Effects of Metal Modification on Titanium Dioxide for Photocatalytic Reduction of Carbon Dioxide

Effects of Metal Modification on Titanium Dioxide for Photocatalytic Reduction of Carbon Dioxide PDF Author: Dong Liu
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Effects of Metal Modification on Titanium Dioxide for Photocatalytic Reduction of Carbon Dioxide

Effects of Metal Modification on Titanium Dioxide for Photocatalytic Reduction of Carbon Dioxide PDF Author: Dong Liu
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Photocatalysts

Photocatalysts PDF Author: Sher Bahadar Khan
Publisher: BoD – Books on Demand
ISBN: 178985475X
Category : Science
Languages : en
Pages : 158

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Book Description
This book enlightens the type, chemical structure, and application of photo-catalysts. It covers the recent developments in photo-catalysts and their applications, particularly in photo-catalytic degradation of different organic pollutants, hydrogen production, etc. It provides a concise but complete coverage and overview of photocatalysts and their recent advances for a broad audience: beginners, graduate students, and specialists in both academic and industrial sectors.

Nearly Zero Energy Communities

Nearly Zero Energy Communities PDF Author: Ion Visa
Publisher: Springer
ISBN: 3319632159
Category : Architecture
Languages : en
Pages : 739

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Book Description
This book addresses the main challenges in implementing the concepts that aim to replace the regular fossil-fuels based energy pattern with the novel energy pattern relying on renewable energy. As the built environment is one major energy consumer, well known and exploited by each community member, the challenges addressing the built environment has to be solved with the consistent contribution of the community inhabitants and its administration. The transition phase, which already is under implementation, is represented by the Nearly Zero Energy Communities (nZEC). From the research topics towards the large scale implementation, the nZEC concept is analyzed in this book, starting with the specific issues of the sustainable built environment, beyond the Nearly Zero Energy Buildings towards a more integrated view on the community (Chapter1) and followed by various implementation concepts for renewable heating & cooling (Chapter 2), for renewable electrical energy production at community level (Chapter 3) and for sustainable water use and reuse (Chapter 4). As the topic is still new, specific instruments supporting education and training (Chapter 5) are needed, aiming to provide the knowledge that can drive the communities in the near future and is expected to increase the acceptance towards renewable energy implemented at community level. The sub-chapters of this book are the proceedings of the 5th edition of the Conference for Sustainable Energy, during 19-21 October 2017, organized by the R&D Centre Renewable Energy Systems and Recycling, in the R&D Institute of the Transilvania University of Brasov. This event was organized under the patronage of the International Federation for the Science of Machines and Mechanisms (IFToMM) - the Technical Committee Sustainable Energy Systems, of the European Sustainable Energy Alliance (ESEIA) and of the Romanian Academy of Technical Sciences.

Modification of Titanium Dioxide for Photocatalytic Degradation of Indoor Volatile Organic Compounds

Modification of Titanium Dioxide for Photocatalytic Degradation of Indoor Volatile Organic Compounds PDF Author: Zahra Shayegan
Publisher:
ISBN:
Category :
Languages : en
Pages : 0

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Book Description
The indoor air quality (IAQ) concern has risen since people spend most of their time (>90%) in indoor environments. Volatile organic compounds (VOCs) are categorized as a major group of gas pollutants. Indoor VOCs, known as hazardous compounds with several proven adverse health effects. Among various purification techniques, a heterogeneous photocatalytic oxidation process (PCO) is a promising technology for removing indoor VOC contaminants. Titanium dioxide (TiO2) is the leading candidate for PCO given its unique properties. However, no TiO2-based photocatalysts completely satisfy all practical requirements, considering the photoexcited charge carriers' short lifetime and a wide band gap requiring ultraviolet (UV) radiation. Moreover, the application of PCO for VOCs degradation is greatly hindered at high humidity levels. Herein, TiO2 modification techniques that include approaches for overcoming the inherent TiO2 limitations and improving the photocatalytic degradation of VOCs are studied. In this research, strategies for improving TiO2 photocatalyst activities by doping with different metal and/or non-metal ions as well as surface modification have been examined. Accordingly, the adsorption capacity and photocatalytic activity of P25 and surface fluorinated P25 coated on nickel foam were evaluated for VOCs removal. In addition, the photoactivity of visible-light-driven photocatalysts including; anatase/rutile carbon-doped P25, anatase/brookite cerium-doped TiO2, and anatase/brookite iron-doped TiO2 coated on nickel foam were evaluated for degradation of VOCs under both UV and visible light irradiation. Surface fluorination was then applied to reduce the surface hydrophilicity of Ce-TiO2 and Fe-TiO2 photocatalysts with the optimum Ce and Fe contents. Notably, their photocatalytic performance was investigated in continuous flow mode-of-operation reactors with small residence time, different relative humidity levels, and low-level inlet contaminant concentration. These techniques can improve PCO performance through the following mechanisms: i) by introducing an electron capturing level in the band gap that would generate some defects in the TiO2 lattice and help capture charge carriers and can also be excited under visible irradiation; ii) by slowing down the charge carrier recombination rate and increasing VOCs degradation; and iii) by reducing the surface hydrophilicity, which increases VOCs' adsorption capacity at high humid conditions.

Visible-Light-Active Photocatalysis

Visible-Light-Active Photocatalysis PDF Author: Srabanti Ghosh
Publisher: John Wiley & Sons
ISBN: 3527342931
Category : Science
Languages : en
Pages : 624

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Book Description
A comprehensive and timely overview of this important and hot topic, with special emphasis placed on environmental applications and the potential for solar light harvesting. Following introductory chapters on environmental photocatalysis, water splitting, and applications in synthetic chemistry, further chapters focus on the synthesis and design of photocatalysts, solar energy conversion, and such environmental aspects as the removal of water pollutants, photocatalytic conversion of CO2. Besides metal oxide-based photocatalysts, the authors cover other relevant material classes including carbon-based nanomaterials and novel hybrid materials. Chapters on mechanistic aspects, computational modeling of photocatalysis and Challenges and perspectives of solar reactor design for industrial applications complete this unique survey of the subject. With its in-depth discussions ranging from a comprehensive understanding to the engineering of materials and applied devices, this is an invaluable resource for a range of disciplines.

Photocatalysis

Photocatalysis PDF Author: Dionysios D Dionysiou
Publisher: Royal Society of Chemistry
ISBN: 1782627103
Category : Science
Languages : en
Pages : 395

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Book Description
From environmental remediation to alternative fuels, this book explores the numerous important applications of photocatalysis. The book covers topics such as the photocatalytic processes in the treatment of water and air; the fundamentals of solar photocatalysis; the challenges involved in developing self-cleaning photocatalytic materials; photocatalytic hydrogen generation; photocatalysts in the synthesis of chemicals; and photocatalysis in food packaging and biomedical and medical applications. The book also critically discusses concepts for the future of photocatalysis, providing a fascinating insight for researchers. Together with Photocatalysis: Fundamentals and Perspectives, these volumes provide a complete overview to photocatalysis.

Titanium Dioxide Photocatalysis

Titanium Dioxide Photocatalysis PDF Author: Vladimiro Dal Santo
Publisher: MDPI
ISBN: 3038976946
Category : Science
Languages : en
Pages : 208

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Book Description
Although the seminal work of Fujishima et al. dates back to 1971, TiO2 still remains the most diffused and studied semiconductor, employed in photo-oxidation processes for cleantech (i.e., polluted water and air treatment), in solar fuel production (mainly hydrogen production by water photo splitting), and in Carbon Capture and Utilization (CCU) processes by CO2 photoreduction. The eleven articles, among them three reviews, in this book cover recent results and research trends of various aspects of titanium dioxide photocatalysis, with the chief aim of improving the final efficiency of TiO2-based materials. Strategies include doping, metal co-catalyst deposition, and the realization of composites with plasmonic materials, other semiconductors, and graphene. Photocatalysts with high efficiency and selectivity can be also obtained by controlling the precise crystal shape (and homogeneous size) and the organization in superstructures from ultrathin films to hierarchical nanostructures. Finally, the theoretical modeling of TiO2 nanoparticles is discussed and highlighted. The range of topics addressed in this book will stimulate the reader’s interest as well as provide a valuable source of information for researchers in academia and industry.

Titanium Dioxide

Titanium Dioxide PDF Author: Dongfang Yang
Publisher: BoD – Books on Demand
ISBN: 1789233267
Category : Technology & Engineering
Languages : en
Pages : 520

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Book Description
Titanium dioxide is currently being used in many industrial products. It provides unique photocatalytic properties for water splitting and purification, bacterial inactivation, and organics degradation. It has also been widely used as the photoanode for dye-sensitized solar cells and coatings for self-cleaning surfaces, biomedical implants, and nanomedicine. This book covers various aspects of titanium dioxide nanomaterials including their unique one-dimensional, two-dimensional, mesoporous, and hierarchical nanostructures and their synthetic methods such as sol-gel, hydrothermal, anodic oxidation, and electrophoretic deposition, as well as its key applications in environmental and energy sectors. Through these 24 chapters written by experts from the international scientific community, readers will have access to a comprehensive overview of the recent research and development findings on the titanium dioxide nanomaterials.

CO2 Conversion and Utilization

CO2 Conversion and Utilization PDF Author: Chunshan Song
Publisher: ACS Symposium
ISBN: 9780841237476
Category : Science
Languages : en
Pages : 0

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Book Description
This book focuses on the chemistry and processes for conversion and utilization of carbon dioxide. Topics include CO 2 utilization, its conversion to industrial chemicals and fuels, its coversion via synthesis gas, and new catalysts and chemical processes for conversion.

Modification of Titanium Dioxide Support for Carbon Monoxide Oxidation

Modification of Titanium Dioxide Support for Carbon Monoxide Oxidation PDF Author:
Publisher:
ISBN:
Category : Carbon monoxide
Languages : en
Pages : 212

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This research is to study the effect of surface modification of TiO2 support on the catalytic activity in CO oxidation. Two methods were employed for surface modification of TiO2 support: the creation of defective sites on TiO2 surface and the modification with trace element. The results found that the presence of higher amount of Ti3+ on the larger crystallite size TiO2 stabilizes small metal particles during impregnation, calcination, and reduction steps via stronger metal-support interaction; hence higher CO oxidation activities. In addition, the modification of TiO2 support with trace element can improve the CO oxidation activity. All of element dopants (i.e., Al, Si and P), the Si-modified TiO2 showed the highest catalytic performance of Ag/TiO2 catalyst. However, there existed an optimum content of Si/Ti molar ratio at ca. 0.05-0.1 which resulted in an improved catalytic activity of Ag/TiO2 in CO oxidation. There was no improvement in CO oxidation activity of the Ag/TiO2 catalyst when the Si/Ti was further increased to 0.3 due probably to the formation of amorphous SiO2 instead of the Ti-O-Si bond. The P-modified TiO2 supported Ag catalysts using phosphorus precursor in the form of oxide promoted the weak adsorbed oxygen species and resulted in catalytic activity improvement in CO oxidation.