The Effect of Electrostatic Fields on Reacting Molecules PDF Download
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Author: Alan Bruce Whiting
Publisher:
ISBN:
Category : Dimethylfulvene
Languages : en
Pages : 31
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Book Description
The work synthesizes some model compounds whose structure provides a dipole for interaction with electric field. The Diels-Alder addition of furan to maleic anhydride and 6,6-dimethylfulvene to maleic anhydride in electric fields of 0, 240, and 350 V/cm were studied, and they were set to react in a cell in which a static electric field was maintained. It was found that the furan addition was uneffected by the fields, but that the proportion of exo to endo isomers of the 6, 6-dimethylfulvene product changed in a qualitatively predictable way. The details are described in the papers.
Author: Alan Bruce Whiting
Publisher:
ISBN:
Category : Dimethylfulvene
Languages : en
Pages : 31
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Book Description
The work synthesizes some model compounds whose structure provides a dipole for interaction with electric field. The Diels-Alder addition of furan to maleic anhydride and 6,6-dimethylfulvene to maleic anhydride in electric fields of 0, 240, and 350 V/cm were studied, and they were set to react in a cell in which a static electric field was maintained. It was found that the furan addition was uneffected by the fields, but that the proportion of exo to endo isomers of the 6, 6-dimethylfulvene product changed in a qualitatively predictable way. The details are described in the papers.
Author: Sason Shaik
Publisher: Royal Society of Chemistry
ISBN: 1839163046
Category : Science
Languages : en
Pages : 447
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Book Description
Electric-field-mediated chemistry is an emerging topic that is rapidly growing and fanning out in many directions. It involves theoretical and experimental aspects, as well as intense interplay between them, including breakthrough achievements such as the proof-of-principle that a Diels–Alder reaction, which involves two simultaneous C–C bond making events, can be catalysed or inhibited simply by changing the direction of an oriented external-electric field (OEEF). This productive interplay between the theoretical and experimental branches of chemistry is continuing, and gradually defining a new sub-field wherein various sources of electric fields, whether external or built-in and designed, or even surface induced fields (plasmons), are brought to bear on chemical reactions, molecular structures, and nano-systems, leading to control of reactivity, selectivity, chirality, molecular orientations, changes in structure, and in dynamics. Written by leaders in the field, Effects of Electric Fields on Structure and Reactivity is the first book on this exciting topic. Starting with an overview of the theory behind – and demonstrations of the effect of – electric fields on structure and reactivity, this accessible reference work aims to encourage those new to the field to consider harnessing these effects in their own work. Covering applications and recent theoretical developments, it is a useful resource for theoretical chemists and experimentalists alike.
Author: Sason S. Shaik
Publisher:
ISBN: 9781839161698
Category : Science
Languages : en
Pages : 0
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Book Description
Starting with an overview of the theory behind - and demonstrations of the effect of - electric fields on structure and reactivity, this accessible reference work aims to encourage those new to the field to consider harnessing these effects in their own work.
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 14
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Book Description
Progress is reviewed in our understanding of the effects of high electrostatic fields (of the order of volts per angstrom) on the adsorption and reaction of atoms and molecules on metal and semiconductor surfaces. Chemical Reactions, Electric Fields, Nanoscale Structures.
Author: George Maroulis
Publisher: Imperial College Press
ISBN: 1860948863
Category : Technology & Engineering
Languages : en
Pages : 694
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Book Description
With the central importance of electric polarizability and hyperpolarizability for a wide spectrum of activities, this book charts the trends in the accurate theoretical determination of these properties in specialized fields. The contributions include reviews and original papers that extend from methodology to applications in specific areas of primary importance such as cluster science and organic synthesis of molecules with specific properties.
Author: A. King
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Book Description
Author: Raphael D. Levine
Publisher: Cambridge University Press
ISBN: 9781139442879
Category : Technology & Engineering
Languages : en
Pages : 574
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Book Description
Molecular reaction dynamics is the study of chemical and physical transformations of matter at the molecular level. The understanding of how chemical reactions occur and how to control them is fundamental to chemists and interdisciplinary areas such as materials and nanoscience, rational drug design, environmental and astrochemistry. This book provides a thorough foundation to this area. The first half is introductory, detailing experimental techniques for initiating and probing reaction dynamics and the essential insights that have been gained. The second part explores key areas including photoselective chemistry, stereochemistry, chemical reactions in real time and chemical reaction dynamics in solutions and interfaces. Typical of the new challenges are molecular machines, enzyme action and molecular control. With problem sets included, this book is suitable for advanced undergraduate and graduate students, as well as being supplementary to chemical kinetics, physical chemistry, biophysics and materials science courses, and as a primer for practising scientists.
Author: Robert Allen Meyers
Publisher: John Wiley & Sons
ISBN: 9780471186342
Category : Medical
Languages : en
Pages : 1090
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Book Description
This is one volume 'library' of information on molecular biology, molecular medicine, and the theory and techniques for understanding, modifying, manipulating, expressing, and synthesizing biological molecules, conformations, and aggregates. The purpose is to assist the expanding number of scientists entering molecular biology research and biotechnology applications from diverse backgrounds, including biology and medicine, as well as physics, chemistry, mathematics, and engineering.
Author: Youngwook Park
Publisher: Springer Nature
ISBN: 9811586934
Category : Science
Languages : en
Pages : 41
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Book Description
This book describes the manipulation of molecular properties, such as orientation, structure, and dynamics, of small molecules and molecular clusters isolated in cold inert matrices by using unprecedentedly strong external electrostatic fields. Manipulation of molecules with controllable external forces is a dream of chemists. Molecules are inherently quantum-mechanical systems, control of which potentially can lead to quantum technology, such as quantum sensing and computing. This book demonstrates a combination of the ice film nanocapacitor method and the matrix isolation technique enabled the application of intense external dc electric fields across the isolated molecules and molecular clusters. Changes in molecular states induced by fields were monitored by means of vibrational spectroscopy. Also, the book presents manipulations of the inversion tunneling dynamics of ammonia molecule and the dislocation of acidic proton in hydrogen chloride–water complex. The book shows that the vibrational spectroscopy with the aid of unprecedentedly strong dc electric field can provide rich information on the electrostatic behaviors of molecules and molecular clusters, which underlie the understanding of intermolecular processes and molecular manipulation.
Author: F. N. Harllee
Publisher:
ISBN:
Category : Ions
Languages : en
Pages : 48
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Book Description
