Templated Organic Synthesis

Templated Organic Synthesis PDF Author: François Diederich
Publisher: John Wiley & Sons
ISBN: 3527613536
Category : Science
Languages : en
Pages : 431

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Book Description
Template-controlled reactions allow the synthesis of complex molecules which would hardly be achievable through classical methods. This handbook offers authoratative information on how noncovalent and covalent templates can be effectively applied to control reaction rates as well as regio- and stereoselectivity. From the concepts of template control such as molecular imprinting, self-replication, and reversible tether-directed remote functionalization, the reader is led to template-based ring-closing reactions, oligomerizations, and multiple functionalizations and their application in the synthesis of supramolecular scaffolds and natural products. The editors and authors (J. F. Stoddart, G. Wulf, D. Lynn, R. Breslow. F. Diederich, just to name a few ) , all internationally recognized experts in their area, succeeded in presenting the manifold aspects of template-controlled synthesis in a didactic way, making this methodology accessible to a broad readership of organic synthetic chemists. Well-selected, reliable key experimental protocols and an up-to-date reference list underline the practical approach of this valuable handbook. Being the first book of its kind, it will serve as a pacemaker and stimulate future research.

Templated Organic Synthesis

Templated Organic Synthesis PDF Author: François Diederich
Publisher: John Wiley & Sons
ISBN: 3527613536
Category : Science
Languages : en
Pages : 431

Get Book Here

Book Description
Template-controlled reactions allow the synthesis of complex molecules which would hardly be achievable through classical methods. This handbook offers authoratative information on how noncovalent and covalent templates can be effectively applied to control reaction rates as well as regio- and stereoselectivity. From the concepts of template control such as molecular imprinting, self-replication, and reversible tether-directed remote functionalization, the reader is led to template-based ring-closing reactions, oligomerizations, and multiple functionalizations and their application in the synthesis of supramolecular scaffolds and natural products. The editors and authors (J. F. Stoddart, G. Wulf, D. Lynn, R. Breslow. F. Diederich, just to name a few ) , all internationally recognized experts in their area, succeeded in presenting the manifold aspects of template-controlled synthesis in a didactic way, making this methodology accessible to a broad readership of organic synthetic chemists. Well-selected, reliable key experimental protocols and an up-to-date reference list underline the practical approach of this valuable handbook. Being the first book of its kind, it will serve as a pacemaker and stimulate future research.

Metal Mediated Template Synthesis of Ligands

Metal Mediated Template Synthesis of Ligands PDF Author: Otilia Costisor
Publisher: World Scientific
ISBN: 9789812794819
Category : Science
Languages : en
Pages : 316

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Book Description
This book surveys the relatively new area of the synthesis of organic ligands when metal ions act as a template. In the last fifty years this field has undergone an explosive development, marked by a great amount of literature. The material in the book has been arranged according to the type of chemical reaction involved. In this frame, the basic principles of metal template reactions and the shape of the molecules are considered. Designed to satisfy the demands of students, young researchers doing their PhDs, and those working in the field of coordination chemistry, the book details the role of the metal ions and the specific properties of the formed complexes. Metal Mediated Template Synthesis of Ligands offers a comprehensive analysis with wide-ranging references and provides an extensive overview of research on metal-directed organic ligands over the past five decades. Contents: The Template Effect; Alkylation Reactions; Schiff Condensation; Mannich Condensation; Self Condensation of Nitriles; Self-Assembled Systems. Readership: Upper level undergraduates, graduate students, academics, researchers industrialists in inorganic, solid-state, supramolecular and organic chemistry.

Introduction to Strategies for Organic Synthesis

Introduction to Strategies for Organic Synthesis PDF Author: Laurie S. Starkey
Publisher: John Wiley & Sons
ISBN: 1118180852
Category : Science
Languages : en
Pages : 360

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Book Description
The stepping-stone text for students with a preliminary knowledge of organic chemistry looking to move into organic synthesis research and graduate-level coursework Organic synthesis is an advanced but important field of organic chemistry, however resources for advanced undergraduates and graduate students moving from introductory organic chemistry courses to organic synthesis research are scarce. Introduction to Strategies for Organic Synthesis is designed to fill this void, teaching practical skills for making logical retrosynthetic disconnections, while reviewing basic organic transformations, reactions, and reactivities. Divided into seven parts that include sections on Retrosynthesis and Protective Groups; Overview of Organic Transformations; Synthesis of Monofunctional Target Molecules; Synthesis of Target Molecules with Two Functional Groups; Synthesis of Aromatic Target Molecules; Synthesis of Compounds Containing Rings; and Predicting and Controlling Stereochemistry, the book covers everything students need to successfully perform retrosynthetic analyses of target molecule synthesis. Starting with a review of functional group transformations, reagents, and reaction mechanisms, the book demonstrates how to plan a synthesis, explaining functional group analysis and strategic disconnections. Incorporating a review of the organic reactions covered, it also demonstrates each reaction from a synthetic chemist's point of view, to provide students with a clearer understanding of how retrosynthetic disconnections are made. Including detailed solutions to over 300 problems, worked-through examples and end-of-chapter comprehension problems, Introduction to Strategies for Organic Synthesis serves as a stepping stone for students with an introductory knowledge of organic chemistry looking to progress to more advanced synthetic concepts and methodologies.

Strategies and Tactics in Organic Synthesis

Strategies and Tactics in Organic Synthesis PDF Author: Michael Harmata
Publisher: Academic Press
ISBN: 9780124502833
Category : Science
Languages : en
Pages : 448

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Book Description
This title provides a forum for investigators to discuss their approach to the science and art of organic synthesis in a unique way. It provides a window into the world of design, function and synthesis that is at the leading edge of the molecular frontier.

Modern Organic Synthesis

Modern Organic Synthesis PDF Author: George S. Zweifel
Publisher: John Wiley & Sons
ISBN: 1119086760
Category : Science
Languages : en
Pages : 416

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Book Description
This book bridges the gap between sophomore and advanced / graduate level organic chemistry courses, providing students with a necessary background to begin research in either an industry or academic environment. • Covers key concepts that include retrosynthesis, conformational analysis, and functional group transformations as well as presents the latest developments in organometallic chemistry and C–C bond formation • Uses a concise and easy-to-read style, with many illustrated examples • Updates material, examples, and references from the first edition • Adds coverage of organocatalysts and organometallic reagents

Metal Carbenes in Organic Synthesis

Metal Carbenes in Organic Synthesis PDF Author: K H Dtz
Publisher: Springer Science & Business Media
ISBN: 9783540218333
Category : Science
Languages : en
Pages : 396

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Book Description
With contributions by numerous experts

Strategic Applications of Named Reactions in Organic Synthesis

Strategic Applications of Named Reactions in Organic Synthesis PDF Author: Laszlo Kurti
Publisher: Elsevier
ISBN: 0080575412
Category : Science
Languages : en
Pages : 808

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Book Description
Kurti and Czako have produced an indispensable tool for specialists and non-specialists in organic chemistry. This innovative reference work includes 250 organic reactions and their strategic use in the synthesis of complex natural and unnatural products. Reactions are thoroughly discussed in a convenient, two-page layout--using full color. Its comprehensive coverage, superb organization, quality of presentation, and wealth of references, make this a necessity for every organic chemist. - The first reference work on named reactions to present colored schemes for easier understanding - 250 frequently used named reactions are presented in a convenient two-page layout with numerous examples - An opening list of abbreviations includes both structures and chemical names - Contains more than 10,000 references grouped by seminal papers, reviews, modifications, and theoretical works - Appendices list reactions in order of discovery, group by contemporary usage, and provide additional study tools - Extensive index quickly locates information using words found in text and drawings

Advanced Nanomaterials

Advanced Nanomaterials PDF Author: Kurt E. Geckeler
Publisher: John Wiley & Sons
ISBN: 3527628959
Category : Technology & Engineering
Languages : en
Pages : 954

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Book Description
In this first comprehensive compilation of review chapters on this hot topic, more than 30 experts from around the world provide in-depth chapters on their specific areas of expertise, covering such essential topics as: * Block Copolymer Systems, Nanofibers and Nanotubes * Helical Polymer-Based Supramolecular Films * Synthesis of Inorganic Nanotubes * Gold Nanoparticles and Carbon Nanotubes * Recent Advances in Metal Nanoparticle-Attached Electrodes * Oxidation Catalysis by Nanoscale Gold, Silver, and Copper * Concepts in Self-Assembly * Nanocomposites * Amphiphilic Poly(Oxyalkylene)-Amines * Mesoporous Alumina * Nanoceramics for Medical Applications * Ecological Toxicology of Engineered Carbon Nanoparticles * Molecular Imprinting * Near-Field Raman Imaging of Nanostructures and Devices * Fullerene-Rich Nanostructures * Interactions of Carbon Nanotubes with Biomolecules * Nanoparticle-Cored Dendrimers and Hyperbranched Polymers * Nanostructured Organogels via Molecular Self-Assembly * Structural DNA Nanotechnology With its coverage of all such important areas as self-assembly, polymeric materials, bionanomaterials, nanotubes, photonic and environmental aspects, this is an essential reference for materials scientists, engineers, chemists, physicists and biologists wishing to gain an in-depth knowledge of all the disciplines involved.

Advances in Organic Synthesis

Advances in Organic Synthesis PDF Author: Atta-ur-Rahman
Publisher: Bentham Science Publishers
ISBN: 1608050297
Category : Science
Languages : en
Pages : 513

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Book Description
Advances in Organic Synthesis is a book series devoted to the latest advances in synthetic approaches towards challenging structures. It presents comprehensive articles written by eminent authorities on different synthetic approaches to selected target molecules and new methods developed to achieve specific synthetic transformations. Contributions are written by eminent scientists and each volume is edited by an authority in the field. Advances in Organic Synthesis is essential for all organic chemists in the academia and industry who wish to keep abreast of rapid and important developments in the field.

Introduction to Enzyme and Coenzyme Chemistry

Introduction to Enzyme and Coenzyme Chemistry PDF Author: T. D. H. Bugg
Publisher: John Wiley & Sons
ISBN: 1118348990
Category : Science
Languages : en
Pages : 310

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Book Description
Enzymes are giant macromolecules which catalyse biochemical reactions. They are remarkable in many ways. Their three-dimensional structures are highly complex, yet they are formed by spontaneous folding of a linear polypeptide chain. Their catalytic properties are far more impressive than synthetic catalysts which operate under more extreme conditions. Each enzyme catalyses a single chemical reaction on a particular chemical substrate with very high enantioselectivity and enantiospecificity at rates which approach “catalytic perfection”. Living cells are capable of carrying out a huge repertoire of enzyme-catalysed chemical reactions, some of which have little or no precedent in organic chemistry. The popular textbook Introduction to Enzyme and Coenzyme Chemistry has been thoroughly updated to include information on the most recent advances in our understanding of enzyme action, with additional recent examples from the literature used to illustrate key points. A major new feature is the inclusion of two-colour figures, and the addition of over 40 new figures of the active sites of enzymes discussed in the text, in order to illustrate the interplay between enzyme structure and function. This new edition provides a concise but comprehensive account from the perspective of organic chemistry, what enzymes are, how they work, and how they catalyse many of the major classes of enzymatic reactions, and will continue to prove invaluable to both undergraduate and postgraduate students of organic, bio-organic and medicinal chemistry, chemical biology, biochemistry and biotechnology.