CRC Handbook of Applied Thermodynamics

CRC Handbook of Applied Thermodynamics PDF Author: David A. Palmer
Publisher: CRC Press
ISBN: 1351079433
Category : Science
Languages : en
Pages : 284

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Book Description
This practical handbook features an overview of the importance of physical properties and thermodynamics; and the use of thermo-dynamics to predict the extent of reaction in proposed new chem-ical combinations. The use of special types of data and pre-diction methods to develop flowsheets for probing projects; and sources of critically evaluated data, dividing the published works into three categories depending on quality are given. Methods of doing one's own critical evaluation of literature, a list of known North American contract experimentalists with the types of data mea-sured by each, methods for measuring equilibrium data, and ther-modynamic concepts to carry out process opti-mization are also featured.

CRC Handbook of Applied Thermodynamics

CRC Handbook of Applied Thermodynamics PDF Author: David A. Palmer
Publisher: CRC Press
ISBN: 1351079433
Category : Science
Languages : en
Pages : 284

Get Book Here

Book Description
This practical handbook features an overview of the importance of physical properties and thermodynamics; and the use of thermo-dynamics to predict the extent of reaction in proposed new chem-ical combinations. The use of special types of data and pre-diction methods to develop flowsheets for probing projects; and sources of critically evaluated data, dividing the published works into three categories depending on quality are given. Methods of doing one's own critical evaluation of literature, a list of known North American contract experimentalists with the types of data mea-sured by each, methods for measuring equilibrium data, and ther-modynamic concepts to carry out process opti-mization are also featured.

Vapor-liquid Equilibrium, Azeotropes, Extractive Distillation

Vapor-liquid Equilibrium, Azeotropes, Extractive Distillation PDF Author: Arthur Rose
Publisher:
ISBN:
Category : Azeotropes
Languages : en
Pages : 164

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Book Description


The Experimental Determination of Solubilities

The Experimental Determination of Solubilities PDF Author: G. T. Hefter
Publisher: John Wiley & Sons
ISBN: 0470864273
Category : Science
Languages : en
Pages : 658

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Book Description
* Guidelines are provided on the reliability of various methods, as well as information for selecting the appropriate technique. * Unique coverage of the whole range of solubility measurements. * Very useful for investigators interested in embarking upon solubility measurements.

Phase Equilibria in Chemical Engineering

Phase Equilibria in Chemical Engineering PDF Author: Stanley M. Walas
Publisher: Butterworth-Heinemann
ISBN: 1483145085
Category : Science
Languages : en
Pages : 689

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Book Description
Phase Equilibria in Chemical Engineering is devoted to the thermodynamic basis and practical aspects of the calculation of equilibrium conditions of multiple phases that are pertinent to chemical engineering processes. Efforts have been made throughout the book to provide guidance to adequate theory and practice. The book begins with a long chapter on equations of state, since it is intimately bound up with the development of thermodynamics. Following material on basic thermodynamics and nonidealities in terms of fugacities and activities, individual chapters are devoted to equilibria primarily between pairs of phases. A few topics that do not fit into these categories and for which the state of the art is not yet developed quantitatively have been relegated to a separate chapter. The chapter on chemical equilibria is pertinent since many processes involve simultaneous chemical and phase equilibria. Also included are chapters on the evaluation of enthalpy and entropy changes of nonideal substances and mixtures, and on experimental methods. This book is intended as a reference and self-study as well as a textbook either for full courses in phase equilibria or as a supplement to related courses in the chemical engineering curriculum. Practicing engineers concerned with separation technology and process design also may find the book useful.

Bibliography of Vapor-liquid Equilibrium Data for Hydrocarbon Systems

Bibliography of Vapor-liquid Equilibrium Data for Hydrocarbon Systems PDF Author: American Petroleum Institute. Division of Refining
Publisher:
ISBN:
Category : Distillation
Languages : en
Pages : 72

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Book Description


Thermodynamic Models

Thermodynamic Models PDF Author: Michael L. Michelsen
Publisher:
ISBN: 9788798996132
Category : Phase rule and equilibrium
Languages : en
Pages : 382

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Book Description


Phase Equilibrium Engineering

Phase Equilibrium Engineering PDF Author: Esteban Alberto Brignole
Publisher: Newnes
ISBN: 044459471X
Category : Technology & Engineering
Languages : en
Pages : 347

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Book Description
Traditionally, the teaching of phase equilibria emphasizes the relationships between the thermodynamic variables of each phase in equilibrium rather than its engineering applications. This book changes the focus from the use of thermodynamics relationships to compute phase equilibria to the design and control of the phase conditions that a process needs. Phase Equilibrium Engineering presents a systematic study and application of phase equilibrium tools to the development of chemical processes. The thermodynamic modeling of mixtures for process development, synthesis, simulation, design and optimization is analyzed. The relation between the mixture molecular properties, the selection of the thermodynamic model and the process technology that could be applied are discussed. A classification of mixtures, separation process, thermodynamic models and technologies is presented to guide the engineer in the world of separation processes. The phase condition required for a given reacting system is studied at subcritical and supercritical conditions. The four cardinal points of phase equilibrium engineering are: the chemical plant or process, the laboratory, the modeling of phase equilibria and the simulator. The harmonization of all these components to obtain a better design or operation is the ultimate goal of phase equilibrium engineering. - Methodologies are discussed using relevant industrial examples - The molecular nature and composition of the process mixture is given a key role in process decisions - Phase equilibrium diagrams are used as a drawing board for process implementation

Phase Behavior of Petroleum Reservoir Fluids

Phase Behavior of Petroleum Reservoir Fluids PDF Author: Karen Schou Pedersen
Publisher: CRC Press
ISBN: 1420018256
Category : Science
Languages : en
Pages : 423

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Book Description
Understanding the phase behavior of the various fluids present in a petroleum reservoir is essential for achieving optimal design and cost-effective operations in a petroleum processing plant. Taking advantage of the authors' experience in petroleum processing under challenging conditions, Phase Behavior of Petroleum Reservoir Fluids introdu

Phase Equilibrium Engineering

Phase Equilibrium Engineering PDF Author: Esteban Brignole
Publisher: Elsevier Inc. Chapters
ISBN: 0128082666
Category : Science
Languages : en
Pages : 41

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Book Description
The application of the principles of phase equilibrium engineering to the development of two innovative technologies for the production of biofuels is discussed in this chapter. The first technology is the production of biodiesel by transesterification of vegetable oils with supercritical methanol; the second, the extraction and dehydration of alcohols by near-critical dual effect solvents that exhibit good solvent power to extract alcohols and water entrainment effect to dehydrate the extracted alcohol. In the first case, the complexity of the reacting system, the large size asymmetry, and strong molecular interactions of the mixture components: methanol, vegetable oils, fatty esters, and glycerin precluded the design and analysis of the process conditions based on thermodynamic model predictions. Therefore, in this case, a systematic approach based on experimental studies was used to unveil the phase scenario and the physical properties required for the design and optimization of this technology. The conceptual design of extraction and dehydration of alcohols by near-critical solvents followed a different path. The process development was initially based on very limited experimental information. In this case, an equation of state for highly nonideal systems was the main tool for exploration of the process conditions over a wide range of pressures, temperatures, and compositions. This equation of state was based on a group contribution approach (GC-EOS) that allowed extrapolating the scarce experimental information available not only in pressure, temperature, and composition but also in molecular structure. The basic conceptual design was later confirmed by experimental information and pilot plant studies. In this case, the design of the experimental studies was guided by the process conceptual design. The experimental results provided key information for the upgrading of the thermodynamic model.

Phase Behavior of Petroleum Reservoir Fluids

Phase Behavior of Petroleum Reservoir Fluids PDF Author: Karen Schou Pedersen
Publisher: CRC Press
ISBN: 0429854668
Category : Science
Languages : en
Pages : 511

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Book Description
Developed in conjunction with several oil companies using experimental data for real reservoir fluids, Phase Behavior of Petroleum Reservoir Fluids introduces industry standard methods for modeling the phase behavior of petroleum reservoir fluids at different stages in the process. Keeping mathematics to a minimum, this book discusses sampling, characterization, compositional analyses, and equations of state used to simulate various pressure–volume–temperature (PVT) properties of reservoir fluids. The Third Edition has been updated throughout. Reflects advances in equation of state modeling for reservoir fluids and CO2-rich fluids Presents association models along with non-classical mixing rules for handling fluids with aqueous components Has an extended coverage of reservoir fluid communication, energy properties, and asphaltene precipitation Provides practical knowledge essential for achieving optimal design and cost-effective operations in a petroleum processing plant This book offers engineers working in the energy sector a solid understanding of the phase behavior of the various fluids present in a petroleum reservoir.