Silicon Reagents for Organic Synthesis

Silicon Reagents for Organic Synthesis PDF Author: William P. Weber
Publisher: Springer Science & Business Media
ISBN: 3642686613
Category : Science
Languages : en
Pages : 446

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Book Description

Silicon Reagents for Organic Synthesis

Silicon Reagents for Organic Synthesis PDF Author: William P. Weber
Publisher: Springer Science & Business Media
ISBN: 3642686613
Category : Science
Languages : en
Pages : 446

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Book Description


Alkene Metathesis in Organic Synthesis

Alkene Metathesis in Organic Synthesis PDF Author: Alois Fürstner
Publisher: Springer
ISBN:
Category : Medical
Languages : en
Pages : 252

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Book Description
The tremendous progress in olefin metathesis achieved during the last decade can hardly be overestimated. Due to the development of a new generation of well defined and high-performance organometallic catalysts, this reaction is rapidly evolving into one of the most versatile tools for advanced organic chemistry, natural product synthesis, fine chemical production and polymer sciences. Written by some of the leading experts in this field, this monograph intends to familiarize the reader with the most exciting developments and frontiers in this flourishing field of chemistry research.

Silicon in Organic Synthesis

Silicon in Organic Synthesis PDF Author: Ernest W. Colvin
Publisher: Butterworth-Heinemann
ISBN: 148314223X
Category : Science
Languages : en
Pages : 361

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Book Description
Silicon in Organic Synthesis provides an introduction to the organic chemistry of silicon. This book places particular emphasis on the concept of silicon as a "ferryman, mediating the transformation of one wholly organic molecule into another. The book begins by reviewing the discovery and development of organosilicon compounds. This is followed by separate chapters on the physical properties of organosilicon compounds; the preparation of a-metallated organosilanes, which play a key role in preparative organosilicon chemistry; migration/rearrangement reactions of silicon; the preparation and chemistry of vinylsilanes, allylsilanes, arylsilanes, and organosilyl metallic compounds. Subsequent chapters cover the synthesis of compounds such as alkene, alkynylsilanes, allenylsilanes, silylketenes, alkyl silyl ethers, acyloxysilanes, and silyl enol ethers. This book aims to serve as a timely introduction to organic chemistry for students and practitioners of synthetic organic chemistry, as well as provide a source of useful information and possibly of new ideas to those already experienced in the area.

Reagents for Silicon-Mediated Organic Synthesis

Reagents for Silicon-Mediated Organic Synthesis PDF Author: Philip L. Fuchs
Publisher: John Wiley & Sons
ISBN: 0470710233
Category : Technology & Engineering
Languages : en
Pages : 859

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Book Description
Over the last three decades the importance of organosilicon chemistry has greatly increased because it has opened a number of new synthetic strategies. Silicon reagents are usually low-cost, versatile and allow a wide range of reactions. This is the first Handbook to compile essential Silicon containing reagents and makes use of the leading reagent database e-EROS. Another hot volume in the series Handbooks of Reagents for Organic Synthesis, this is a must-have resource for all synthetic chemists working in drug development and medicinal chemistry. For the selection the Editor focussed on three key synthetic approaches with the greatest impact: 1. Use of silicon as a 'temporary tether' by unifying a reactive pair of functional groups and taking advantage of their template-biased intramolecular cyclization. 2. The specific use of the silane functionality as a hetero t-butyl group, often colloquially referred to as the use of silicon as a 'fat proton'. 3. The use of the Brook rearrangement as an 'anion relay stratagem'. A new feature in this Handbook is the reagent finder, an alphabetically organized lookup table arranged by organic functionality and specific structure of the silicon atom to which it is bound.

(Trimethylsilyl)allenes in Organic Synthesis

(Trimethylsilyl)allenes in Organic Synthesis PDF Author: David John Carini
Publisher:
ISBN:
Category :
Languages : en
Pages : 366

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Book Description


Science of Synthesis: C-1 Building Blocks in Organic Synthesis Vol. 1

Science of Synthesis: C-1 Building Blocks in Organic Synthesis Vol. 1 PDF Author: Piet W.N.M. van Leeuwen
Publisher: Thieme
ISBN: 3131765313
Category : Science
Languages : en
Pages : 954

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Book Description
The two-volume set on C-1 Building Blocks in Organic Synthesis critically reviews the state of the art of a wide variety of reactions by which one carbon atom is added to an organic molecule, forming a C-C bond. In spite of the numerous classic reactions of this kind, there has been enormous progress in recent years, especially for those reactions involving catalytic methods. Introduction of substituted methyl groups is a major challenge and only very recently the first catalysts have been discovered that enable the introduction of fluoromethyl groups in aromatics.

Science of Synthesis: Houben-Weyl Methods of Molecular Transformations Vol. 4

Science of Synthesis: Houben-Weyl Methods of Molecular Transformations Vol. 4 PDF Author: Ian Fleming
Publisher: Thieme
ISBN: 3131779314
Category : Science
Languages : en
Pages : 1764

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Book Description
Science of Synthesis: Houben-Weyl Methods of Molecular Transformations is the entirely new edition of the acclaimed reference series, Houben-Weyl, the standard synthetic chemistry resource since 1909. This new edition is published in English and will comprise of 48 volumes published between the years 2000 and 2008. Science of Synthesis is a quality reference work developed by a highly esteemed editorial board to provide a comprehensive and critical selection of reliable organic and organometallic synthetic methods. Science of Synthesis is designed to be the first point of reference when searching for a synthesis strategy. This volume covers compounds of the group 15 metaloids (As, Sb, Bi) and Silicon. In Volume 4, there are single chapters devoted to each of the three group 15 elements, and then 42 chapters for the various kinds of silicon-containing compounds used in organic synthesis. The chapters are organized by the functionality attached to the element, and appear in an order determined by the rules used for the whole series of Science of Synthesis, with the space given to each determined both by the range of chemistry that needs to be described and by the importance of the functional arrangement in synthesis. For full information on the Science of Synthesis series, visit the Science of Synthesis Homepage.

A Guide to Reagents in Organic Synthesis

A Guide to Reagents in Organic Synthesis PDF Author: Vinod Jena
Publisher: Lulu.com
ISBN: 1329162145
Category : Reference
Languages : en
Pages : 163

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Book Description
This book is collection of various reagents used in organic synthesis. This book will provide a good practice problems on reagents for all the aspirants of competitive examination. The materials are given concise manner with proper problems.

Reagents for Silicon-Mediated Organic Synthesis

Reagents for Silicon-Mediated Organic Synthesis PDF Author: Philip L. Fuchs
Publisher: John Wiley & Sons
ISBN: 1118636139
Category : Technology & Engineering
Languages : en
Pages : 816

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Book Description
Over the last three decades the importance of organosiliconchemistry has greatly increased because it has opened a number ofnew synthetic strategies. Silicon reagents are usually low-cost,versatile and allow a wide range of reactions. This is the firstHandbook to compile essential Silicon containing reagents and makesuse of the leading reagent database e-EROS. Another hotvolume in the series Handbooks of Reagents for OrganicSynthesis, this is a must-have resource for all syntheticchemists working in drug development and medicinal chemistry. For the selection the Editor focussed on three key syntheticapproaches with the greatest impact: 1. Use of silicon as a 'temporary tether' by unifying a reactivepair of functional groups and taking advantage of theirtemplate-biased intramolecular cyclization. 2. The specific use of the silane functionality as a heterot-butyl group, often colloquially referred to as the use ofsilicon as a 'fat proton'. 3. The use of the Brook rearrangement as an 'anion relaystratagem'. A new feature in this Handbook is the reagent finder, analphabetically organized lookup table arranged by organicfunctionality and specific structure of the silicon atom to whichit is bound.

Domino Reactions

Domino Reactions PDF Author: Lutz F. Tietze
Publisher: John Wiley & Sons
ISBN: 3527671323
Category : Science
Languages : en
Pages : 658

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Book Description
The follow-up to the successful "Domino Reaction in Organic Synthesis", this ready reference brings up to date on the original concept. The chapters have been arranged according to the name of well-known transformations of the first step and in combination with the formed products. Each chapter is written by an internationally renowned expert, and the book is edited by L. F. Tietze, who established the concept of domino reactions. The one-stop source for all synthetic chemists to improve the synthetic efficiency and allow an ecologically and economically beneficial preparation of every chemical compound.