Characteristics and Applications of Thin Liquid Films Flowing Down High-Curvature Surfaces

Characteristics and Applications of Thin Liquid Films Flowing Down High-Curvature Surfaces PDF Author: Abolfazl Sadeghpour
Publisher:
ISBN:
Category :
Languages : en
Pages : 160

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Book Description
Thin liquid films flowing down vertical fibers present a wealth of complex and interesting interfacial dynamics, including the formation of droplets and traveling wave patterns. Such dynamics is an important consideration in various applications, such as fiber coating and direct-contact heat and mass exchangers which take advantage of extended interfacial areas and larger residence time afforded by the bead formation along the fiber. A rigorous investigation on the fluid dynamics and interfacial heat and mass transfer mechanism of liquid films flowing along vertical strings is, thus, needed to enable physics-based optimization and analysis of multi-string designs for the mentioned applications. This dissertation presents a combination of experimental, numerical, and theoretical study of liquid films flowing down a vertical fiber. Additionally, we report a first-ever combined experimental and theoretical study of the instability in thin film flows of a high-surface energy low-viscosity liquid (i.e. water) along cotton threads. Utilizing our finding, we then adapted the multi-string configuration for novel applications, such as humidification, dehumidification, and particle capturing. We started with a thorough experimental study of viscous liquids flowing down vertical fibers (i.e. polymer strings). Previous researchers suggested that the liquid film thickness and velocity profiles of nearly flat portion of a liquid film that precedes the onset of instability can be specified regardless of the nozzle geometry. As a result, they largely overlooked the effects of nozzle on the pattern and characteristics of the downstream flow. We performed a systematic experimental study by varying the nozzle inner diameter from 0.5 to 3.2 mm at various mass flow rates (from 0.02 to 0.08 g/s). We focused on experimental conditions within the Rayleigh Plateau (RP) instability regime, where traveling wave solution emerges and generates uniformly-spaced drop-like liquid beads on vertical fibers. Our results emphasize the strong influence of nozzle geometry on the flow regime and the flow characteristics. We experimentally measured the thickness of the flat film portion after the nozzle, which we term the preinstability thickness, and identified it as a flow parameter which governs the size, spacing, and velocity of downstream liquid beads. We also performed a set of complementary numerical simulations that solves the full Navier-Stokes equations to predict the fluid dynamics of the downstream flow, such as the liquid velocity profile along the fiber. To better understand the influence of nozzle diameter on the regime transition as well as the downstream bead dynamics, we performed a detailed theoretical study of viscous flow down a vertical fiber. We proposed a full lubrication model that includes slip boundary conditions, nonlinear curvature terms, and a film stabilization term, and compared the predicted film dynamics against the experimental results. Numerical simulations confirm that in addition to fiber sizes and flow rates, the downstream flow regime and characteristics are also significantly affected by the nozzle geometry. Moreover, the effect of film stabilization term on the flow pattern and bead characteristic is studied. We also compared our results with previously studied theoretical methods, such as CM model, linear curvature model, and full curvature model. Additionally, we leveraged our successful demonstration of stable water flow along a vertical cotton string to construct a multi-string water vapor capturing system, where a massive array traveling water beads act as the condensation interface for water vapor in the counterflowing air stream. These water beads form through intrinsic flow instability and offer high curvature surfaces to enhance the vapor condensation rate. The effects of the water flow rate and air velocity on the condensation rates are experimentally characterized. The gas-stream pressure drop of the design is also measured. The condensation rates and gas-stream pressure drop from our multi-string dehumidifier is compared with the existing dehumidifier designs. A simplified theoretical model is also presented as the starting point for further optimizing the design parameters of our device. Finally, we extended our investigation for potential applications of the cotton-based multi-string configuration and proposed a novel string-based particle collector. Wet electrostatic precipitators (WESP) are generally highly effective for collecting fine particles in air streams from various sources such as diesel engines, power plants, and oil refineries. However, some limiting factors, such as high water usage, poses restrictions. Our new compact particle collector utilizes an array of traveling water beads on vertical cotton strings to collect the pre-charged particles in the counterflowing air stream. The experimental and numerical investigation presented in this work is performed to determine the collection efficiency and the optimal water flow rate for our new design. The unique configuration of our string-based counterflow WESP in this study exhibits high number-based collection efficiency, > 80%, for a wide range of particle diameters, 10 nm - 2.5 m, while decreasing the water usage significantly, which can provide a basis for the design of more water-efficient WESPs.

Characteristics and Applications of Thin Liquid Films Flowing Down High-Curvature Surfaces

Characteristics and Applications of Thin Liquid Films Flowing Down High-Curvature Surfaces PDF Author: Abolfazl Sadeghpour
Publisher:
ISBN:
Category :
Languages : en
Pages : 160

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Book Description
Thin liquid films flowing down vertical fibers present a wealth of complex and interesting interfacial dynamics, including the formation of droplets and traveling wave patterns. Such dynamics is an important consideration in various applications, such as fiber coating and direct-contact heat and mass exchangers which take advantage of extended interfacial areas and larger residence time afforded by the bead formation along the fiber. A rigorous investigation on the fluid dynamics and interfacial heat and mass transfer mechanism of liquid films flowing along vertical strings is, thus, needed to enable physics-based optimization and analysis of multi-string designs for the mentioned applications. This dissertation presents a combination of experimental, numerical, and theoretical study of liquid films flowing down a vertical fiber. Additionally, we report a first-ever combined experimental and theoretical study of the instability in thin film flows of a high-surface energy low-viscosity liquid (i.e. water) along cotton threads. Utilizing our finding, we then adapted the multi-string configuration for novel applications, such as humidification, dehumidification, and particle capturing. We started with a thorough experimental study of viscous liquids flowing down vertical fibers (i.e. polymer strings). Previous researchers suggested that the liquid film thickness and velocity profiles of nearly flat portion of a liquid film that precedes the onset of instability can be specified regardless of the nozzle geometry. As a result, they largely overlooked the effects of nozzle on the pattern and characteristics of the downstream flow. We performed a systematic experimental study by varying the nozzle inner diameter from 0.5 to 3.2 mm at various mass flow rates (from 0.02 to 0.08 g/s). We focused on experimental conditions within the Rayleigh Plateau (RP) instability regime, where traveling wave solution emerges and generates uniformly-spaced drop-like liquid beads on vertical fibers. Our results emphasize the strong influence of nozzle geometry on the flow regime and the flow characteristics. We experimentally measured the thickness of the flat film portion after the nozzle, which we term the preinstability thickness, and identified it as a flow parameter which governs the size, spacing, and velocity of downstream liquid beads. We also performed a set of complementary numerical simulations that solves the full Navier-Stokes equations to predict the fluid dynamics of the downstream flow, such as the liquid velocity profile along the fiber. To better understand the influence of nozzle diameter on the regime transition as well as the downstream bead dynamics, we performed a detailed theoretical study of viscous flow down a vertical fiber. We proposed a full lubrication model that includes slip boundary conditions, nonlinear curvature terms, and a film stabilization term, and compared the predicted film dynamics against the experimental results. Numerical simulations confirm that in addition to fiber sizes and flow rates, the downstream flow regime and characteristics are also significantly affected by the nozzle geometry. Moreover, the effect of film stabilization term on the flow pattern and bead characteristic is studied. We also compared our results with previously studied theoretical methods, such as CM model, linear curvature model, and full curvature model. Additionally, we leveraged our successful demonstration of stable water flow along a vertical cotton string to construct a multi-string water vapor capturing system, where a massive array traveling water beads act as the condensation interface for water vapor in the counterflowing air stream. These water beads form through intrinsic flow instability and offer high curvature surfaces to enhance the vapor condensation rate. The effects of the water flow rate and air velocity on the condensation rates are experimentally characterized. The gas-stream pressure drop of the design is also measured. The condensation rates and gas-stream pressure drop from our multi-string dehumidifier is compared with the existing dehumidifier designs. A simplified theoretical model is also presented as the starting point for further optimizing the design parameters of our device. Finally, we extended our investigation for potential applications of the cotton-based multi-string configuration and proposed a novel string-based particle collector. Wet electrostatic precipitators (WESP) are generally highly effective for collecting fine particles in air streams from various sources such as diesel engines, power plants, and oil refineries. However, some limiting factors, such as high water usage, poses restrictions. Our new compact particle collector utilizes an array of traveling water beads on vertical cotton strings to collect the pre-charged particles in the counterflowing air stream. The experimental and numerical investigation presented in this work is performed to determine the collection efficiency and the optimal water flow rate for our new design. The unique configuration of our string-based counterflow WESP in this study exhibits high number-based collection efficiency, > 80%, for a wide range of particle diameters, 10 nm - 2.5 m, while decreasing the water usage significantly, which can provide a basis for the design of more water-efficient WESPs.

Thin Liquid Films

Thin Liquid Films PDF Author: Ralf Blossey
Publisher: Springer Science & Business Media
ISBN: 9400744552
Category : Science
Languages : en
Pages : 158

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Book Description
This book is a treatise on the thermodynamic and dynamic properties of thin liquid films at solid surfaces and, in particular, their rupture instabilities. For the quantitative study of these phenomena, polymer thin films (sometimes referred to as “ultrathin”) have proven to be an invaluable experimental model system. What is it that makes thin film instabilities special and interesting? First, thin polymeric films have an important range of applications. An understanding of their instabilities is therefore of practical relevance for the design of such films. The first chapter of the book intends to give a snapshot of current applications, and an outlook on promising future ones. Second, thin liquid films are an interdisciplinary research topic, which leads to a fairly heterogeneous community working on the topic. It justifies attempting to write a text which gives a coherent presentation of the field which researchers across their specialized communities might be interested in. Finally, thin liquid films are an interesting laboratory for a theorist to confront a well-established theory, hydrodynamics, with its limits. Thin films are therefore a field in which a highly fruitful exchange and collaboration exists between experimentalists and theorists. The book stretches from the more concrete to more abstract levels of study: we roughly progress from applications via theory and experiment to rigorous mathematical theory. For an experimental scientist, the book should serve as a reference and guide to what is the current consensus of the theoretical underpinnings of the field of thin film dynamics. Controversial problems on which such a consensus has not yet been reached are clearly indicated in the text, as well as discussed in a final chapter. From a theoretical point of view, the field of dewetting has mainly been treated in a mathematically ‘light’ yet elegant fashion, often making use of scaling arguments. For the untrained researcher, this approach is not always easy to follow. The present book attempts to bridge between the ‘light’ and the ‘rigorous’, always with the ambition to enhance insight and understanding - and to not let go the elegance of the theory.

Thin Liquid Films

Thin Liquid Films PDF Author: Ivan Ivanov
Publisher: Taylor & Francis
ISBN: 1351408208
Category : Science
Languages : en
Pages : 1141

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Book Description
This comprehensive reference provided a systematic examination of both the theory and applications of thin liquid films - giving a critical review of major concepts and unresolved or controversial problems, as well as revealing experimental methods. It includes results previously unpublished. Combining the work of 20 leading researchers, Thin Liquid Films furnishes a fundamental overview of thermodynamics of thin liquid films. Generously illustrated with equations, tables and drawling and containing more than 2,200 citations to pertinent literature, this is an authoritative reference for physical, surface, and colloid chemists, biophysicists and physicists; chemical engineers and advanced graduate students in chemistry, chemical engineering, biophysics and physics.

Characteristics of Thin Liquid Films Flow on Inclined Surfaces

Characteristics of Thin Liquid Films Flow on Inclined Surfaces PDF Author: Gil Ingel
Publisher:
ISBN:
Category :
Languages : en
Pages : 152

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Book Description


Falling Liquid Films

Falling Liquid Films PDF Author: S. Kalliadasis
Publisher: Springer Science & Business Media
ISBN: 1848823673
Category : Mathematics
Languages : en
Pages : 446

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Book Description
Falling Liquid Films gives a detailed review of state-of-the-art theoretical, analytical and numerical methodologies, for the analysis of dissipative wave dynamics and pattern formation on the surface of a film falling down a planar inclined substrate. This prototype is an open-flow hydrodynamic instability, that represents an excellent paradigm for the study of complexity in active nonlinear media with energy supply, dissipation and dispersion. It will also be of use for a more general understanding of specific events characterizing the transition to spatio-temporal chaos and weak/dissipative turbulence. Particular emphasis is given to low-dimensional approximations for such flows through a hierarchy of modeling approaches, including equations of the boundary-layer type, averaged formulations based on weighted residuals approaches and long-wave expansions. Whenever possible the link between theory and experiment is illustrated, and, as a further bridge between the two, the development of order-of-magnitude estimates and scaling arguments is used to facilitate the understanding of basic, underlying physics. This monograph will appeal to advanced graduate students in applied mathematics, science or engineering undertaking research on interfacial fluid mechanics or studying fluid mechanics as part of their program. It will also be of use to researchers working on both applied, fundamental theoretical and experimental aspects of thin film flows, as well as engineers and technologists dealing with processes involving isothermal or heated films. This monograph is largely self-contained and no background on interfacial fluid mechanics is assumed.

Instabilities and Breakup in Thin Liquid Films

Instabilities and Breakup in Thin Liquid Films PDF Author: Vineeth Chandran Suja
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Book Description
Liquid films having dimensions that are relatively small in the direction normal to their surface are commonly referred to as thin liquid films. Due to their prevalence in nature and due to their unique geometrical characteristics, a comprehensive understanding of thin film dynamics including instabilities and break-up within thin liquid films is of fundamental and practical interest. Practically this understanding is crucial to tuning the stability thin films in a number of important applications such as for stabilizing foams in foods and beverages, destabilizing foams in lubricants, avoiding surface irregularities in liquid coatings and treating ophthalmic disorders originating from the unnatural breakup of the tear film. Fundamentally, the microscopic thickness of these liquid films along with their large surface to volume ratio presents a convenient framework to investigate characteristics of two dimensional flows, and probe the effects of surface phenomenon such as evaporation and surfactant dynamics on fluid flows. Motivated by the importance of thin liquid films, in this thesis, we experimentally investigate the instabilities and break-up within thin liquid films. In the first part of the thesis (Chapters 2 - 4), we develop and optimize experimental tools and protocols for systematically studying thin liquid films. Notably, we show that single bubble/drop experiments are a convenient and complementary technique to study the dynamics of thin liquid films. Subsequently, we detail a new technique for automatically and robustly measuring the spatiotemporal thickness of thin liquid films - hyperspectral interferometry coupled with machine learning. Finally, we will also establish the operating regimes within which the size of bubbles formed on capillaries for single bubble experiments can be precisely controlled to avoid an air compressibility driven shape instabilities. In the subsequent parts of the thesis we utilize the developed tools to study four different problems - Bubble stability in worm like micellar (WLM) polymer solutions (Chapter 5), Lubricant foaming (Chapters 6 - 8), Drying of thin polymer films (Chapter 9) and Dewetting of the tear film (Chapter 10). In Chapter 5, we explore a problem relevant for the cosmetic industry, and characterize the drainage characteristics of thin films between bubbles and flat wormlike micellar solution - air interfaces. The supramolecular structure and elasticity of the wormlike micelles alters the dynamics of film drainage in WLM as compared to those in thin films containing pure surfactants. The unique features of film drainage include film elasticity driven 'dimple recoil' and a single step transition to a Newton black film beyond a critical film thickness. In Chapters 6 - 8, we explore a problem relevant for the lubricant industry, and study the stability of thin liquid films in lubricants with and without antifoams. Utilizing single bubble experiments, we reveal that the stability of thin films between bubbles in lubricant base oils are enhanced by Marangoni flows driven by the differential evaporation of the various components in the oil. Fundamentally, we also show that the spatiotemporal characteristics of these Marangoni flows are regulated by the concentration and volatility of the volatile species in the oil. Interestingly when the concentration of the volatile species approaches 50%, evaporation driven Marangoni flows become chaotic, with disordered spatial structure, chaotic fluctuations, spatially invariant mean film thickness statistics, high sensitivity to initial conditions, rapidly decaying spatial correlation and a power spectrum for thickness fluctuation that obeys a power law scaling that closely resembles the Kolmogorov's -5/3rd scaling. In the presence of filtered lubricants with antifoams, we reveal that the stability of thin films are positively correlated to the number of filtration cycles, and inversely correlated to the nominal filter pore size and the initial antifoam concentration. In Chapter 9 we explore a problem relevant for film coating, and study the drying of aqueous polymer solutions. Depending on the polymer concentration and the polymer diffusivities, we show that a classical Rayleigh-Taylor instability can develop within the drying solution. We also present the scaling laws describing the onset time of the instability as a function of the physical properties and initial polymer concentrations of the solutions. In Chapter 10 we report a platform to characterize the thickness of the tear film in vivo. By qualitatively comparing the dewetting characteristics observed in vivo with in vitro experiments, we will show that the mechanisms of dewetting is influenced by the presence of interfacial rheology. Further we also reveal that the spatial locations that are prone to dewetting are determined by the presence of interfacial rheology and the spatiotemporal drainage characteristics of the tear film. In Chapter 11 we summarize the findings in this thesis and discuss a number of interesting venues for future research.

Thin Liquid Films

Thin Liquid Films PDF Author: I. B. Ivanov
Publisher:
ISBN: 9780203735732
Category : Liquid films
Languages : en
Pages : 0

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Book Description
This comprehensive reference provided a systematic examination of both the theory and applications of thin liquid films - giving a critical review of major concepts and unresolved or controversial problems, as well as revealing experimental methods. It includes results previously unpublished. Combining the work of 20 leading researchers, Thin Liquid Films furnishes a fundamental overview of thermodynamics of thin liquid films. Generously illustrated with equations, tables and drawling and containing more than 2,200 citations to pertinent literature, this is an authoritative reference for physical, surface, and colloid chemists, biophysicists and physicists; chemical engineers and advanced graduate students in chemistry, chemical engineering, biophysics and physics.

Stable Localized Patterns in Thin Liquid Films

Stable Localized Patterns in Thin Liquid Films PDF Author: Robert J. Deissler
Publisher:
ISBN:
Category : Liquid films
Languages : en
Pages : 18

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Book Description


Stability of Thin Liquid Films

Stability of Thin Liquid Films PDF Author: Antonio Iván Jiménez-Laguna
Publisher:
ISBN:
Category :
Languages : en
Pages : 516

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Book Description


Dynamic Evolution of Thin Liquid Films Over Curved Substrates

Dynamic Evolution of Thin Liquid Films Over Curved Substrates PDF Author: Xingyi Shi
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Book Description
We encounter thin liquid films on a daily basis. The micron-thick tear film coating the cornea ensures the clarity of our vision. Pulmonary surfactants coating the air-liquid interface in the alveoli enable us to breath. Lubricant foaming in a gear box can lead to machine degradation and unsafe operations. Textile dye solution films drying unevenly can leave undesirable marks on the fabric. A fundamental understanding of thin liquid film stability is key to optimizing the compositions of the base liquid to suit our needs and applications. In this research, we examine the effects of liquid composition and substrate materials on the dynamics of thin liquid films by building heat and mass transfer models and conducting interferometric experiments via the dynamic fluid-film interferometer. The geometry of a thin liquid film dictates that the liquid-air interactions are critical in affecting the dynamics of the films. Many such interactions can lead to an uneven distribution of surface tension, creating Marangoni flow. The interplay between the Marangoni flow and other physical forces such as capillarity and gravity govern the dynamics of most thin liquid films. A key part of the work focuses on one of the simplest systems that captures all of the major physical forces at play in a thin liquid film: evaporating binary silicone oil films over a glass dome or an air bubble. The binary silicone oil composes of two silicone oils with different viscosity, surface tension, and evaporation rate. Evaporation and the curvature of the substrates create a thin film with varying thickness and composition, thereby surface tension. In the experimental system, a thin film is formed by forcing the curved substrate upward until the apex of the substrate penetrates the initially flat air/liquid interface. The forcing is then stopped and the evolution of the film is recorded by a camera positioned directly above the thin film. Combining experimental observations and theoretical modeling, we elucidate the mechanisms behind the resulting dramatic thin film dynamics. For a binary silicone oil film over a glass dome, at low volume fractions of the less evaporative species ( 0.3%), the liquid film remains axisymmetric and is stabilized by van der Waals interactions and Marangoni flows [1]. At higher concentrations ( 0.35%), the increase in Marangoni flow leads to a film that is more susceptible to ambient disturbances, resulting in asymmetry breakage events [2]. Faster dynamics are observed for an oil film over an air bubble, due to the reduction in resistance to flow. At low volume fractions of the more evaporative species (