The Chemistry of Cyclo-Octatetraene and Its Derivatives

The Chemistry of Cyclo-Octatetraene and Its Derivatives PDF Author: G. I. Fray
Publisher: Cambridge University Press
ISBN: 9780521215800
Category : Science
Languages : en
Pages : 512

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Book Description
Cyclo-octatetraene is a compound of fundamental importance to theoretical chemists and has played an outstanding role in many aspects of organic and organometallic chemistry. As [8]annulene, the next higher vinylogue of benzene, it is essential to the understanding of cyclic alternating pi systems. As a medium-ring polyene, it undergoes a wide variety of reactions that are often accompanied by skeletal transformations, and it is the progenitor of a large number of interesting species, ranging in complexity from cyclobutadiene to triamantane. It also forms an exceptional variety of complexes with transition metals, important from the viewpoint of bonding theory, and increasingly useful in providing routes to systems that are not readily available by the conventional transformations of organic chemistry. The recent rapid developments and growth of interest in the study of cyclo-octatetraenes and its derivatives make this comprehensive review especially timely.

The Chemistry of Cyclo-Octatetraene and Its Derivatives

The Chemistry of Cyclo-Octatetraene and Its Derivatives PDF Author: G. I. Fray
Publisher: Cambridge University Press
ISBN: 9780521215800
Category : Science
Languages : en
Pages : 512

Get Book Here

Book Description
Cyclo-octatetraene is a compound of fundamental importance to theoretical chemists and has played an outstanding role in many aspects of organic and organometallic chemistry. As [8]annulene, the next higher vinylogue of benzene, it is essential to the understanding of cyclic alternating pi systems. As a medium-ring polyene, it undergoes a wide variety of reactions that are often accompanied by skeletal transformations, and it is the progenitor of a large number of interesting species, ranging in complexity from cyclobutadiene to triamantane. It also forms an exceptional variety of complexes with transition metals, important from the viewpoint of bonding theory, and increasingly useful in providing routes to systems that are not readily available by the conventional transformations of organic chemistry. The recent rapid developments and growth of interest in the study of cyclo-octatetraenes and its derivatives make this comprehensive review especially timely.

Advanced Organic Chemistry

Advanced Organic Chemistry PDF Author: Francis A. Carey
Publisher: Springer Science & Business Media
ISBN: 0387448977
Category : Science
Languages : en
Pages : 1213

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Book Description
The two-part, fifth edition of Advanced Organic Chemistry has been substantially revised and reorganized for greater clarity. The material has been updated to reflect advances in the field since the previous edition, especially in computational chemistry. Part A covers fundamental structural topics and basic mechanistic types. It can stand-alone; together, with Part B: Reaction and Synthesis, the two volumes provide a comprehensive foundation for the study in organic chemistry. Companion websites provide digital models for study of structure, reaction and selectivity for students and exercise solutions for instructors.

Aromaticity

Aromaticity PDF Author: Israel Fernandez
Publisher: Elsevier
ISBN: 0128227435
Category : Science
Languages : en
Pages : 517

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Book Description
Evaluating the aromaticity of a molecular system and the influence of this concept on its properties is a crucial step in the development of novel aromatic systems. Modern computational methods can provide researchers with a high level of insight into such aromaticity, but identifying the most appropriate method for assessing a specific system can prove difficult. Aromaticity: Modern Computational Methods and Applications reviews the latest state-of-the-art computational methods in this field and discusses their applicability for evaluating the aromaticity of a system. In addition to covering aromaticity for typical organic molecules, this volume also explores systems possessing transition metals in their structures, macrocycles and even transition structures. The influence of the aromaticity on the properties of these species (including the structure, magnetic properties and reactivity) is highlighted, along with potential applications in fields including materials science and medicinal chemistry. Finally, the controversial and fuzzy nature of aromaticity as a concept is discussed, providing the basis for an updated and more comprehensive definition of this concept. Drawing on the knowledge of an international team of experts, Aromaticity: Modern Computational Methods and Applications is a unique guide for anyone researching, studying or applying principles of aromaticity in their work, from computational and organic chemists to pharmaceutical and materials scientists. - Reviews a range of computational methods to assess the aromatic nature of different compounds, helping readers select the most useful tool for the system they are studying - Presents a complete guide to the key concepts and fundamental principles of aromaticity - Provides guidance on identifying which variables should be modified to tune the properties of an aromatic system for different potential applications

The Chemistry of Cyclobutanes

The Chemistry of Cyclobutanes PDF Author: Zvi Rappoport
Publisher: John Wiley & Sons
ISBN: 047086401X
Category : Science
Languages : en
Pages : 1266

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Book Description
The Chemistry of Cyclobutanes provides an in depth and comprehensive review of cyclobutanes and includes chapters on the theoretical and computational foundations; on analytical and spectroscopical aspects with dedicated chapters on Mass Spectrometry, NMR and IR/UV. There are also extensive application examples enabling the reader to collect both a theoretical and practical understanding. The Chemistry of Functional Groups Series was originally founded by Saul Patai (1918-1998) and in the 39 years of publishing has produced more than 100 volumes, providing outstanding reviews on all aspects of functional groups including analytical, physical and synthetic and applied chemistry. Saul Patai has been helped by outstanding editors, especially Zvi Rappoport who has now taken responsibility for the series to continue the tradition of producing high quality reviews with editors such as Y. Apeloig, I. Marek and J. Liebman.

Classics in Hydrocarbon Chemistry

Classics in Hydrocarbon Chemistry PDF Author: Henning Hopf
Publisher: John Wiley & Sons
ISBN: 3527296069
Category : Science
Languages : en
Pages : 578

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Book Description
Kohlenstoff und Wasserstoff - jedem Chemiestudenten sind sie wohlbekannt als Grundbausteine der Organischen Chemie. Welch ungeahnte Vielfalt von Verbindungen sich aus diesen Elementen aufbauen läßt, zeigt dieses einzigartige Buch. Dabei beschränkt es sich nicht nur auf die bloße Darstellung von Struktur und Eigenschaften von Kohlenwasserstoffen, sondern verdeutlicht überdies die Herausforderung, die Moleküle wie Tetrahedran, Superphan oder Dodecahedran an das synthetische Geschick eines jeden Organikers stellen. In seinem Konzept folgt das Werk - retrosynthetische Analyse der Reaktionssequenzen, ausführliche Erläuterung der Synthesemethoden, umfassende Verweise auf die Originalliteratur - dem Bestseller von K. C. Nicolaou und E. J. Sorensen "Classics in Total Synthesis". Es vermittelt so eine Fülle von generellen Prinzipien und Methoden der organischen Synthese und empfiehlt sich auf Jahre hinaus als Standardwerk, das jedem Studenten und Organiker in Forschung und Lehre geläufig sein sollte.

March's Advanced Organic Chemistry

March's Advanced Organic Chemistry PDF Author: Michael B. Smith
Publisher: John Wiley & Sons
ISBN: 1119371805
Category : Science
Languages : en
Pages : 2146

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Book Description
The completely revised and updated, definitive resource for students and professionals in organic chemistry The revised and updated 8th edition of March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure explains the theories of organic chemistry with examples and reactions. This book is the most comprehensive resource about organic chemistry available. Readers are guided on the planning and execution of multi-step synthetic reactions, with detailed descriptions of all the reactions The opening chapters of March's Advanced Organic Chemistry, 8th Edition deal with the structure of organic compounds and discuss important organic chemistry bonds, fundamental principles of conformation, and stereochemistry of organic molecules, and reactive intermediates in organic chemistry. Further coverage concerns general principles of mechanism in organic chemistry, including acids and bases, photochemistry, sonochemistry and microwave irradiation. The relationship between structure and reactivity is also covered. The final chapters cover the nature and scope of organic reactions and their mechanisms. This edition: Provides revised examples and citations that reflect advances in areas of organic chemistry published between 2011 and 2017 Includes appendices on the literature of organic chemistry and the classification of reactions according to the compounds prepared Instructs the reader on preparing and conducting multi-step synthetic reactions, and provides complete descriptions of each reaction The 8th edition of March's Advanced Organic Chemistry proves once again that it is a must-have desktop reference and textbook for every student and professional working in organic chemistry or related fields. Winner of the Textbook & Acadmic Authors Association 2021 McGuffey Longevity Award.

Advances in Organometallic Chemistry

Advances in Organometallic Chemistry PDF Author:
Publisher: Academic Press
ISBN: 0080580327
Category : Science
Languages : en
Pages : 415

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Book Description
Advances in Organometallic Chemistry

Advances in Heterocyclic Chemistry

Advances in Heterocyclic Chemistry PDF Author:
Publisher: Academic Press
ISBN: 0080576311
Category : Science
Languages : en
Pages : 405

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Book Description
Advances in Heterocyclic Chemistry

Topics in Organic Electrochemistry

Topics in Organic Electrochemistry PDF Author: W.E. Britton
Publisher: Springer Science & Business Media
ISBN: 148992034X
Category : Science
Languages : en
Pages : 306

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Book Description


Organometallics in Organic Synthesis 2

Organometallics in Organic Synthesis 2 PDF Author: Helmut Werner
Publisher: Springer Science & Business Media
ISBN: 3642742696
Category : Science
Languages : en
Pages : 326

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Book Description
Organic Synthesis via Organometallics is an interdisciplinary project sponsored by the Volkswagen Stiftung to stimulate research and discussion of advances in the field. To improve international communication , leading experts are invited to regular symposia. In this volume, 17 lectures presented at the second symposium in Würzburg, October 1988, are collected. From the topics covered it complements the previous volume, edited by A. de Meijere and H. tom Dieck.