A Study of Ion-molecule Reactions Using the Flowing Afterglow Technique PDF Download
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Author: Linda Margaret Parker
Publisher:
ISBN:
Category : Afterglow (Physics)
Languages : en
Pages : 270
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Book Description
Author: Linda Margaret Parker
Publisher:
ISBN:
Category : Afterglow (Physics)
Languages : en
Pages : 270
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Book Description
Author: Ying Zhang
Publisher:
ISBN:
Category :
Languages : en
Pages : 216
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Book Description
Author: Veronica M. Bierbaum
Publisher:
ISBN:
Category :
Languages : en
Pages : 56
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Book Description
A powerful new method has been developed for studying the dynamics of thermal energy ion-molecule reactions. Ion reactions are carried out in a well-characterized, state-of-the-art flowing afterglow apparatus and the excited products are monitored optically. Two complementary techniques are used: direct observation of wavelength dispersed infrared chemiluminescence and laser-induced fluorescence detection, i.e. laser excitation of the product molecules to bound electronic states and detection of the resulting visible fluorescence. The initial vibrational distributions have been determined for products formed in a wide variety of ion-molecule processes, including proton transfer, charge transfer, heavy atom transfer and associative detachment reactions. information on nascent rotational populations and on vibrational deactivation of ions has also been obtained recently. (Author).
Author: J. Franklin
Publisher: Springer Science & Business Media
ISBN: 1475700881
Category : Science
Languages : en
Pages : 394
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Book Description
After a few faint stirrings of interest in ion-molecule reactions during the early days of mass spectrometry, the subject was almost completely neglected for many years. There was a renascence of interest in the subject following pioneering experiments by Tal'roze in Russia and independently by Steven son and Schissler and Field, Franklin, and Lampe in this country. Since that time, interest in the subject has continued to grow and the number of papers published to expand almost exponentially during the past 15 years. The result is a body of literature that is now almost beyond any single individual's capacity for encompassing in his reading and research activities. Thus, it seemed timely to prepare a book giving in some detail a comprehen sive review of the field. Ideally, such a book would be written by one or possibly two authors. Unfortunately, the sheer bulk and variety of the studies of ion-molecule reactions has made it impractical for a single person to prepare a book on the subject in a time that would permit it to be issued before the material covered was obsolete. Consequently, the only practical, although surely not the ideal, solution is to issue a multiauthor volume. The present book represents our best efforts to accomplish this goal. We have secured from 18 authors material representing the most advanced work in the field and the resulting compilation is presented herein.
Author: James M. Farrar
Publisher: Wiley-Interscience
ISBN:
Category : Science
Languages : en
Pages : 680
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Book Description
The first comprehensive collection of all the major techniques used to study gas phase interactions is presented in this volume. With complete coverage of what a given technique can accomplish, its advantages and disadvantages, the book is designed to teach advanced students and researchers entering the field how to investigate a broad range of topics. Included is coverage of traditional topics such as ion cyclotron resonance, as well as more recent innovations, including Fourier transform mass spectrometry and ionic cluster studies. Several diagrams of instrumentation and examples of experimental data are also provided.
Author: Pierre J. Ausloos
Publisher: Springer Science & Business Media
ISBN: 1461329310
Category : Science
Languages : en
Pages : 507
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Book Description
The investigation of the elementary reactions of reactive intermediate species began about half a centruy ago with the advent of free radical kinetics as an active area of chemical research. In spite of the relatively greater ease of detection of a species carrying an electrical charge, and the fact that organic chemists had for decades postulated mechanisms involving ionic intermediates, the systematic study of the elementary reactions of ions was delayed for more than twenty years after the first beginnings of free radical kinetics. Even at this writing, in 1978, the word "kinetics" is considered by many chemists to be synomomous with "kinetics of neutral species". Yet in spite of the relatively late start and separation from the mainstream of kinetics, the field of ion physics and chemistry is fluorishing, and growing at an ever faster pace. Instrumentalists devise ever more sophisticated apparatuses with capabilities of delving into nearly every aspect of the interactions between ions and molecules. Even satellites orbiting the earth are now being used effectively to determine rate coefficients of ionospheric ion-neutral reactions, some of which can not as yet be measured in the laboratory.
Author: J. L. Franklin
Publisher: Springer Science & Business Media
ISBN: 1468419382
Category : Science
Languages : en
Pages : 403
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Book Description
Of Volume 2.- 8. Flowing Afterglow Studies.- 1. Introduction.- 2. Studies Bearing on Intermediate Complex Formation in Thermal Energy Collisions.- 2.1. Temperature Dependence of Slow Ion-Molecule Reactions.- 2.2. Three-Body Reaction Rate Constants.- 2.3. Rotational Excitation in Ion-Neutral Reactions.- 2.4. Miscellaneous Considerations of Intermediate Complex Processes.- 3. Studies Bearing on Negative-Ion Resonance Formation.- 4. Studies Bearing on Energetics.- 5. Conclusions.- References.- 9. Ion Cyclotron Resonance Spectrometry.- 1. Introduction.- 1.1. General Characteristics.- 2. Theoretica.
Author: Robert Jeffrey Schmitt
Publisher:
ISBN:
Category : Afterglow (Physics)
Languages : en
Pages : 260
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Book Description
Author: Karen Knutsen
Publisher:
ISBN:
Category : Charge transfer
Languages : en
Pages : 390
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Book Description
Author: Toshihiro Fujii
Publisher: Springer
ISBN: 1489975888
Category : Science
Languages : en
Pages : 350
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Book Description
This book explores the mechanism of alkali-metal ion/molecule association reaction, surveys the instrumental basis to study its kinetic, and describes the instrumentation to the measurement of alkali-metal ion affinities. The applications of the ion complexation mechanism in the condensed phase in reaction to direct analysis MS are also covered. Other topics include mechanism and reaction rate, experimental and theoretical ion affinities, applications of ion attachment reactions (IAR) to mass spectrometry such as alkali ion CIMS, ion attachment MS and cationization mass spectrometry of ESI, FAB, FD, LD, MALDI and SIMS and topics of IAR-based direct analysis mass spectrometry.
