrams, the Hazardous and Radioactive Waste Treatment Technologies Handbook provides the latest information on current technologies in the market. Intended as a reference for scientists, engineers, and engineering students, it covers waste-related thermal and non-thermal technologies, separation techniques, and stabilization technologies. It provides an overview of recent waste technologies, for both hazardous chemical wastes and radioactive wastes. By implementing the techniques presented in this book, readers will be able to decide which appropriate technology to use and how to design the equipment for their particular needs.

Control of mercury emissions from coalfired electric utility boilers interim report including errata dated 32102

Control of mercury emissions from coalfired electric utility boilers interim report including errata dated 32102 PDF Author:
Publisher: DIANE Publishing
ISBN: 1428900284
Category :
Languages : en
Pages : 346

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Book Description


Mercury Control

Mercury Control PDF Author: Evan J. Granite
Publisher: John Wiley & Sons
ISBN: 3527329498
Category : Technology & Engineering
Languages : en
Pages : 479

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Book Description
This essential handbook and ready reference offers a detailed overview of the existing and currently researched technologies available for the control of mercury in coal-derived gas streams and that are viable for meeting the strict standards set by environmental protection agencies. Written by an internationally acclaimed author team from government agencies, academia and industry, it details US, EU, Asia-Pacific and other international perspectives, regulations and guidelines.

EM

EM PDF Author:
Publisher:
ISBN:
Category : Air quality management
Languages : en
Pages : 716

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Book Description


Toxicological Effects of Methylmercury

Toxicological Effects of Methylmercury PDF Author: National Research Council
Publisher: National Academies Press
ISBN: 0309171717
Category : Nature
Languages : en
Pages : 364

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Book Description
Mercury is widespread in our environment. Methylmercury, one organic form of mercury, can accumulate up the aquatic food chain and lead to high concentrations in predatory fish. When consumed by humans, contaminated fish represent a public health risk. Combustion processes, especially coal-fired power plants, are major sources of mercury contamination in the environment. The U.S. Environmental Protection Agency (EPA) is considering regulating mercury emissions from those plants. Toxicological Effects of Methylmercury reviews the health effects of methylmercury and discusses the estimation of mercury exposure from measured biomarkers, how differences between individuals affect mercury toxicity, and appropriate statistical methods for analysis of the data and thoroughly compares the epidemiological studies available on methylmercury. Included are discussions of current mercury levels on public health and a delineation of the scientific aspects and policy decisions involved in the regulation of mercury. This report is a valuable resource for individuals interested in the public health effects and regulation of mercury. The report also provides an excellent example of the implications of decisions in the risk assessment process for a larger audience.

Coal Fired Flue Gas Mercury Emission Controls

Coal Fired Flue Gas Mercury Emission Controls PDF Author: Jiang Wu
Publisher: Springer
ISBN: 3662463474
Category : Technology & Engineering
Languages : en
Pages : 163

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Book Description
Mercury (Hg) is one of the most toxic heavy metals, harmful to both the environment and human health. Hg is released into the atmosphere from natural and anthropogenic sources and its emission control has caused much concern. This book introduces readers to Hg pollution from natural and anthropogenic sources and systematically describes coal-fired flue gas mercury emission control in industry, especially from coal-fired power stations. Mercury emission control theory and experimental research are demonstrated, including how elemental mercury is oxidized into oxidized mercury and the effect of flue gas contents on the mercury speciation transformation process. Mercury emission control methods, such as existing APCDs (air pollution control devices) at power stations, sorbent injection, additives in coal combustion and photo-catalytic methods are introduced in detail. Lab-scale, pilot-scale and full-scale experimental studies of sorbent injection conducted by the authors are presented systematically, helping researchers and engineers to understand how this approach reduces the mercury emissions in flue gas and to apply the methods in mercury emission control at coal-fired power stations. Readers will arrive at a comprehensive understanding of various mercury emission control methods that are suitable for industrial applications. The book is intended for scientists, researchers, engineers and graduate students in the fields of energy science and technology, environmental science and technology and chemical engineering.

Developments in FGD

Developments in FGD PDF Author: Hermine N. Soud
Publisher:
ISBN:
Category : Coal mines and mining
Languages : en
Pages : 96

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Book Description