Vapor-liquid Equilibrium Data for the Binary Systems Ethyl Alcohol-benzene and Ethyl Alcohol-toluene PDF Download
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Author: Joseph C. Landwehr
Publisher:
ISBN:
Category :
Languages : en
Pages : 48
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Author: Joseph C. Landwehr
Publisher:
ISBN:
Category :
Languages : en
Pages : 48
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Author: Andrzej Mączyński
Publisher:
ISBN:
Category : Hydrocarbons
Languages : en
Pages : 282
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Author: James C. K. Ho
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
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This thesis comprises of two parts. The first part is the determination of vapor-liquid equilibrium data at atmospheric pressure and 55°C for the ternary system n-hexane-ethyl alcohol-benzene and for the three possible binary systems n-hexane-ethyl alcohol, n-hexane-benzene and ethyl alcohol-benzene which constituted the ternary system. A modified Gillespie equilibrium still is employed to conduct the investigation. The equilibrium data for the three binary systems and the ternary system appear to be consistent as shown from the thermodynamic consistency tests. The experimental results indicate that two binary systems, namely, n-hexane-ethyl alcohol and ethyl alcohol-benzene form azeotrope at 760 nm. Hg. and 55°C. The ternary system deviates considerably from ideal liquid phase behavior. However, no ternary azeotrope is found from the experiment. The second part presents a method for predicting binary vapor-liquid equilibrium data at various conditions if the equilibrium data for the system concerned are available over the complete concentration range at any one isothermal or isobaric condition. The proposed method is limited to nonazeotropic solutions.
Author: Eduard Hála
Publisher: Elsevier
ISBN: 1483160866
Category : Technology & Engineering
Languages : en
Pages : 624
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Vapor-Liquid Equilibrium, Second Edition covers the theoretical principles and methods of calculation of equilibrium conditions from various experimental data and the elements of measuring technique, as well as the instruments for the direct determination of the equilibrium compositions of the liquid and vapor phases of the system. The book discusses the relations necessary for the thermodynamic treatment of the equilibrium between the liquid and vapor phase of a system; the concept of an ideal solution and auxiliary thermodynamic functions; and the activity and the activity coefficient. The text also describes vapor-liquid equilibrium in real systems (electrolytes and non-electrolytes) and in systems whose components (i.e. temperature, pressure, and composition of phases) mutually react according to several stoichiometric equations. The criteria of purity of substances and the methods of measuring temperature; low, medium, and high pressures; the pressures of the saturated vapors at given temperatures; and the boiling points at given pressures used in laboratory work in the field of vapor-liquid equilibrium are considered. The book also tackles the methods for the direct determination of equilibrium data (distillation, circulation, static, dew and bubble point, and flow methods). The text concludes with a review of the literature on the systems whose vapor-liquid equilibrium data had been measured and reported to the beginning of 1954. Workers in the chemical industry who deal with problems of distillation and rectification will find the book useful.
Author: Jorge A. Guzman
Publisher:
ISBN:
Category : Vapor-liquid equilibrium
Languages : en
Pages : 506
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Author: Ivan Wichterle
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 340
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Author: Ivan Wichterle
Publisher: Elsevier Publishing Company
ISBN:
Category : Vapor-liquid equilibrium
Languages : en
Pages : 1454
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Author: Leon Robert Kiley
Publisher:
ISBN:
Category :
Languages : en
Pages : 534
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Author: P.R. Tandon
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Author: Eduard Hála
Publisher: Pergamon
ISBN:
Category : Science
Languages : en
Pages : 634
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