Combustion Driven Ammonia Generation Strategies for Passive Ammonia SCR System

Combustion Driven Ammonia Generation Strategies for Passive Ammonia SCR System PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Book Description
A method for controlling ammonia generation in an exhaust gas feedstream output from an internal combustion engine equipped with an exhaust aftertreatment system including a first aftertreatment device includes executing an ammonia generation cycle to generate ammonia on the first aftertreatment device. A desired air-fuel ratio output from the engine and entering the exhaust aftertreatment system conducive for generating ammonia on the first aftertreatment device is determined. Operation of a selected combination of a plurality of cylinders of the engine is selectively altered to achieve the desired air-fuel ratio entering the exhaust aftertreatment system.

Combustion Driven Ammonia Generation Strategies for Passive Ammonia SCR System

Combustion Driven Ammonia Generation Strategies for Passive Ammonia SCR System PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Book Description
A method for controlling ammonia generation in an exhaust gas feedstream output from an internal combustion engine equipped with an exhaust aftertreatment system including a first aftertreatment device includes executing an ammonia generation cycle to generate ammonia on the first aftertreatment device. A desired air-fuel ratio output from the engine and entering the exhaust aftertreatment system conducive for generating ammonia on the first aftertreatment device is determined. Operation of a selected combination of a plurality of cylinders of the engine is selectively altered to achieve the desired air-fuel ratio entering the exhaust aftertreatment system.

Passive Ammonia-SCR Catalyst System for NOx Abatement from Lean-burn Gasoline Engines

Passive Ammonia-SCR Catalyst System for NOx Abatement from Lean-burn Gasoline Engines PDF Author: Vitaly Y. Prikhodko
Publisher:
ISBN:
Category : Ammonia
Languages : en
Pages : 135

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Book Description
This dissertation summarizes experimental and computational observations from investigations of a selective catalytic reduction (SCR) system for reducing nitrogen oxides (NOx) in lean gasoline engine exhaust based on utilizing ammonia (NH3) generated by a three-way catalyst (TWC) during brief periods of fuel-rich engine operation. NH3 released from the TWC is stored and available to reduce NOx on a downstream SCR catalyst during subsequent periods of lean engine operation. The experimental results include high-speed measurements of transient NH3 formation on the TWC monolith catalysts, as the catalysts were exposed to lean gasoline engine exhaust from a commercial engine. In addition to the experimental investigations, dynamic computational simulations of NH3 generation on the TWC catalyst were implemented to provide more detailed information about NH3 generation on TWCs based on available reaction kinetic mechanisms. Based on the experimental and computational results, estimates of the potential fuel efficiency gains and emissions relevant to simulated drive cycles indicate that passive SCR can potentially achieve significant fuel efficiency benefits while still meeting regulated NOx emissions limits for vehicles powered by lean gasoline engines. However, optimal performance of the system will most likely require development of emission control methods that include accurate models for SCR catalyst NH3 storage and reaction under realistic drive-cycle transients.

Selective Catalytic Reduction Technology for the Control of Nitrogen Oxide Emissions from Coal-Fired Boilers

Selective Catalytic Reduction Technology for the Control of Nitrogen Oxide Emissions from Coal-Fired Boilers PDF Author: Gene Knight
Publisher: DIANE Publishing
ISBN: 1437904726
Category : Technology & Engineering
Languages : en
Pages : 28

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Book Description
The Clean Coal Technology Demo. Program (CCTDP) is an effort to demonstrate a new generation of innovative coal utilization processes in a series of facilities built across the country. These projects are carried out on a commercial scale to prove technical feasibility and provide the info. required for future applications. Projects have demonstrated technical options with the potential to meet the needs of energy markets while satisfying environ. requirements. Part of this program is the demo. of technologies designed to reduce emissions of oxides of nitrogen (NOx) from existing coal-fired utility boilers. This report summarizes the status of selective catalytic reduction (SCR) technology for the control of NOx emissions from high-sulfur, coal-fired boilers. Illus.

Ammonia Synthesis Catalysts

Ammonia Synthesis Catalysts PDF Author: Huazhang Liu
Publisher: World Scientific
ISBN: 981435578X
Category : Science
Languages : en
Pages : 895

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Book Description
This book provides a review of worldwide developments in ammonia synthesis catalysts over the last 30 years. It focuses on the new generation of Fe1-xO based catalysts and ruthenium catalysts - both are major breakthroughs for fused iron catalysts. The basic theory for ammonia synthesis is systematically explained, covering topics such as the chemical components, crystal structure, preparation, reduction, performance evaluation, characterization of the catalysts, the mechanism and kinetics of ammonia synthesis reaction. Both theory and practice are combined in this presentation, with emphasis on the research methods, application and exploitation of catalysts. The comprehensive volume includes an assessment of the economic and engineering aspects of ammonia plants based on the performance of catalysts. Recent developments in photo-catalysis, electro-catalysis, biocatalysis and new uses of ammonia are also introduced in this book. The author, Professor Huazhang Liu, has been engaged in research and practice for more than 50 years in this field and was the inventor of the first Fe1-xO based catalysts in the world. He has done a lot of research on Fe3O4 based- and ruthenium based-catalysts, and has published more than 300 papers and obtained 21 patents during his career.

Ammonia and Hydrogen for Green Energy Transition

Ammonia and Hydrogen for Green Energy Transition PDF Author: Sudarshan Kumar
Publisher: Springer Nature
ISBN: 981970507X
Category :
Languages : en
Pages : 399

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Book Description


Selective Catalytic Reduction of NOx

Selective Catalytic Reduction of NOx PDF Author: Oliver Kröcher
Publisher:
ISBN: 9783038973652
Category :
Languages : en
Pages :

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Book Description
The most efficient process to reduce NOx emissions from lean exhaust gases, selective catalytic reduction (SCR) with ammonia, has undergone tremendous development over the past decades. Originally only applied in stationary power plants and industrial installations, SCR systems are now installed in millions of mobile diesel engines, ranging from off-road machineries, to heavy-duty and light-duty trucks and passenger cars, to locomotives and ships. All of these applications involve specific challenges due to tighter emission limits, new internal combustion engine technologies, or alternative fuels. Three review articles and 14 research articles in this book describe recent results and research trends of various aspects of the SCR process. Reaction engineering aspects, such as the proper dosage of ammonia or urea, respectively, are as important as further developments of the different SCR catalysts, by deepening the understanding of their functionality or by systematic improvements of their properties, such as low-temperature activity, selectivity, or poisoning-resistance. Another covered aspect is cost reduction through the use of cheaper base materials for the production is active and stable SCR catalysts. Finally, research efforts are reported to develop SCR processes with different reducing agents, which would open doors to new applications in the future. The range of topics addressed in this book will stimulate the reader's interest as well as provide a valuable source of information for researchers in academia and industry.

Sustainable Ammonia Production

Sustainable Ammonia Production PDF Author: Inamuddin
Publisher: Springer Nature
ISBN: 3030351068
Category : Technology & Engineering
Languages : en
Pages : 136

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Book Description
This book presents sustainable synthetic pathways and modern applications of ammonia. It focuses on the production of ammonia using various catalytic systems and its use in fuel cells, membrane, agriculture, and renewable energy sectors. The book highlights the history, investigation, and development of sustainable pathways for ammonia production, current challenges, and state-of-the-art reviews. While discussing industrial applications, it fills the gap between laboratory research and viable applications in large-scale production.

A Systematic Approach for Performance Comparisons of NOx Converter Designs

A Systematic Approach for Performance Comparisons of NOx Converter Designs PDF Author: Michelle Bendrich
Publisher:
ISBN:
Category : Ammonia
Languages : en
Pages : 83

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Book Description
In today's vehicle applications, Selective Catalytic Reduction (SCR) ammonia dosing is completed using complex control algorithms that need to be parameterized for the individual catalytic converter technology. The parameterization of these control strategies is not always completed during the early design phase (i.e., simulation studies and laboratory tests), as this procedure is very time consuming. This results in catalytic converter screenings being completed with dosing strategies that do not allow for the observation of the true potential of each catalytic converter. Therefore, a challenge arises in the effective design of catalytic converters. This work presents a simulation-based method for the automated optimization of a simple ammonia dosing strategy, which can easily be used for simulations during the early catalytic converter design phase. The dosing strategy relies on a look-up table whose entries relate a desired ammonia surface coverage to a catalyst temperature. These entries are optimized for a given driving cycle to maximize the NOx conversion and fulfill the desired ammonia slip constraints. Using this strategy, comparisons of SCR catalyst technologies (iron and copper zeolite SCR) and catalyst volumes during driving cycles are completed. Likewise, the dosing strategy is applied to a catalytic converter configuration consisting of a front-end SCR and a back-end Ammonia Slip Catalyst (ASC) to study how an ASC can assist in meeting regulatory requirements during driving cycles.

NOx Trap Catalysts and Technologies

NOx Trap Catalysts and Technologies PDF Author: Luca Lietti
Publisher: Royal Society of Chemistry
ISBN: 1788014758
Category : Science
Languages : en
Pages : 434

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Book Description
Vehicle exhaust emissions, particularly from diesel cars, are considered to be a significant problem for the environment and human health. Lean NOx Trap (LNT) or NOx Storage/Reduction (NSR) technology is one of the current techniques used in the abatement of NOx from lean exhausts. Researchers are constantly searching for new inexpensive catalysts with high efficiency at low temperatures and negligible fuel penalties, to meet the challenges of this field. This book will be the first to comprehensively present the current research on this important area. Covering the technology used, from its development in the early 1990s up to the current state-of-the-art technologies and new legislation. Beginning with the fundamental aspects of the process, the discussion will cover the real application standard through to the detailed modelling of full scale catalysts. Scientists, academic and industrial researchers, engineers working in the automotive sector and technicians working on emission control will find this book an invaluable resource.

Injection Technologies and Mixture Formation Strategies For Spark Ignition and Dual-Fuel Engines

Injection Technologies and Mixture Formation Strategies For Spark Ignition and Dual-Fuel Engines PDF Author: Alessandro Ferrari
Publisher: SAE International
ISBN: 1468603116
Category : Transportation
Languages : en
Pages : 407

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Book Description
Fuel injection systems and performance is fundamental to combustion engine performance in terms of power, noise, efficiency, and exhaust emissions. There is a move toward electric vehicles (EVs) to reduce carbon emissions, but this is unlikely to be a rapid transition, in part due to EV batteries: their size, cost, longevity, and charging capabilities as well as the scarcity of materials to produce them. Until these isssues are resolved, refining the spark-ignited engine is necessary address both sustainability and demand for affordable and reliable mobility. Even under policies oriented to smart sustainable mobility, spark-ignited engines remain strategic, because they can be applied to hybridized EVs or can be fueled with gasoline blended with bioethanol or bio-butanol to drastically reduce particulate matter emissions of direct injection engines in addition to lower CO2 emissions. In this book, Alessandro Ferrari and Pietro Pizzo provide a full review of spark-ignited engine fuel injection systems. The most popular typologies of fuel injection systems are considered, with special focus on state-of-the-art solutions. Dedicated sections on the methods for air mass evaluation, fuel delivery low-pressure modules, and the specific subsystems for idle, cold start, and warm-up control are also included. The authors pay special attention to mixture formation strategies, as they are a fundamental theme for SI engines. An exhaustive overview of fuel injection technologies is provided, and mixture formation strategies for spark ignited combustion engines are considered. Fuel Injection Systems illustrates the performance of these systems and will also serve as a reference for engineers who are active in the aftermarket, offering detailed information on fuel injection system solutions that are mounted in older vehicles.