Development of Novel Catalytic Materials for Removal of Emerging Organic Pollutants by Advanced Oxidation Processes (AOPS) PDF Download
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Author: Shailesh Subhashrao Sable
Publisher:
ISBN:
Category :
Languages : en
Pages : 212
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Book Description
L'objectiu principal del nostre treball és el desenvolupament de nous materials catalítics i mètodes prometedors, eficients i respectuosos amb el medi ambient, per la degradació i la mineralització de contaminants orgànics mitjançant Processos d'Oxidació Avançada (POA) per al tractament d'aigües residuals. Amb aquest propòsit, diverses famílies de catalitzadors han estat sintetitzades per diferents mètodes i s'ha evaluat la seva activitat catalítica en els processos d'oxidació avançada d'ozonització catalítica i el procés Fenton heterogeni, tant per al tractament de compostos farmacèutics emergents com l'àcid clofíbric (CFA) com compostos recalcitrants d'origen industrial com fenol, en condicions ambientals. Entre tots els catalitzadors estudiats en el procés d'ozonització catalítica, el catalitzador d'òxid de Cu-Al preparat per un mètode de co-precipitació, ha mostrat una excel·lent activitat i estabilitat en l'ozonització catalítica de CFA, assolint un 82% i 96% de mineralització en 2 i 6 h, respectivament. En quant al procés Fenton, catalitzadors d'òxid de Fe presentant fases d'hematita i maghemita, i a les que s'han afegit petites quantitats de Pd (Pd/FeOOH) han mostrat molt bons resultats en l'eliminació de CFA mitjançant un procés Fenton heterogeni. En el procés combinat d'adsorció+oxidació, la zeolita ZSM5 contenint Fe i Pd (Pd/Fe-ZSM5) ha presentat una bona activitat en l'eliminació de fenol mitjançant adsorció i oxidació per un procés Fenton heterogeni.
Author: Shailesh Subhashrao Sable
Publisher:
ISBN:
Category :
Languages : en
Pages : 212
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Book Description
L'objectiu principal del nostre treball és el desenvolupament de nous materials catalítics i mètodes prometedors, eficients i respectuosos amb el medi ambient, per la degradació i la mineralització de contaminants orgànics mitjançant Processos d'Oxidació Avançada (POA) per al tractament d'aigües residuals. Amb aquest propòsit, diverses famílies de catalitzadors han estat sintetitzades per diferents mètodes i s'ha evaluat la seva activitat catalítica en els processos d'oxidació avançada d'ozonització catalítica i el procés Fenton heterogeni, tant per al tractament de compostos farmacèutics emergents com l'àcid clofíbric (CFA) com compostos recalcitrants d'origen industrial com fenol, en condicions ambientals. Entre tots els catalitzadors estudiats en el procés d'ozonització catalítica, el catalitzador d'òxid de Cu-Al preparat per un mètode de co-precipitació, ha mostrat una excel·lent activitat i estabilitat en l'ozonització catalítica de CFA, assolint un 82% i 96% de mineralització en 2 i 6 h, respectivament. En quant al procés Fenton, catalitzadors d'òxid de Fe presentant fases d'hematita i maghemita, i a les que s'han afegit petites quantitats de Pd (Pd/FeOOH) han mostrat molt bons resultats en l'eliminació de CFA mitjançant un procés Fenton heterogeni. En el procés combinat d'adsorció+oxidació, la zeolita ZSM5 contenint Fe i Pd (Pd/Fe-ZSM5) ha presentat una bona activitat en l'eliminació de fenol mitjançant adsorció i oxidació per un procés Fenton heterogeni.
Author: Süheyda Atalay
Publisher: Springer
ISBN: 3319289500
Category : Science
Languages : en
Pages : 69
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Book Description
This brief summarizes the role of certain catalysts and associated processes that are involved in the reduction or elimination of hazardous substances from wastewater and the exploitation of renewable raw materials. The authors begin by providing a summary of the most recent developments in catalysts used in the advanced oxidation of organic pollutants in aqueous phase. Advanced Oxidation Processes (AOPS) are described in terms of homogeneous and heterogeneous catalysts. Some emphasis is placed on the role nanocatalysts, perovskite-type catalysts, and green catalysts play in several AOPs such as Fenton Chemistry, photocatalytic oxidation, and the hybrid technologies that combine different processes. Catalyst preparation, characterization, reaction chemistry, and process technology are described. Specific wastewater case studies which illustrate the role of these catalysts in AOPs completes the brief.
Author: Elvis Fosso-Kankeu
Publisher: John Wiley & Sons
ISBN: 1119631416
Category : Science
Languages : en
Pages : 320
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Book Description
Photocatalysts in Advanced Oxidation Processes for Wastewater Treatment comprehensively covers a range of topics aiming to promote the implementation of photocatalysis at large scale through provision of facile and green methods for catalysts synthesis and elucidation of pollutants degradation mechanisms. This book is divided into two main parts namely “Synthesis of effective photocatalysts” (Part I) and “Mechanisms of the photocatalytic degradation of various pollutants” (Part II). The first part focuses on the exploration of various strategies to synthesize sustainable and effective photocatalysts. The second part of the book provides an insights into the photocatalytic degradation mechanisms and pathways under ultraviolet and visible light irradiation, as well as the challenges faced by this technology and its future prospects.
Author: Olívia Salomé G P Soares
Publisher: Mdpi AG
ISBN: 9783036542836
Category : Technology & Engineering
Languages : en
Pages : 136
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Book Description
With the increasing global usage of water and the continuous addition of contaminants to water sources, new challenges have arisen that are associated with the abatement of organic pollutants, particularly those that are refractory to conventional water and wastewater treatment technologies. Advanced oxidation processes (AOPs) present a competitive alternative to promote the oxidation of organic contaminants by strong oxidative radicals generated from oxygen, ozone, wet peroxide, and UV radiation. The use of catalysts not only improves efficiency but may present remarkable cost advantages for practical applications of AOPs in the abatement of several pollutants. In this Special Issue of Catalysts, we invite authors to submit original research papers focused on the synthesis and characterization of novel heterogeneous catalysts and their uses in advanced oxidation processes for the removal of organic pollutants from aqueous solutions.
Author: Cheuk Fung Japhet Law (author)
Publisher:
ISBN:
Category : Electronic books
Languages : en
Pages : 169
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Book Description
In recent years, the increasing release of trace organic chemicals to the aquatic environment have been problematic to both the ecosystem and the human society. These trace organic chemicals, regarded as emerging contaminants, include different categories of chemicals, which are either deemed to be safe for human consumption or they are naturally occurring compounds. As a newly recognized class of emerging contaminant, artificial sweeteners are proven to be one of the most ubiquitous classes of emerging contaminants in environmental waters. Its transformation to different suite of TPs during water treatment processes generated more toxic influence than the parent compound is problematic. The realization of the widespread of emerging contaminants, together with their ambiguous fate and impact to the environment have led to the development of advanced oxidation processes that can effectively attenuate this wide range of contaminants. In this work, several catalytic advanced oxidation processes were studied. On one hand, it aimed to evaluate their effectiveness on the removal of the artificial sweetener – acesulfame; and on the other hand, to shed lights on the future development of catalytic advanced oxidation processes. In the first part of this thesis, the photo-Fenton treatment was evaluated on its potential to effectively remove acesulfame together with the produced transformation products, and the post-treatment toxicity screening. The photo-Fenton treatment was found to be effective in removing both the parent compound and the transformation products, without leading to an increase in toxicity, which is largely related to the effective removal of the transformation products. In attempt to reduce the reliance on UV irradiation, newly synthesized carbon and nitrogen co-doped TiO2-based photocatalyst was applied to capture the simulated sunlight for the degradation of acesulfame. The heterogenous photocatalytic treatment was found to involve several different oxidative reactive species for both degradation and transformation by using several scavengers to alter the degradation profile. Unexpected transformation product was also formed upon treatment in actual water matrix, suggesting the impact of water constituents to the transformation of emerging contaminants. Toxicity results indicated the inability to achieve detoxification, suggesting that a more effective degradation process was needed. To accelerate the degradation process, and enhance the performance at neutral pH, the use of redox mediators for Fenton/Fenton-like system was evaluated. Developed novel Fenton-like system involving copper(II) as transition metal ion, persulfate as oxidant and mercaptosuccinic acid as redox mediator led to effective removal of different contaminants. Elucidation of the proposed oxidation mechanism suggested the role of each components of the system, and the generation of different reactive species for degradation as indicated by the different acesulfame transformation profile obtained. The implementation of redox mediators to Fenton/Fenton-like system was beneficial and an effective approach. In short, this work presents several kinds of catalytic advanced oxidation process and shed lights on improving the degradation performance with directions for the future development of better and more effective water treatment processes.
Author: Aziz, Hamidi Abdul
Publisher: IGI Global
ISBN: 1522557679
Category : Technology & Engineering
Languages : en
Pages : 519
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Book Description
Population growth and industrial development have increased the amount of wastewater generated by urban areas, and one of the major problems facing industrialized nations is the contamination of the environment by hazardous chemicals. Therefore, to meet the standards, suitable treatment alternatives should be established. Advanced Oxidation Processes (AOPs) in Water and Wastewater Treatment is a pivotal reference source that provides vital research on the current, green, and advanced technologies for wastewater treatment. While highlighting topics such as groundwater treatment, environmental legislation, and oxidation processes, this publication explores the contamination of environments by hazardous chemicals as well as the methods of decontamination and the reduction of negative effects on the environment. This book is a vital reference source for environmental engineers, waste authorities, solid waste management companies, landfill operators, legislators, environmentalists, and academicians seeking current research on achieving sustainable management for wastewater treatment.
Author: Marta I. Litter
Publisher: CRC Press
ISBN: 1138001279
Category : Science
Languages : en
Pages : 390
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Book Description
Advanced Oxidation Technologies (AOTs) or Processes (AOPs) are relatively new and innovative technologies to remove harmful and toxic pollutants. The most important processes among them are those using light, such as UVC/H2O2, photo-Fenton and heterogeneous photocatalysis with TiO2. These technologies are also relatively low-cost and therefore useful for countries under development, where the economical resources are scarcer than in developed countries. This book provides a state-of-the-art overview on environmental applications of Advanced Oxidation Technologies (AOTs) as sustainable, low-cost and low-energy consuming treatments for water, air, and soil. It includes information on innovative research and development on TiO2 photocatalytic redox processes, Fenton, Photo-Fenton processes, zerovalent iron technology, and others, highlighting possible applications of AOTs in both developing and industrialized countries around the world in the framework of “A crosscutting and comprehensive look at environmental problems”. The book is aimed at professionals and academics worldwide, working in the areas of water resources, water supply, environmental protection, and will be a useful information source for decision and policy makers and other stakeholders working on solutions for environmental problems.
Author: Suresh C. Ameta
Publisher: Academic Press
ISBN: 0128105259
Category : Science
Languages : en
Pages : 430
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Book Description
Advanced Oxidation Processes for Waste Water Treatment: Emerging Green Chemical Technology is a complete resource covering the fundamentals and applications of all Advanced Oxidation Processes (AOPs). This book presents the most up-to-date research on AOPs and makes the argument that AOPs offer an eco-friendly method of wastewater treatment. In addition to an overview of the fundamentals and applications, it details the reactive species involved, along with sections on reactor designs, thus helping readers understand and implement these methods. - Presents in-depth coverage of all types of Advanced Oxidation Processes, including Super Critical Water Oxidation, Photo-Fenton and Like Processes - Includes a fundamental review, applications, reactive species and reactor designs - Reviews applications across waste types, including industrial waste, domestic and municipal sewage, and hospital wastes
Author: Maulin P. Shah
Publisher: Elsevier
ISBN: 0128226250
Category : Technology & Engineering
Languages : en
Pages : 344
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Book Description
Advanced Oxidation Processes for Effluent Treatment Plants provides a complete overview of the recent advances made in oxidation-based water treatment processes, including their limitations, challenges and potential applications in removing environmental pollutants. The book introduces new trends and advances in environmental bioremediation technology with a thorough discussion of recent developments in this field, with multiple biological and chemical wastewater treatment processes presented in detail. Additionally, every chapter explains the wastewater treatment plants that utilize these methods, illustrating them in terms of plant size, layout, design and installation location. New trends and advances in environmental bioremediation technology are also covered. This is the go-to resources for engineers and scientists requiring an introduction to the principles of environmental bioremediation technologies. - Illustrates the importance of various advance oxidation processes in effluent treatment plants - Highlights the reuse and recovery of resources from wastewater - Examines the occurrence of novel micro-pollutants - Emphasizes the role of nanotechnology in the bioremediation of pollutants - Introduces new trends in environmental bioremediation
Author: Mika Sillanpää
Publisher: Elsevier
ISBN: 0128192283
Category : Technology & Engineering
Languages : en
Pages : 384
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Book Description
Approx.372 pagesApprox.372 pages
