Development of Improved HPLC Analyses for Nitrated Polycyclic Hydrocarbons and Quinones from Airborne Inhalable Particulate Matter PDF Download
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Author: Arthur Greenberg
Publisher:
ISBN:
Category : Air
Languages : en
Pages : 20
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Book Description
Author: Arthur Greenberg
Publisher:
ISBN:
Category : Air
Languages : en
Pages : 20
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Book Description
Author: Yalan Wang
Publisher:
ISBN:
Category : Hydrocarbons
Languages : en
Pages : 156
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Book Description
Studies were conducted to characterized airborne particulate extractable organic matter (EOM) with respect to chemical composition and biological activity. It has been well established that the nitrated polycyclic hydrocarbons (nitroPAH) are environmental contaminants. To identify nitro-PAH in ambient air sample, a technique was developed involving introduction of a reducer column into an reversephase high performance liquid chromatography (HPLC) system. Strong fluorescence signals were achieved from nitro-PAH and detected together with u.v. signals for the qualitative and quantitative analysis of nitro-PAH. 2-Nitrotriptycene was synthesized according to published procedures and used as an internal standard. By use of the above technique, 9nitroanthracene, 1-nitropyrene, 7 -nitrobenz (a) anthracene, 6-nitrochrysene and 6-nitrobenzo(a)pyrene were detected in NBS diesel particulate sample. PAH-quinones may be formed from the appropriate PAH's by their photochemical oxidation in the atmosphere. In this study, an analytical method for the identification of PAH-quinones in airborne particulates was developed. The same HPLC system was employed as that for nitro-PAH. 3,6BaP-dione and 7,8-BaP-dione were identified in both CYC extract and DCM extract of an ambient air sample by using the analytical method developed. Since hydroxynitropyrenes have been identified as making a significant contribution to the mutagenicity of airborne particulate matter, this prompted us to investigate one such compound, 1nitropyren-2-ol. This compound was synthesized according to published procedures. 1-Nitropyren2-ol was detected in one of the ambient air samples and in an NBS diesel particulate sample by using our reverse-phase HPLC system monitoring at 546 nm. To provide more data for estimating the photochemical products of 1nitropyrene, the filters coated with 1nitropyrene were exposed either to sunlight or to u.v. light. The breakdown products were analyzed using HPLC. No 1-nitropyren-2-ol was found in the filters exposed in both ways. Further work is needed to identify the breakdown products.
Author: Arthur Greenberg
Publisher:
ISBN:
Category : Air
Languages : en
Pages : 30
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Author:
Publisher:
ISBN:
Category : Air
Languages : en
Pages : 934
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Author: National Research Council
Publisher: National Academies Press
ISBN: 0309042844
Category : Science
Languages : en
Pages : 338
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Book Description
Most people in the United States spend far more time indoors than outdoors. Yet, many air pollution regulations and risk assessments focus on outdoor air. These often overlook contact with harmful contaminants that may be at their most dangerous concentrations indoors. A new book from the National Research Council explores the need for strategies to address indoor and outdoor exposures and examines the methods and tools available for finding out where and when significant exposures occur. The volume includes: A conceptual framework and common terminology that investigators from different disciplines can use to make more accurate assessments of human exposure to airborne contaminants. An update of important developments in assessing exposure to airborne contaminants: ambient air sampling and physical chemical measurements, biological markers, questionnaires, time-activity diaries, and modeling. A series of examples of how exposure assessments have been applied-properly and improperly-to public health issues and how the committee's suggested framework can be brought into practice. This volume will provide important insights to improve risk assessment, risk management, pollution control, and regulatory programs.
Author:
Publisher:
ISBN:
Category : Power resources
Languages : en
Pages : 852
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Book Description
Author:
Publisher:
ISBN:
Category : Polycyclic aromatic hydrocarbons
Languages : en
Pages : 500
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Book Description
Author: Muharrem Ince
Publisher: BoD – Books on Demand
ISBN: 1789844207
Category : Technology & Engineering
Languages : en
Pages : 100
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Book Description
This book covers hydrocarbon pollution, measurement techniques for hydrocarbons, risk assessment, and environmental impact. This comprehensive book takes a broad view of the subject and integrates a wide variety of approaches. This book attempts to address the needs of graduate and postgraduate students and other professionals or readers interested in food, soil, water, and air pollution. The aim of this book is to explain and clarify important studies, and compare and develop the new and groundbreaking measurement techniques. Written by leading experts in their respective areas, the book is highly recommended to professionals interested in environmental and human health because it provides specific and comprehensive examples.
Author: Richard H. Stadler
Publisher: John Wiley & Sons
ISBN: 0470430095
Category : Technology & Engineering
Languages : en
Pages : 744
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Book Description
Process-Induced Food Toxicants combines the analytical, health, and risk management issues relating to all of the currently known processing-induced toxins that may be present in common foods. It considers the different processing methods used in the manufacture of foods, including thermal treatment, drying, fermentation, preservation, fat processing, and high hydrostatic pressure processing, and the potential contaminants for each method. The book discusses the analysis, formation, mitigation, health risks, and risk management of each hazardous compound. Also discussed are new technologies and the impact of processing on nutrients and allergens.
Author: C. Melber
Publisher: WHO
ISBN:
Category : Medical
Languages : en
Pages : 154
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Book Description
On cover: IPCS International Programme on Chemical Safety. Published under the joint sponsorship of the United Nations Environment Programme, the International Labour Organization and the World Health Organization, and produced within the framework of the Inter-organization Programme for the Sound Management of Chemicals (IOMC)
