Validation of a two-dimensional model for vanadium redox-flow batteries

Validation of a two-dimensional model for vanadium redox-flow batteries PDF Author: Maik Becker
Publisher: Cuvillier Verlag
ISBN: 373696210X
Category : Science
Languages : en
Pages : 150

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Book Description
Redox-Flow batteries can play a crucial role in the future electricity supply in order to balance the time lag between the generation of electrical energy from photovoltaics or wind power and the demand for electrical energy. However, to deploy the technology on a large scale, significant cost reductions are required. A thorough knowledge of the reactions and processes taking place within a redox-flow battery is very helpful for this task and this knowledge can be significantly improved by using a suitable mathematical model to describe the processes in a single cell of a redox-flow battery. Nevertheless, this requires a valid model that has been compared with experimental data and that can reproduce these data plausibly and validly. In this thesis, the validation of a two-dimensional model for the description of potential and current density distributions in the porous electrodes of a vanadium redox-flow battery is presented, taking into account effects of kinetics and mass transport. Newly developed potential probes are used for in-situ measurement of solid and liquid phase potentials within a single cell of a vanadium redox-flow battery. The description of the measured cell voltage and potential probe signals by the model reveals a good congruence between the model and the experimental data, so the model can be regarded as valid. Additional suggestions for improvements of the model and the implementation of further models describing membrane crossover effects or electrolyte properties are given.

Validation of a two-dimensional model for vanadium redox-flow batteries

Validation of a two-dimensional model for vanadium redox-flow batteries PDF Author: Maik Becker
Publisher: Cuvillier Verlag
ISBN: 373696210X
Category : Science
Languages : en
Pages : 150

Get Book Here

Book Description
Redox-Flow batteries can play a crucial role in the future electricity supply in order to balance the time lag between the generation of electrical energy from photovoltaics or wind power and the demand for electrical energy. However, to deploy the technology on a large scale, significant cost reductions are required. A thorough knowledge of the reactions and processes taking place within a redox-flow battery is very helpful for this task and this knowledge can be significantly improved by using a suitable mathematical model to describe the processes in a single cell of a redox-flow battery. Nevertheless, this requires a valid model that has been compared with experimental data and that can reproduce these data plausibly and validly. In this thesis, the validation of a two-dimensional model for the description of potential and current density distributions in the porous electrodes of a vanadium redox-flow battery is presented, taking into account effects of kinetics and mass transport. Newly developed potential probes are used for in-situ measurement of solid and liquid phase potentials within a single cell of a vanadium redox-flow battery. The description of the measured cell voltage and potential probe signals by the model reveals a good congruence between the model and the experimental data, so the model can be regarded as valid. Additional suggestions for improvements of the model and the implementation of further models describing membrane crossover effects or electrolyte properties are given.

Multiscale Modeling, Simulation and Design – From Conventional Methods to the Latest in Data Science

Multiscale Modeling, Simulation and Design – From Conventional Methods to the Latest in Data Science PDF Author: J. N. Harb
Publisher: The Electrochemical Society
ISBN: 1607688336
Category : Science
Languages : en
Pages : 95

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Book Description


Battery System Modeling

Battery System Modeling PDF Author: Shunli Wang
Publisher: Elsevier
ISBN: 0323904335
Category : Science
Languages : en
Pages : 356

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Book Description
Battery System Modeling provides advances on the modeling of lithium-ion batteries. Offering step-by-step explanations, the book systematically guides the reader through the modeling of state of charge estimation, energy prediction, power evaluation, health estimation, and active control strategies. Using applications alongside practical case studies, each chapter shows the reader how to use the modeling tools provided. Moreover, the chemistry and characteristics are described in detail, with algorithms provided in every chapter. Providing a technical reference on the design and application of Li-ion battery management systems, this book is an ideal reference for researchers involved in batteries and energy storage. Moreover, the step-by-step guidance and comprehensive introduction to the topic makes it accessible to audiences of all levels, from experienced engineers to graduates. - Explains how to model battery systems, including equivalent, electrical circuit and electrochemical nernst modeling - Includes comprehensive coverage of battery state estimation methods, including state of charge estimation, energy prediction, power evaluation and health estimation - Provides a dedicated chapter on active control strategies

Electrochemical Energy

Electrochemical Energy PDF Author: Pei Kang Shen
Publisher: CRC Press
ISBN: 1351231200
Category : Science
Languages : en
Pages : 1051

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Book Description
Electrochemical Energy: Advanced Materials and Technologies covers the development of advanced materials and technologies for electrochemical energy conversion and storage. The book was created by participants of the International Conference on Electrochemical Materials and Technologies for Clean Sustainable Energy (ICES-2013) held in Guangzhou, China, and incorporates select papers presented at the conference. More than 300 attendees from across the globe participated in ICES-2013 and gave presentations in six major themes: Fuel cells and hydrogen energy Lithium batteries and advanced secondary batteries Green energy for a clean environment Photo-Electrocatalysis Supercapacitors Electrochemical clean energy applications and markets Comprised of eight sections, this book includes 25 chapters featuring highlights from the conference and covering every facet of synthesis, characterization, and performance evaluation of the advanced materials for electrochemical energy. It thoroughly describes electrochemical energy conversion and storage technologies such as batteries, fuel cells, supercapacitors, hydrogen generation, and their associated materials. The book contains a number of topics that include electrochemical processes, materials, components, assembly and manufacturing, and degradation mechanisms. It also addresses challenges related to cost and performance, provides varying perspectives, and emphasizes existing and emerging solutions. The result of a conference encouraging enhanced research collaboration among members of the electrochemical energy community, Electrochemical Energy: Advanced Materials and Technologies is dedicated to the development of advanced materials and technologies for electrochemical energy conversion and storage and details the technologies, current achievements, and future directions in the field.

Model-based Design and Optimization of Vanadium Redox Flow Batteries

Model-based Design and Optimization of Vanadium Redox Flow Batteries PDF Author: Sebastian König
Publisher: Cuvillier Verlag
ISBN: 3736986157
Category : Technology & Engineering
Languages : en
Pages : 182

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Book Description
In this work, a holistic approach is used to develop a multi-physical model of the Vanadium Redox Flow Battery on a system level. The model is validated with experimental data from three flow battery manufacturers and is then deployed in an extensive parameter study for designing a flow battery cell. Using finite element analysis (FEA), twenty-four different cell designs are derived, which vary in electrode area and the design of the electrolyte inlet and outlet supply channels. The performance of the designs is then simulated in a single-stack and a three-stack string system. The presented model is also deployed in a flow rate optimization study. Here, a novel strategy involving the model-based optimization of operation-points defined by state-of-charge and charging or discharging current is presented and compared to conventional flow rate control strategies. Finally, a stack voltage controller is introduced, which prevents the violation of cell voltage limits as long as the pump capacity is not fully utilized.

Redox Flow Batteries

Redox Flow Batteries PDF Author: Huamin Zhang
Publisher: CRC Press
ISBN: 1351648721
Category : Science
Languages : en
Pages : 409

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Book Description
Flow batteries have received attention in large-scale energy storage due to their flexible design, high safety, high energy efficiency, and environmental friendliness. In recent years, they have been rapidly developed and tested in a variety of scales that prove their feasibility and advantages of use. As energy becomes a global focus, it is important to consider flow battery systems. This book offers a detailed introduction to the function of different kinds of redox flow batteries, including vanadium flow batteries, as well as the electrochemical processes for their development, materials and components, applications, and near future prospects. Redox Flow Batteries: Fundamentals and Applications will give readers a full understanding of flow batteries from fundamentals to commercial applications.

Technologies and Applications for Smart Charging of Electric and Plug-in Hybrid Vehicles

Technologies and Applications for Smart Charging of Electric and Plug-in Hybrid Vehicles PDF Author: Ottorino Veneri
Publisher: Springer
ISBN: 3319436511
Category : Technology & Engineering
Languages : en
Pages : 323

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Book Description
This book outlines issues related to massive integration of electric and plug-in hybrid electric vehicles into power grids. Electricity is becoming the preferred energy vector for the next new generation of road vehicles. It is widely acknowledged that road vehicles based on full electric or hybrid drives can mitigate problems related to fossil fuel dependence. This book explains the emerging and understanding of storage systems for electric and plug-in hybrid vehicles. The recharging stations for these types of vehicles might represent a great advantage for the electric grid by facilitating integration of renewable and distributed energy production. This book presents a broad review from analyzing current literature to on-going research projects about the new power technologies related to the various charging architectures for electric and plug-in hybrid vehicles. Specifically focusing on DC fast charging operations, as well as, grid-connected power converters and the full range of energy storage systems. These key components are analyzed for distributed generation and charging system integration into micro-grids. The authors demonstrate that these storage systems represent effective interfaces for the control and management of renewable and sustainable distributed energy resources. New standards and applications are emerging from micro-grid pilot projects around the world and case studies demonstrate the convenience and feasibility of distributed energy management. The material in this unique volume discusses potential avenues for further research toward achieving more reliable, more secure and cleaner energy.

Energy Storage

Energy Storage PDF Author: Alfred Rufer
Publisher: CRC Press
ISBN: 1351621920
Category : Technology & Engineering
Languages : en
Pages : 351

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Book Description
This book will provide the technical community with an overview of the development of new solutions and products that address key topics, including electric/hybrid vehicles, ultrafast battery charging, smart grids, renewable energy (e.g., solar and wind), peak shaving, and reduction of energy consumption. The needs for storage discussed are within the context of changes between the centralized power generation of today and the distributed utility of tomorrow, including the integration of renewable energy sources. Throughout the book, methods for quantitative and qualitative comparison of energy storage means are presented through their energy capacity as well as through their power capability for different applications. The definitions and symbols for energy density and power density are given and relate to the volume and weight of a given system or component. A relatively underdeveloped concept that is crucial to this text is known as the theory of Ragone plots. This theory makes possible the evaluation of the real amount of energy that can possibly release out of a given system, with respect to the level of power dependency chosen for the discharge process. From systems using electrochemical transformations, to classical battery energy storage elements and so-called flow batteries, to fuel cells and hydrogen storage, this book further investigates storage systems based on physical principles (e.g., gravitational potential forces, air compression, and rotational kinetic energy). This text also examines purely electrical systems such as superconductive magnets and capacitors. Another subject of analysis is the presentation of power electronic circuits and architectures that are needed for continuously controllable power flow to and from different storage means. For all systems described, the elementary principles of operation are given as well as the relationships for the quantified storage of energy. Finally, Energy Storage: Systems and Components contains multiple international case studies and a rich set of exercises that serve both students and practicing engineers.

Laminar Flow Forced Convection in Ducts

Laminar Flow Forced Convection in Ducts PDF Author: R. K. Shah
Publisher: Academic Press
ISBN: 1483191303
Category : Technology & Engineering
Languages : en
Pages : 492

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Book Description
Laminar Flow Forced Convection in Ducts is a sourcebook for compact heat exchanger analytical data. This book describes the analytical solutions for laminar fluid flow and forced convection heat transfer in circular and noncircular pipes, including applicable differential equations and boundary conditions involving velocity and temperature problems of fluid flow. The book also discusses fluid flow—how much power is required to pump fluids through the heat exchanger, as well as the heat transfer—the determination of q" distribution, and the temperature of fluid and walls. The text also analyzes the coolant or heat transfer fluid flows in a nuclear power reactor composed of a bundle of circular section fuel rods located inside a round tube. R.A. Axford addresses fluid flow and heat transfers results for the rod bundle geometry in "Heat Transfer in Rod Bundles." The book also provides an overview and guidelines that can be used for the designer and the applied mathematician. This book is suitable for engineers working in electronics, aerospace, instrumentation, and biomechanics that use cooling or heating exchanges or solar collection systems.

Numerical Modeling of an All Vanadium Redox Flow Battery

Numerical Modeling of an All Vanadium Redox Flow Battery PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 46

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Book Description
We develop a capability to simulate reduction-oxidation (redox) flow batteries in the Sierra Multi-Mechanics code base. Specifically, we focus on all-vanadium redox flow batteries; however, the capability is general in implementation and could be adopted to other chemistries. The electrochemical and porous flow models follow those developed in the recent publication by [28]. We review the model implemented in this work and its assumptions, and we show several verification cases including a binary electrolyte, and a battery half-cell. Then, we compare our model implementation with the experimental results shown in [28], with good agreement seen. Next, a sensitivity study is conducted for the major model parameters, which is beneficial in targeting specific features of the redox flow cell for improvement. Lastly, we simulate a three-dimensional version of the flow cell to determine the impact of plenum channels on the performance of the cell. Such channels are frequently seen in experimental designs where the current collector plates are borrowed from fuel cell designs. These designs use a serpentine channel etched into a solid collector plate.