Transition Metal Catalysis in Aerobic Alcohol Oxidation

Transition Metal Catalysis in Aerobic Alcohol Oxidation PDF Author: Francesca Cardona
Publisher: Royal Society of Chemistry
ISBN: 1849738238
Category : Science
Languages : en
Pages : 304

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Book Description
This book deals with the search for environmentally benign procedures for the oxidation of alcohols and gives an overview of their transition-metal-catalyzed aerobic oxidation.

Transition Metal Catalysis in Aerobic Alcohol Oxidation

Transition Metal Catalysis in Aerobic Alcohol Oxidation PDF Author: Francesca Cardona
Publisher: Royal Society of Chemistry
ISBN: 1849738238
Category : Science
Languages : en
Pages : 304

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Book Description
This book deals with the search for environmentally benign procedures for the oxidation of alcohols and gives an overview of their transition-metal-catalyzed aerobic oxidation.

Transition Metal Based Catalysts for Aerobic Alcohol Oxidation

Transition Metal Based Catalysts for Aerobic Alcohol Oxidation PDF Author: Luke Rogan
Publisher:
ISBN:
Category :
Languages : en
Pages : 0

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Book Description


Liquid Phase Aerobic Oxidation Catalysis

Liquid Phase Aerobic Oxidation Catalysis PDF Author: Shannon S. Stahl
Publisher: John Wiley & Sons
ISBN: 3527690158
Category : Technology & Engineering
Languages : en
Pages : 456

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Book Description
The first book to place recent academic developments within the context of real life industrial applications, this is a timely overview of the field of aerobic oxidation reactions in the liquid phase that also illuminates the key challenges that lie ahead. As such, it covers both homogeneous as well as heterogeneous chemocatalysis and biocatalysis, along with examples taken from various industries: bulk chemicals and monomers, specialty chemicals, flavors and fragrances, vitamins, and pharmaceuticals. One chapter is devoted to reactor concepts and engineering aspects of these methods, while another deals with the relevance of aerobic oxidation catalysis for the conversion of renewable feedstock. With chapters written by a team of academic and industrial researchers, this is a valuable reference for synthetic and catalytic chemists at universities as well as those working in the pharmaceutical and fine chemical industries seeking a better understanding of these reactions and how to design large scale processes based on this technology.

Oxidation of Alcohols to Aldehydes and Ketones

Oxidation of Alcohols to Aldehydes and Ketones PDF Author: Gabriel Tojo
Publisher: Springer Science & Business Media
ISBN: 038725725X
Category : Science
Languages : en
Pages : 388

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Book Description
The aim of this book is to help people performing routine operations in Organic Synthesis in a laboratory. This book, the first one in a series, focuses on the oxidation of alcohols to aldehydes and ketones. Probably, this is the most important routine operation in Organic Synthesis.

Polyoxomolybdates as Green Catalysts for Aerobic Oxidation

Polyoxomolybdates as Green Catalysts for Aerobic Oxidation PDF Author: Anjali Patel
Publisher: Springer
ISBN: 3319129880
Category : Science
Languages : en
Pages : 63

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Book Description
Heterogeneously catalyzed selective oxidations of alcohols is a highly topical field. The first chapter of this brief describes the importance of the selective oxidation of alcohols and advantages of heterogeneous catalysts over conventional catalysts, use of environmentally benign oxidants, and the design of selective catalysts by tailoring of polyoxometalates at the molecular level. Chapter 2 describes synthesis, characterization 11-molybdophosphate based supported materials and their use as heterogeneous catalysts for oxidation of alcohols with molecular oxygen under solvent free mild reaction condition. ZrO2, Al2O3, MCM-41 and zeolite Hβ were used as supports. Chapter 3 describes synthesis, characterization of transition metals (Mn, Co, Ni, Cu)- substituted phosphomolybdates and their use as heterogeneous catalysts for oxidation of alcohols with molecular oxygen under solvent free mild reaction condition. Chapter 4 describes conclusive remarks for present catalytic systems.

Redox-Active Ligands

Redox-Active Ligands PDF Author: Marine Desage-El Murr
Publisher: John Wiley & Sons
ISBN: 352783088X
Category : Science
Languages : en
Pages : 373

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Book Description
Redox-Active Ligands Authoritative resource showcasing a new family of ligands that can lead to better catalysts and promising applications in organic synthesis Redox-Active Ligands gives a comprehensive overview of the unique features of redox-active ligands, describing their structure and synthesis, the characterization of their coordination complexes, and important applications in homogeneous catalysis. The work reflects the diversity of the subject by including ongoing research spanning coordination chemistry, organometallic chemistry, bioinspired catalysis, proton and electron transfer, and the ability of such ligands to interact with early and late transition metals, lanthanides, and actinides. The book is divided into three parts, devoted to introduction and concepts, applications, and case studies. After the introduction on key concepts related to the field, and the different types of ligands and complexes in which ligand-centered redox activity is commonly observed, mechanistic and computational studies are described. The second part focuses on catalytic applications of redox-active complexes, including examples from radical transformations, coordination chemistry and organic synthesis. Finally, case studies of redox-active guanidine ligands, and of lanthanides and actinides are presented. Other specific sample topics covered include: An overview of the electronic features of redox-active ligands, covering their historical perspective and biological background The versatility and mode of action of redox-active ligands, which sets them apart from more classic and tunable ligands such as phosphines or N-heterocyclic carbenes Preparation and catalytic applications of complexes of stable N-aryl radicals Metal complexes with redox-active ligands in H+/e- transfer transformations By providing up-to-date information on important concepts and applications, Redox-Active Ligands is an essential reading for researchers working in organometallic and coordination chemistry, catalysis, organic synthesis, and (bio)inorganic chemistry, as well as newcomers to the field.

Oxidation of Primary Alcohols to Carboxylic Acids

Oxidation of Primary Alcohols to Carboxylic Acids PDF Author: Gabriel Tojo
Publisher: Springer Science & Business Media
ISBN: 0387354328
Category : Science
Languages : en
Pages : 124

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Book Description
As the second volume in a comprehensive encyclopedia of organic reactions, this work provides an elaborated description of the experimental methods used for the oxidation of alcohols to acids. It supplies important data on possible interferences from protecting groups and functional groups, as well as on potential side-reactions. This book is a must for anyone involved in the preparation of organic compounds.

Interfacial Catalysis

Interfacial Catalysis PDF Author: Alexander G. Volkov
Publisher: CRC Press
ISBN: 9780203910429
Category : Science
Languages : en
Pages : 690

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Book Description
A comprehensive volume on interfacial catalysis, this book includes contributions from an international group of specialists in chemistry, environmental science, informatics, physiology, nuclear energy, and physics. The editor has organized the material into the main topics of fundamental characteristics, phase transfer catalysis, reversed micelles, biological aspects, and interfacial photocatalysis. Individual topics include self-organized microheterogeneous structures, nanochemistry, interfacial catalysis in metal complexation, the role of water molecules in ion transfer at the oil/water interface, and ultrathin films in enhanced oil recovery.

Catalytic Asymmetric Synthesis

Catalytic Asymmetric Synthesis PDF Author: Takahiko Akiyama
Publisher: John Wiley & Sons
ISBN: 1119736412
Category : Science
Languages : en
Pages : 798

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Book Description
Catalytic Asymmetric Synthesis Seminal text presenting detailed accounts of the most important catalytic asymmetric reactions known today This book covers the preparation of enantiomerically pure or enriched chemical compounds by use of chiral catalyst molecules. While reviewing the most important catalytic methods for asymmetric organic synthesis, this book highlights the most important and recent developments in catalytic asymmetric synthesis. Edited by two well-qualified experts, sample topics covered in the work include: Metal catalysis, organocatalysis, photoredox catalysis, enzyme catalysis C–H bond functionalization reactions Carbon–carbon bond formation reactions, carbon–halogen bond formation reactions, hydrogenations, polymerizations, flow reactions Axially chiral compounds Retaining the best of its predecessors but now thoroughly up to date with the important and recent developments in catalytic asymmetric synthesis, the 4th edition of Catalytic Asymmetric Synthesis serves as an excellent desktop reference and text for researchers and students, from upper-level undergraduates all the way to experienced professionals in industry or academia.

Biomimetic Oxidations Catalyzed By Transition Metal Complexes

Biomimetic Oxidations Catalyzed By Transition Metal Complexes PDF Author: Bernard Meunier
Publisher: World Scientific
ISBN: 1783262389
Category : Science
Languages : en
Pages : 697

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Book Description
Since the classic work Metal-Catalyzed Oxidations of Organic Compounds (edited by R A Sheldon and J K Kochi, 1991), no book has been devoted to advances in the field of biomimetic oxidations, which was created nearly 18 years ago. This expanding research field is covered in this volume. All the different aspects of the modeling of oxidations catalyzed by metalloenzymes are dealt with.This invaluable book will be useful to postgraduates as well as researchers in academia and industry, and will also benefit second year university students.