Thermodynamics and Rheology

Thermodynamics and Rheology PDF Author: J. Verhás
Publisher: Springer Science & Business Media
ISBN: 9780792342519
Category : Science
Languages : en
Pages : 240

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Book Description
This book presents a general classical field theory, incorporating continuum mechanics, electrodynamics, and thermodynamics. The continuum equations of material behavior are derived from the principles of Onsager's non-equilibrium thermodynamics supplemented with dynamic degrees of freedom. The book contains the basic principles and methods of modern continuum mechanics and of rheology. Non-equilibrium thermodynamics is discussed in detail. Applications include elasticity, thermoelasticity, viscoelasticity, plasticity, rheooptics, etc. The models of rheology are developed within a consistent thermodynamic framework. Viscoelastic and plastic response, Ostwald's curve of generalized Newtonian fluids, creep, elasticity preceding plastic flow, the rules of rheooptics, etc., are discussed, and the empirical Cox-Merz rule is proved. The thermodynamic results are compared to the results of microscopic theories. Several kinds of colloids, polymers, and liquid crystals are studied. The technical level of the book is high. It is designed for engineers, physicists, natural scientists and applied mathematicians.

Thermodynamics and Rheology

Thermodynamics and Rheology PDF Author: J. Verhás
Publisher: Springer Science & Business Media
ISBN: 9780792342519
Category : Science
Languages : en
Pages : 240

Get Book Here

Book Description
This book presents a general classical field theory, incorporating continuum mechanics, electrodynamics, and thermodynamics. The continuum equations of material behavior are derived from the principles of Onsager's non-equilibrium thermodynamics supplemented with dynamic degrees of freedom. The book contains the basic principles and methods of modern continuum mechanics and of rheology. Non-equilibrium thermodynamics is discussed in detail. Applications include elasticity, thermoelasticity, viscoelasticity, plasticity, rheooptics, etc. The models of rheology are developed within a consistent thermodynamic framework. Viscoelastic and plastic response, Ostwald's curve of generalized Newtonian fluids, creep, elasticity preceding plastic flow, the rules of rheooptics, etc., are discussed, and the empirical Cox-Merz rule is proved. The thermodynamic results are compared to the results of microscopic theories. Several kinds of colloids, polymers, and liquid crystals are studied. The technical level of the book is high. It is designed for engineers, physicists, natural scientists and applied mathematicians.

Polyelectrolytes

Polyelectrolytes PDF Author: Visakh P. M.
Publisher: Springer
ISBN: 3319016806
Category : Technology & Engineering
Languages : en
Pages : 388

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Book Description
This book offers a valuable reference source to graduate and post graduate students, engineering students, research scholars polymer engineers from industry. The book provides the reader with current developments of theoretical models describing the thermodynamics polyelectrolytes as well as experimental findings. A particular emphasis is put on the rheological description of polyelectrolyte solutions and hydrogels.

Thermodynamics of Irreversible Processes

Thermodynamics of Irreversible Processes PDF Author: Gerard D. C. Kuiken
Publisher: John Wiley & Sons
ISBN:
Category : Science
Languages : en
Pages : 472

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Book Description
Thermodynamics of irreversible Processes provides a thorough treatment of the basic axioms of irreversible systems and deals with specific applications to diffusion of liquids and matter in flow. This volume will prove to be invaluable reading for anyone working in the field of irreversible phenomena. Thermodynamics of Irreversible Processes, presents :- A lucid review of classical thermodynamics Rigorous derivations of the fundamental principles of irreversible thermodynamics In-depth studies of multicomponent diffusion, with applications to non-ideal systems Thorough treatments of relaxation phenomena and linear viscoelasticity An essential text for anyone working with irreversible thermodynamics, rheology and multi-component mixtures Thermodynamics of irreversible Processes is the first advanced text dealing with the applications of irreversible thermodynamics to multicomponent diffusion and viscoelasticity. Gerard Kuiken has written a book which will appeal to students and researchers in chemistry, chemical technology, polymer and materials science, physics and rheology.

The Vitreous State

The Vitreous State PDF Author: Ivan S. Gutzow
Publisher: Springer Science & Business Media
ISBN: 3662031876
Category : Science
Languages : en
Pages : 483

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Book Description
The present book is devoted to problems of a physically important state of condensed matter - the vitreous state. We tried to summarize here the experimental evidence and the different theoretical approaches - structural, thermodynamic and those of statistical physics - connected with the formation, the kinetic stability and with the general nature of glasses as a particular physical state. In addition, a summary is given on the information available concerning proces ses of nucleation and crystallization of glass-forming systems, on methods of preventing or, in contrast, catalyzing crystallization in vitrifying liquids, on the kinetics of nucleation, the modes of crystal growth in undercooled melts and the devitrification of glasses. It was our aim to summarize in the present volume the basic principles and the most significant developments of a newly emerging science - glass science - and to show that, at least, in principle, any substance can exist in the vitreous state. Moreover, we have tried to demonstrate that the characteristic properties of the vitreous state may be attributed under certain conditions not only to systems with an amorphous structure (like the common glasses) but also to a number of other states of condensed matter including the crystalline one.

Beyond Equilibrium Thermodynamics

Beyond Equilibrium Thermodynamics PDF Author: Hans Christian Öttinger
Publisher: John Wiley & Sons
ISBN: 0471727911
Category : Technology & Engineering
Languages : en
Pages : 651

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Book Description
Beyond Equilibrium Thermodynamics fills a niche in the market by providing a comprehensive introduction to a new, emerging topic in the field. The importance of non-equilibrium thermodynamics is addressed in order to fully understand how a system works, whether it is in a biological system like the brain or a system that develops plastic. In order to fully grasp the subject, the book clearly explains the physical concepts and mathematics involved, as well as presenting problems and solutions; over 200 exercises and answers are included. Engineers, scientists, and applied mathematicians can all use the book to address their problems in modelling, calculating, and understanding dynamic responses of materials.

Polymer Alloys and Blends

Polymer Alloys and Blends PDF Author: L. A. Utracki
Publisher:
ISBN: 9781569901045
Category : Science
Languages : en
Pages : 367

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Book Description
An introduction to polymer alloys and blends.

Rheology of Non-spherical Particle Suspensions

Rheology of Non-spherical Particle Suspensions PDF Author: Francisco Chinesta
Publisher: Elsevier
ISBN: 0081008120
Category : Science
Languages : en
Pages : 398

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Book Description
This book provides a review of the current understanding of the behavior of non-spherical particle suspensions providing experimental results, rheological models and numerical modeling. In recent years, new models have been developed for suspension rheology and as a result applications for nanocomposites have increased. The authors tackle issues within experimental, model and numerical simulations of the behavior of particle suspensions. Applications of non-spherical particle suspension rheology are widespread and can be found in organic matrix composites, nanocomposites, biocomposites, fiber-filled fresh concrete flow, blood and biologic fluids. - Understand how to model and predict the final microstructure and properties of particle suspensions - Explores nano, micro, meso and macro scales - Rheology, thermomechanical and electromagnetic physics are discussed

Rheology of Polymer Blends and Nanocomposites

Rheology of Polymer Blends and Nanocomposites PDF Author: Sabu Thomas
Publisher: Elsevier
ISBN: 0128169567
Category : Technology & Engineering
Languages : en
Pages : 326

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Book Description
Rheology of Polymer Blends and Nanocomposites: Theory, Modelling and Applications focuses on rheology in polymer nanocomposites. It provides readers with a solid grounding in the fundamentals of rheology, with an emphasis on recent advancements. Chapters explore potential future applications for nanocomposites and polymer blends, giving readers a thorough understanding of the specific features derived from rheology as a tool for the study of polymer blends and nanocomposites. This book is ideal for industrial and academic researchers in the field of polymer blends and nanocomposites, but is also a great resource for anyone who wants to learn about the applications of rheology. - Sets out the principles of rheology as it is applied to polymer blends and nanocomposites - Demonstrates how rheological techniques are best applied to different classes of nanocomposites - Assesses the opportunities and major challenges of rheological approaches to polymer blends and nanocomposites

Rheology and Non-Newtonian Fluids

Rheology and Non-Newtonian Fluids PDF Author: Fridtjov Irgens
Publisher: Springer Science & Business Media
ISBN: 3319010530
Category : Technology & Engineering
Languages : en
Pages : 192

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Book Description
This book gives a brief but thorough introduction to the fascinating subject of non-Newtonian fluids, their behavior and mechanical properties. After a brief introduction of what characterizes non-Newtonian fluids in Chapter 1 some phenomena characteristic of non-Newtonian fluids are presented in Chapter 2. The basic equations in fluid mechanics are discussed in Chapter 3. Deformation kinematics, the kinematics of shear flows, viscometric flows, and extensional flows are the topics in Chapter 4. Material functions characterizing the behavior of fluids in special flows are defined in Chapter 5. Generalized Newtonian fluids are the most common types of non-Newtonian fluids and are the subject in Chapter 6. Some linearly viscoelastic fluid models are presented in Chapter 7. In Chapter 8 the concept of tensors is utilized and advanced fluid models are introduced. The book is concluded with a variety of 26 problems. Solutions to the problems are ready for instructors

Polymer Thermodynamics

Polymer Thermodynamics PDF Author: Sabine Enders
Publisher: Springer
ISBN: 3642176828
Category : Technology & Engineering
Languages : en
Pages : 434

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Book Description
Making Flory-Huggins Practical: Thermodynamics of Polymer-Containing Mixtures, by B. A. Wolf * Aqueous Solutions of Polyelectrolytes: Vapor-Liquid Equilibrium and Some Related Properties, by G. Maurer, S. Lammertz, and L. Ninni Schäfer * Gas-Polymer Interactions: Key Thermodynamic Data and Thermophysical Properties, by J.-P. E. Grolier, and S. A.E. Boyer * Interfacial Tension in Binary Polymer Blends and the Effects of Copolymers as Emulsifying Agents, by S. H. Anastasiadis * Theory of Random Copolymer Fractionation in Columns, by Sabine Enders * Computer Simulations and Coarse-Grained Molecular Models Predicting the Equation of State of Polymer Solutions, by K. Binder, B. Mognetti, W. Paul, P. Virnau, and L. Yelash * Modeling of Polymer Phase Equilibria Using Equations of State, by G. Sadowski