Electron Spin Resonance Spectroscopy of Organic Radicals PDF Download
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Author: Fabian Gerson
Publisher: John Wiley & Sons
ISBN: 352760524X
Category : Science
Languages : de
Pages : 479
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Book Description
Electron spin resonance spectroscopy is the method used to determine the structure and life expectancy of a number of radicals. Written by Fabian Gerson and Walter Huber, top experts in the field of electron spin resonance spectroscopy, this book offers a compact yet readily comprehensible introduction to the modern world of ESR. Thanks to its comprehensive coverage, ranging from fundamental theory right up to the treatment of all important classes of organic radicals and triplet-state molecules that can be analyzed using ESR spectroscopy, this unique book is suitable for users in both research and industry. Instead of using complex mathematical derivations, the authors present a readily understandable approach to the field by interpreting sample spectra and classifying experimental data. In short, the ideal book for newcomers to the subject and an absolute must-have for everyone confronted with ESR spectroscopy and wanting to become acquainted with this widely-used method of analysis.
Author: Fabian Gerson
Publisher: John Wiley & Sons
ISBN: 352760524X
Category : Science
Languages : de
Pages : 479
Get Book
Book Description
Electron spin resonance spectroscopy is the method used to determine the structure and life expectancy of a number of radicals. Written by Fabian Gerson and Walter Huber, top experts in the field of electron spin resonance spectroscopy, this book offers a compact yet readily comprehensible introduction to the modern world of ESR. Thanks to its comprehensive coverage, ranging from fundamental theory right up to the treatment of all important classes of organic radicals and triplet-state molecules that can be analyzed using ESR spectroscopy, this unique book is suitable for users in both research and industry. Instead of using complex mathematical derivations, the authors present a readily understandable approach to the field by interpreting sample spectra and classifying experimental data. In short, the ideal book for newcomers to the subject and an absolute must-have for everyone confronted with ESR spectroscopy and wanting to become acquainted with this widely-used method of analysis.
Author: Fabian Gerson
Publisher: John Wiley & Sons
ISBN: 9783527302758
Category : Science
Languages : de
Pages : 490
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Book Description
Electron spin resonance spectroscopy is the method used to determine the structure and life expectancy of a number of radicals. Written by Fabian Gerson and Walter Huber, top experts in the field of electron spin resonance spectroscopy, this book offers a compact yet readily comprehensible introduction to the modern world of ESR. Thanks to its comprehensive coverage, ranging from fundamental theory right up to the treatment of all important classes of organic radicals and triplet-state molecules that can be analyzed using ESR spectroscopy, this unique book is suitable for users in both research and industry. Instead of using complex mathematical derivations, the authors present a readily understandable approach to the field by interpreting sample spectra and classifying experimental data. In short, the ideal book for newcomers to the subject and an absolute must-have for everyone confronted with ESR spectroscopy and wanting to become acquainted with this widely-used method of analysis.
Author: J. Fraissard
Publisher: Springer Science & Business Media
ISBN: 9401005346
Category : Science
Languages : en
Pages : 652
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Book Description
Magnetic resonance techniques are especially interesting in the study of colloids and interfaces due to their unique ability to elucidate structure, dynamics and function at the atomic and molecular level. This book illustrates the most up to date applications of innovative NMR and EPR techniques, including magnetic resonance imaging and microscopy, to gas-solid and liquid-solid interfaces, organic and biological surfaces, microemulsions, liquid crystals, membranes, structure and dynamics of polymers and micellar systems, and diffusion in heterogeneous systems. A compendium of advanced NMR and EPR techniques and a state of the art description of the power of advanced new methodologies for the study of molecular dynamics and interfaces.
Author: B. Catoire
Publisher: Springer
ISBN: 9783642772160
Category : Science
Languages : en
Pages : 0
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Book Description
E.S.R. techniques which are mature from a fundamental point of view. now constitute a routine investigation tool in chemistry as well as in biophysics in order to study and to follow the behaviour of radical species. Among the practical applications. let us mention for instance : -diffusion phenomena (solid -solid. liquid -solid such as the diffusion of molecules through membranes. films fibers ... ). -study of radical species to improve the elaboration of materials with high added value (composites). -detection of ionised food. -liquid crystals. polymers. -radiochemistry. -targetting of drugs. toxicology. A better understanding of basic phenomena allows to optimize industrial products and processes applied as well as in advanced fields as in well established ones. The high sensivity of ESR Spectroscopy and its derived specific techniques (spin labelling. spin probe. spin trapping ... ) offer information on the fme morphological structure of the matter as well as on its behaviour under various treatments otherwise not available. A Symposium was organized in Lyon (France) in January 1990 to promote the use of ESR. Its originality was to deal with the practical applications of ESR to organic and bioorganic materials. The scope of this meeting was to enlarge the field of application from basic research to more applied subjects and this may concern industrial as well as academic researchers. Moreover. the purpose of this symposium was to promote exchanges between European specialists working in public or private areas.
Author: Patrick Bertrand
Publisher: Springer Nature
ISBN: 3030396630
Category : Science
Languages : en
Pages : 420
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Book Description
Although originally invented and employed by physicists, electron paramagnetic resonance (EPR) spectroscopy has proven to be a very efficient technique for studying a wide range of phenomena in many fields, such as chemistry, biochemistry, geology, archaeology, medicine, biotechnology, and environmental sciences. Acknowledging that not all studies require the same level of understanding of this technique, this book thus provides a practical treatise clearly oriented toward applications, which should be useful to students and researchers of various levels and disciplines. In this book, the principles of continuous wave EPR spectroscopy are progressively, but rigorously, introduced, with emphasis on interpretation of the collected spectra. Each chapter is followed by a section highlighting important points for applications, together with exercises solved at the end of the book. A glossary defines the main terms used in the book, and particular topics, whose knowledge is not required for understanding the main text, are developed in appendices for more inquisitive readers.
Author: Ashutosh K. Shukla
Publisher: John Wiley & Sons
ISBN: 111928631X
Category : Science
Languages : en
Pages : 295
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Book Description
Basic theory, applications, and recent trends in analytical techniques used in crude oil and related products analysis This book covers the application of different spectroscopic methods to characterize crude oil and related products. Its topics are presented in a pedagogical manner so that those new to the subject can better understand the content. The book begins by familiarizing the reader with the rheological characterization of crude oil and related products. Subsequent chapters are directed towards the current trends of different spectroscopic methods for the characterization of crude oil. Analytical Characterization Methods for Crude Oil and Related Products features chapters on: optical interrogation of petroleum asphaltenes (myths and reality); ESR characterization of organic free radicals in petroleum products; high-field, pulsed, and double resonance studies of crude oils and their derivatives; NMR spectroscopy in bitumen characterization; applications of Raman spectroscopy in crude oil and bitumen characterization; and more. Uses a bottom-up approach—starting from the basic theory of the technique followed by its applications and recent trends in crude oil analysis Includes informative content so as to take a technician to the level of using a particular analytical method Covers relevany information so as to enable a manager in the industry to make purchasing decisions Analytical Characterization Methods for Crude Oil and Related Products is aimed at researchers in academia as well as technicians and developers of new analytical methods in the oil industry and related areas. It will also be of interest to professionals, scientists, and graduate students in analytical sciences dealing with oil and environmental analysis.
Author: Anders Lund
Publisher: Springer
ISBN: 9781402012495
Category : Science
Languages : en
Pages : 664
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Book Description
EPR of Free Radicals in Solids: Trends in Methods and Applications presents methods and applications of modern EPR for the study of free radical processes in solids, which so far are only available in the journal literature. The first part of the book, covering trends in methods, contains experimentally oriented chapters on continuous wave and pulsed EPR techniques and special methods involving muon magnetic resonance and optical detection and theory for dynamic studies. New simulation schemes, including the influence of dynamics, are presented as well as advances in the calculation of hyperfine and electronic g-tensors. The second part of the book presents applications involving studies of radiation and photo-induced inorganic and organic radicals in inert matrices, including novel results of quantum effects in small radicals. High-spin molecules and complexes are also considered as well as radical processes in photosynthesis. Recent advances in EPR dosimetry are summarized.
Author: John Wertz
Publisher: Springer Science & Business Media
ISBN: 9400940750
Category : Science
Languages : en
Pages : 510
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Book Description
In the twenty-five years since its discovery by Zavoiskii, the technique of electron spin resonance (ESR) spectroscopy has provided detailed struc tural information on a variety of paramagnetic organic and inorganic sys tems. It is doubtful that even much later than 1945 any chemist would have been so bold as to predict the great diversity of systems which have proved amenable to study by ESR spectroscopy. In this book we have attempted to provide numerous examples of actual ESR spectra to illus trate the wide scope of application. No attempt has been made to present a comprehensive coverage of the literature in any field, but references to reviews and key articles are given throughout the book. This introductory textbook had its origin in lecture notes prepared for an American Chemical Society short course on electron spin resonance. The present version is the result of extensive revision and expansion of the original notes. Experience with such courses has convinced us that there are large numbers of chemists, physicists, and biologists who have a strong interest in electron spin resonance. The mathematical training of most of the short-course students is limited to calculus. Their contact with theories of molecular structure is largely limited to that obtained in an elementary physical chemistry course. It is to an audience of such background that this book is directed.
Author: Gareth R. Eaton
Publisher: Springer Science & Business Media
ISBN: 3211929487
Category : Science
Languages : en
Pages : 192
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Book Description
There is a growing need in both industrial and academic research to obtain accurate quantitative results from continuous wave (CW) electron paramagnetic resonance (EPR) experiments. This book describes various sample-related, instrument-related and software-related aspects of obtaining quantitative results from EPR expe- ments. Some speci?c items to be discussed include: selection of a reference standard, resonator considerations (Q, B ,B ), power saturation, sample position- 1 m ing, and ?nally, the blending of all the factors together to provide a calculation model for obtaining an accurate spin concentration of a sample. This book might, at ?rst glance, appear to be a step back from some of the more advanced pulsed methods discussed in recent EPR texts, but actually quantitative “routine CW EPR” is a challenging technique, and requires a thorough understa- ing of the spectrometer and the spin system. Quantitation of CW EPR can be subdivided into two main categories: (1) intensity and (2) magnetic ?eld/mic- wave frequency measurement. Intensity is important for spin counting. Both re- tive intensity quantitation of EPR samples and their absolute spin concentration of samples are often of interest. This information is important for kinetics, mechanism elucidation, and commercial applications where EPR serves as a detection system for free radicals produced in an industrial process. It is also important for the study of magnetic properties. Magnetic ?eld/microwave frequency is important for g and nuclear hyper?ne coupling measurements that re?ect the electronic structure of the radicals or metal ions.
Author: M. Ikeya
Publisher: World Scientific
ISBN: 9789810212001
Category : Science
Languages : en
Pages : 524
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Book Description
This is the first book covering an interdisciplinary field between microwave spectroscopy of electron paramagnetic resonance (EPR) or electron spin resonance (ESR) and chronology science, radiation dosimetry and ESR (EPR) imaging in material sciences. The main object is to determine the elapsed time with ESR from forensic medicine to the age and radiation dose in earth and space science. This book is written primarily for earth scientists as well as for archaeologists and for physicists and chemists interested in new applications of the method. This book can serve as an undergraduate and graduate school textbook on applications of ESR to geological and archaeological dating, radiation dosimetry and microscopic magnetic resonance imaging (MRI). Introduction to ESR and chronology science and principle of ESR dating and dosimetry are described with applications to actual problems according to materials.
