Author: J. L. Carroll
Publisher:
ISBN:
Category : Nitrates
Languages : en
Pages : 80
Book Description
The Photoactivated Reduction of Uranium(VI) to Uranium(IV) Nitrate
Author: J. L. Carroll
Publisher:
ISBN:
Category : Nitrates
Languages : en
Pages : 80
Book Description
Publisher:
ISBN:
Category : Nitrates
Languages : en
Pages : 80
Book Description
Preparation of Uranium (IV) Nitrate Solutions
Author: Robert S. Ondrejcin
Publisher:
ISBN:
Category : Precipitation (Chemistry)
Languages : en
Pages : 16
Book Description
Publisher:
ISBN:
Category : Precipitation (Chemistry)
Languages : en
Pages : 16
Book Description
The Carbon Reduction of Uranium Oxide
Author: Harley A. Wilhelm
Publisher:
ISBN:
Category : Reduction (Chemistry)
Languages : en
Pages : 42
Book Description
Publisher:
ISBN:
Category : Reduction (Chemistry)
Languages : en
Pages : 42
Book Description
Photochemical Reduction of Uranyl Nitrate
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 52
Book Description
The photochemical reduction of uranyl nitrate solutions to tetravalent uranium was investigated as a means of producing uranium dioxide feed for the saltless direct oxide reduction (SDOR) process. At high uranium concentrations, reoxidation of U{sup +4} occurs rapidly. The kinetics of the nitric oxidation of tetravalent uranium depend on the concentrations of hydrogen ion, nitrate ion, nitrous acid, and tetravalent uranium in the same manner as was reported elsewhere for the nitrate oxidation of PU{sup +3}. Reaction rate data were successfully correlated with a mechanism in which nitrogen dioxide is the reactive intermediate. Addition of a nitrous acid scavenger suppresses the reoxidation reaction. An immersion reactor employing a mercury vapor lamp gave reduction times fast enough for routine production usage. Precipitation techniques for conversion of aqueous U(NO3)4 to hydrous UO2 were evaluated. Prolonged dewatering times tended to make the process time consuming. Use of 3- to 4-M aqueous NaOH gave the best dewatering times observed. Reoxidation of the UO2 by water of hydration was encountered, which required the drying process to be carried out under a reducing atmosphere.
Publisher:
ISBN:
Category :
Languages : en
Pages : 52
Book Description
The photochemical reduction of uranyl nitrate solutions to tetravalent uranium was investigated as a means of producing uranium dioxide feed for the saltless direct oxide reduction (SDOR) process. At high uranium concentrations, reoxidation of U{sup +4} occurs rapidly. The kinetics of the nitric oxidation of tetravalent uranium depend on the concentrations of hydrogen ion, nitrate ion, nitrous acid, and tetravalent uranium in the same manner as was reported elsewhere for the nitrate oxidation of PU{sup +3}. Reaction rate data were successfully correlated with a mechanism in which nitrogen dioxide is the reactive intermediate. Addition of a nitrous acid scavenger suppresses the reoxidation reaction. An immersion reactor employing a mercury vapor lamp gave reduction times fast enough for routine production usage. Precipitation techniques for conversion of aqueous U(NO3)4 to hydrous UO2 were evaluated. Prolonged dewatering times tended to make the process time consuming. Use of 3- to 4-M aqueous NaOH gave the best dewatering times observed. Reoxidation of the UO2 by water of hydration was encountered, which required the drying process to be carried out under a reducing atmosphere.
Production of Uranium Dioxide by Flame Denitration and Reduction of Aqueous Uranyl Nitrate
Author: William Henry Hedley
Publisher:
ISBN:
Category : Reduction (Chemistry)
Languages : en
Pages : 54
Book Description
Publisher:
ISBN:
Category : Reduction (Chemistry)
Languages : en
Pages : 54
Book Description
Nuclear Science Abstracts
Author:
Publisher:
ISBN:
Category : Nuclear energy
Languages : en
Pages : 1256
Book Description
Publisher:
ISBN:
Category : Nuclear energy
Languages : en
Pages : 1256
Book Description
Reactor Fuel Processing
Author:
Publisher:
ISBN:
Category : Nuclear engineering
Languages : en
Pages : 726
Book Description
Publisher:
ISBN:
Category : Nuclear engineering
Languages : en
Pages : 726
Book Description
Keywords Index to U.S. Government Technical Reports (permuted Title Index).
Author: United States. Department of Commerce. Office of Technical Services
Publisher:
ISBN:
Category : Government publications
Languages : en
Pages : 618
Book Description
Publisher:
ISBN:
Category : Government publications
Languages : en
Pages : 618
Book Description
Keywords Index to U.S. Government Technical Reports
Author:
Publisher:
ISBN:
Category : Government publications
Languages : en
Pages : 116
Book Description
Publisher:
ISBN:
Category : Government publications
Languages : en
Pages : 116
Book Description
Reactor fuel processing
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 1074
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 1074
Book Description