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ISBN:
Category :
Languages : en
Pages : 5
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Book Description
A complex pattern of coupling between fluid flow and mass transport develops when heterogeneous reactions occur. For instance, dissolution and precipitation reactions can change a porous medium's physical properties, such as pore geometry and thus permeability. These changes influence fluid flow, which in turn impacts the composition of dissolved constituents and the solid phases, and the rate and direction of advective transport. Two-dimensional modeling studies using TOUGHREACT were conducted to investigate the coupling between flow and transport developed as a consequence of differences in density, dissolution precipitation, and medium heterogeneity. The model includes equilibrium reactions for aqueous species, kinetic reactions between the solid phases and aqueous constituents, and full coupling of porosity and permeability changes resulting from precipitation and dissolution reactions in porous media. In addition, a new permeability relationship is implemented in TOUGHREACT to examine the effects of geochemical reactions and density difference on plume migration in porous media. Generally, the evolutions in the concentrations of the aqueous phase are intimately related to the reaction-front dynamics. Plugging of the medium contributed to significant transients in patterns of flow and mass transport.
Author:
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Category :
Languages : en
Pages : 14
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Book Description
The couplings among chemical reaction rates, advective and diffusive transport in fractured media or soils, and changes in hydraulic properties due to precipitation and dissolution within fractures and in rock matrix are important for both nuclear waste disposal and remediation of contaminated sites. This paper describes the development and application of LEHGC2.0, a mechanistically-based numerical model for simulation of coupled fluid flow and reactive chemical transport including both fast and slow reactions invariably saturated media. Theoretical bases and numerical implementations are summarized, and two example problems are demonstrated. The first example deals with the effect of precipitation-dissolution on fluid flow and matrix diffusion in a two-dimensional fractured media. Because of the precipitation and decreased diffusion of solute from the fracture into the matrix, retardation in the fractured medium is not as large as the case wherein interactions between chemical reactions and transport are not considered. The second example focuses on a complicated but realistic advective-dispersive-reactive transport problem. This example exemplifies the need for innovative numerical algorithms to solve problems involving stiff geochemical reactions.
Author: Mao Bai
Publisher: Amer Society of Civil Engineers
ISBN: 9780784404607
Category : Mathematics
Languages : en
Pages : 334
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Book Description
"Coupled Processes in Subsurface Deformation, Flow, and Transport presents a rational and unified treatment of coupled processes, with emphasis on the coupling and feedbacks present where solid deformation, fluid flow, and solute transport combine, and in the representation of heterogeneous media through multi-porosity approaches. Analytical and numerical solutions are presented for subsurface systems subjected to varying mechanical, thermal, and chemical disturbances."--BOOK JACKET.
Author: Peter C. Lichtner
Publisher: Walter de Gruyter GmbH & Co KG
ISBN: 1501509799
Category : Science
Languages : en
Pages : 452
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Book Description
Volume 34 of Reviews in Mineralogy focuses on methods to describe the extent and consequences of reactive flow and transport in natural subsurface systems. Since the field of reactive transport within the Earth Sciences is a highly multidisciplinary area of research, including geochemistry, geology, physics, chemistry, hydrology, and engineering, this book is an attempt to some extent bridge the gap between these different disciplines. This volume contains the contributions presented at a short course held in Golden, Colorado, October 25-27, 1996 in conjunction with the Mineralogical Society of America's (MSA) Annual Meeting with the Geological Society of America in Denver, Colorado.
Author: National Research Council
Publisher: National Academies Press
ISBN: 0309170990
Category : Science
Languages : en
Pages : 398
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Book Description
Fluid flow and solute transport within the vadose zone, the unsaturated zone between the land surface and the water table, can be the cause of expanded plumes arising from localized contaminant sources. An understanding of vadose zone processes is, therefore, an essential prerequisite for cost-effective contaminant remediation efforts. In addition, because such features are potential avenues for rapid transport of chemicals from contamination sources to the water table, the presence of fractures and other channel-like openings in the vadose zone poses a particularly significant problem, Conceptual Models of Flow and Transport in the Fractured Vadose Zone is based on the work of a panel established under the auspices of the U.S. National Committee for Rock Mechanics. It emphasizes the importance of conceptual models and goes on to review the conceptual model development, testing, and refinement processes. The book examines fluid flow and transport mechanisms, noting the difficulty of modeling solute transport, and identifies geochemical and environmental tracer data as important components of the modeling process. Finally, the book recommends several areas for continued research.
Author: M. Thangarajan
Publisher: CRC Press
ISBN: 1498742858
Category : Science
Languages : en
Pages : 511
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Book Description
Your Guide to Effective Groundwater Management Groundwater Assessment, Modeling, and Management discusses a variety of groundwater problems and outlines the solutions needed to sustain surface and ground water resources on a global scale. Contributors from around the world lend their expertise and provide an international perspective on groundwater management. They address the management of groundwater resources and pollution, waste water treatment methods, and the impact of climate change on groundwater and water availability (specifically in arid and semi-arid regions such as India and Africa). Incorporating management with science and modeling, the book covers all areas of groundwater resource assessment, modeling, and management, and combines hands-on applications with relevant theory. For Water Resource Managers and Decision Makers The book describes techniques for the assessment of groundwater potential, pollution, prevention, and remedial measures, and includes a new approach for groundwater modeling based on connections (network theory). Approximately 30 case studies and six hypothetical studies are introduced reflecting a range of themes that include: groundwater basics and the derivation of groundwater flow equations, exploration and assessment, aquifer parameterization, augmentation of aquifer, water and environment, water and agriculture, the role of models and their application, and water management policies and issues. The book describes remote sensing (RS) applications, geographical information systems (GIS), and electrical resistivity methods to delineate groundwater potential zones. It also takes a look at: Inverse modeling (pilot-points method) Simulation optimization models Radionuclide migration studies through mass transport modeling Modeling for mapping groundwater potential Modeling for vertical 2-D and 3-D groundwater flow Groundwater Assessment, Modeling, and Management explores the management of water resources and the impact of climate change on groundwater. Expert contributors provide practical information on hydrologic engineering and groundwater resources management for students, researchers, scientists, and other practicing professionals in environmental engineering, hydrogeology, irrigation, geophysics, and environmental science.
Author: Robert P. Lowell
Publisher: John Wiley & Sons
ISBN: 1118671899
Category : Science
Languages : en
Pages : 304
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Book Description
Magma to Microbe Published by the American Geophysical Union as part of the Geophysical Monograph Series, Volume 178. Hydrothermal systems at oceanic spreading centers reflect the complex interactions among transport, cooling and crystallization of magma, fluid circulation in the crust, tectonic processes, water-rock interaction, and the utilization of hydrothermal fluids as a metabolic energy source by microbial and macro-biological ecosystems. The development of mathematical and numerical models that address these complex linkages is a fundamental part the RIDGE 2000 program that attempts to quantify and model the transfer of heat and chemicals from “mantle to microbes” at oceanic ridges. This volume presents the first “state of the art” picture of model development in this context. The most outstanding feature of this volume is its emphasis on mathematical and numerical modeling of a broad array of hydrothermal processes associated with oceanic spreading centers. By examining the state of model development in one volume, both cross-fertilization of ideas and integration across the disparate disciplines that study seafloor hydrothermal systems is facilitated. Students and scientists with an interest in oceanic spreading centers in general and more specifically in ridge hydrothermal processes will find this volume to be an up-to-date and indispensable resource.
Author: George D. Redden
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Book Description
Reactions that lead to the formation of mineral precipitates, colloids or growth of biofilms in porous media often depend on the molecular-level diffusive mixing. For example, for the formation of mineral phases, exceeding the saturation index for a mineral is a minimum requirement for precipitation to proceed. Solute mixing frequently occurs at the interface between two solutions each containing one or more soluble reactants, particularly in engineered systems where contaminant degradation or modification or fluid flow are objectives. Although many of the fundamental component processes involved in the deposition or solubilization of solid phases are reasonably well understood, including precipitation equilibrium and kinetics, fluid flow and solute transport, the deposition of chemical precipitates, biofilms and colloidal particles are all coupled to flow, and the science of such coupled processes is not well developed. How such precipitates (and conversely, dissolution of solids) are distributed in the subsurface along flow paths with chemical gradients is a complex and challenging problem. This is especially true in systems that undergo rapid change where equilibrium conditions cannot be assumed, particularly in subsurface systems where reactants are introduced rapidly, compared to most natural flow conditions, and where mixing fronts are generated. Although the concept of dispersion in porous media is frequently used to approximate mixing at macroscopic scales, dispersion does not necessarily describe pore-level or molecular level mixing that must occur for chemical and biological reactions to be possible. An example of coupling between flow, mixing and mineral precipitation, with practical applications to controlling fluid flow or contaminant remediation in subsurface environments is shown in the mixing zone between parallel flowing solutions. Two- and three-dimensional experiments in packed-sand media were conducted where solutions containing calcium and carbonate ions came into contact along a parallel flow boundary and mixed by dispersion and diffusion. The result is the propagation of calcium carbonate precipitates along the solution-solution boundary in the direction of flow. As carbonate precipitates fill the pore space mixing of the two solutions is restricted and therefore precipitation, flow, and transport are coupled. The distribution of carbonate phases is a complex interaction involving precipitation and dissolution kinetics, which are functions of pore-scale saturation indices and solute ratios, heterogeneous vs. homogeneous nucleation and growth mechanisms and changes in porosity and flow. Experimental and modeling results illustrate challenges in understanding the macroscopic and microscopic phenomena that depend on solute mixing, the relevance of molecular and pore-scale processes to the macroscopic behavior, and potential impact on metal mobility in porous media. Mineral precipitation and changes in porosity are simulated at the pore-scale using the Smooth Particle Hydrodynamics method. Macroscopic simulations were performed using discretized, continuum-scale modeling with parameterization representing macroscopic media properties. One of the modeling goals is to use pore-scale simulations to provide the basis for parameterization of macroscopic (more practical) model predictions.
Author: Ravi Naidu
Publisher: CRC Press
ISBN: 1482224488
Category : Nature
Languages : en
Pages : 333
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Book Description
Remediation of groundwater is complex and often challenging. But the cost of pump and treat technology, coupled with the dismal results achieved, has paved the way for newer, better technologies to be developed. Among these techniques is permeable reactive barrier (PRB) technology, which allows groundwater to pass through a buried porous barrier that either captures the contaminants or breaks them down. And although this approach is gaining popularity, there are few references available on the subject. Until now. Permeable Reactive Barrier: Sustainable Groundwater Remediation brings together the information required to plan, design/model, and apply a successful, cost-effective, and sustainable PRB technology. With contributions from pioneers in this area, the book covers state-of-the-art information on PRB technology. It details design criteria, predictive modeling, and application to contaminants beyond petroleum hydrocarbons, including inorganics and radionuclides. The text also examines implementation stages such as the initial feasibility assessment, laboratory treatability studies (including column studies), estimation of PRB design parameters, and development of a long-term monitoring network for the performance evaluation of the barrier. It also outlines the predictive tools required for life cycle analysis and cost/performance assessment. A review of current PRB technology and its applications, this book includes case studies that exemplify the concepts discussed. It helps you determine when to recommend PRB, what information is needed from the site investigation to design it, and what regulatory validation is required.
Author: National Research Council
Publisher: National Academies Press
ISBN: 0309049962
Category : Science
Languages : en
Pages : 568
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Book Description
Scientific understanding of fluid flow in rock fracturesâ€"a process underlying contemporary earth science problems from the search for petroleum to the controversy over nuclear waste storageâ€"has grown significantly in the past 20 years. This volume presents a comprehensive report on the state of the field, with an interdisciplinary viewpoint, case studies of fracture sites, illustrations, conclusions, and research recommendations. The book addresses these questions: How can fractures that are significant hydraulic conductors be identified, located, and characterized? How do flow and transport occur in fracture systems? How can changes in fracture systems be predicted and controlled? Among other topics, the committee provides a geomechanical understanding of fracture formation, reviews methods for detecting subsurface fractures, and looks at the use of hydraulic and tracer tests to investigate fluid flow. The volume examines the state of conceptual and mathematical modeling, and it provides a useful framework for understanding the complexity of fracture changes that occur during fluid pumping and other engineering practices. With a practical and multidisciplinary outlook, this volume will be welcomed by geologists, petroleum geologists, geoengineers, geophysicists, hydrologists, researchers, educators and students in these fields, and public officials involved in geological projects.
