Synthesis and Characterization of Ligands and Transition Metal Complexes Containing M-terphenyl Scaffolds PDF Download
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Author:
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Languages : en
Pages : 335
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Author:
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ISBN:
Category :
Languages : en
Pages : 335
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Author: Toby James Blundell
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Category :
Languages : en
Pages :
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Author: John C. Linehan
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Category :
Languages : en
Pages : 514
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Author: Daniel P. Lisbon
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Category :
Languages : en
Pages : 270
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Author: Veeranna Yempally
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Category :
Languages : en
Pages :
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The role of bulky tin ligands in the stabilization of transition metal complexes with electronic unsaturation has been studied to understand the mode of binding of small molecules at an unsaturated metal center. We were able to isolate electronically unsaturated Pt-Sn bimetallic complexes effective in the reversible activation of small molecules including CO, H2, C2H4, and NH3 at room temperature. We have examined the effect of the modification of ligands in Pt-Sn bimetallic complexes for the activation of small molecules and have observed that the Pt(SnBut3)2(CNBut)2 bimetallic complex reversibly activates hydrogen at room temperature both in the solid state and in solution. Similarly, we have also prepared bimetallic Pt-Sn complexes with an NHC carbine ligand which were also shown to activate hydrogen and alkenes reversibly. A bimetallic Fe-Sn cluster complex, Fe2 ([mu]-SnBut2)2(CO)8, was synthesized from the reaction of But3SnH with the Fe2(CO)9 and shown to be selective at activating the benzylic C-H bond of alkylaromatic solvent molecules. The new complexes containing tin have been characterized spectroscopically to gain an insight into the reaction mechanism involved in small molecule activation.
Author: Andrew Fessak
Publisher:
ISBN:
Category :
Languages : en
Pages : 197
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Author: Jamie Hicks
Publisher: Springer
ISBN: 9811029059
Category : Science
Languages : en
Pages : 214
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This thesis describes the synthesis and characterization of numerous metal-metal bonded complexes that are stabilized by extremely bulky amide ligands. It provides a comprehensive overview of the field, including discussions on groundbreaking complexes and reactions, before presenting in detail, exciting new findings from the PhD studies. The thesis appeals to researchers, professors and chemistry undergraduates with an interest in inorganic and/or organometallic chemistry.
![Synthesis and Structural Characterization of Mono- and Dinuclear Transition Metal Complexes Containing the Tetraaza-[14] Annulene Ligand PDF](https://books.google.com/books/content/images/frontcover/FVNAOAAACAAJ?fife=w80-h100)
Author: Joanna Czuchajowska-Wiesinger
Publisher:
ISBN:
Category : Transition metal complexes
Languages : en
Pages : 362
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Author: Diane A. Dickie
Publisher:
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Category :
Languages : en
Pages : 44
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![Synthesis, Reactivity and Structural Characterization of Transition Metal Complexes Containing Dibenzotetraaza [14] Annulene Macrocyclic Ligands PDF](https://books.google.com/books/content/images/frontcover/0IZsPwAACAAJ?fife=w80-h100)
Author: Marvin Cecil Weiss
Publisher:
ISBN:
Category : Transition metal compounds
Languages : en
Pages : 924
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