Structural and Synthetic Studies on Homo- and Heterogeneous Transition Metal Carbonyl Cluster Species PDF Download
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Author: Stephen Leonard Cook
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Author: Stephen Leonard Cook
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Author: S. L. Cook
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Author: Paul J. Dyson
Publisher: CRC Press
ISBN: 1482283077
Category : Science
Languages : en
Pages : 180
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Book Description
Transition metal carbonyl clusters (TMCCs) continue to inspire great interest in chemical research, as much for their fascinating structures as for potential industrial applications conferred by their unique properties. This highly accessible book introduces the bonding, structure, spectroscopic properties, and characterization of clusters, and then explores their synthesis, reactivity, reaction mechanisms and use in organic synthesis and catalysis. Transition Metal Carbonyl Cluster Chemistry describes models and rules that correlate cluster structure with electron count, which are then applied in worked examples. Subsequent chapters explain how bonding relates to molecular structure, demonstrate the use of spectroscopic techniques such as NMR, IR and MS in cluster chemistry, and outline the factors contributing to the stability, dynamics and reactivity of clusters. The second part of this book discusses the synthesis and applications of TMCCs. It emphasizes the differences between the reactivities of clusters vs. mononuclear metal complexes, contingent to the availability of multiple-bonding sites and heterosite reactivity. The final chapters discuss reactions in which clusters act as homogeneous catalysts; including discussion on the use of solid and biphasic liquid-liquid supported clusters in heterogeneous catalysts. A useful reference for those commencing further research or post-graduate study on metal carbonyl clusters and advanced organometallic chemistry, this book is also a cornerstone addition to academic and libraries as well as private collections.
Author: Guillermo Gonzalez-Moraga
Publisher: Springer Science & Business Media
ISBN: 3642859267
Category : Science
Languages : en
Pages : 310
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Book Description
Cluster chemistry is one of the recent, exciting areas of Inorganic Chemistry. The occurence of molecular clusters, like fullerene C60, constitutes a fundamental feature midway between the chemistry of isolated chemical compounds and that of the elements. Main features of the Cluster Chemistry of both main group and transition metal elements are treated in this book. The author highlights aspects releated to the synthesis, the structure, the special bonding and the reactivity of these species. The book is written as a textbook for senior undergraduate and postgraduate students. References in tables andillustrations permit the reader to reach relevant original information. Professor Gonzalez-Moraga fills a demand for a publication appropriate for dissemination and specially for teaching this exciting subject. From the Contents: Current Concepts in Modern Chemistry - Transition Metal Cluster Chemistry - Main Group-Transition Metal Mixed Clusters - Cluster Compounds of the Main Group Elements - Synthetic Analogues of the Active Sites of Iron-Sulfur Proteins.
Author: Pierre Braunstein
Publisher: Wiley-VCH
ISBN: 9783527295494
Category : Science
Languages : en
Pages : 708
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Book Description
Metal cluster chemistry is at the cutting edge between molecular and solid-state chemistry and has therefore had a great impact on the researchers working on organic, coordination, and solid-state chemistry, catalysis, physics, and materials science. The development of new sophisticated synthetic techniques has led to enormous progress in the synthesis of this diverse class of compounds. The number of clusters is growing rapidly, since the possible variations in the metal and ligand sphere are numerous. Modern bonding theories, such as the isolobal principle, have allowed a better understanding of the structures and properties of metal clusters, and thus paved the way for the usage of these versatile materials. Catalysis and nanomaterials are just two of the very promising application-oriented fields. Seventy six contributions, written by world experts in this research field, provide extensive coverage of different aspects of cluster chemistry, ranging from synthesis, structure determination, and dynamics to applications. Up-to-date information, including an impressive collection of structural data and illustrations, extensive coverage of the most important publications of the last decade, and many more features make this three-volume set a complete single-source guide for all researchers working in the area of cluster chemistry.
Author: Robert Bertram English
Publisher:
ISBN:
Category : Chemistry
Languages : en
Pages : 410
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Author: Zaozao Qiu
Publisher: Springer Science & Business Media
ISBN: 3642243606
Category : Science
Languages : en
Pages : 143
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Book Description
Zaozao Qiu shows in this thesis that transition metals can mediate or catalyze the cycloaddition or coupling reactions of carboryne with alkynes or alkenes to afford benzocarboranes, alkenylcarboranes or dihydrobenzocarboranes. These results represent powerful strategies to assemble useful complex molecules from very simple precursors in a single operation. Carboranes have many applications in medicine. However, their unique structures make derivatization difficult and the limited efficient synthetic methods to obtain functional carborane materials have restricted applications of carboranes within a narrow scope. This work breaks a new ground in metal-carboryne chemistry and will have a significant impact on synthetic, cluster and materials chemistry.
Author: Duward F. Shriver
Publisher: Wiley-VCH
ISBN:
Category : Science
Languages : en
Pages : 456
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Book Description
Seven chapters summarize the current status of organometallic cluster chemistry from the viewpoints of synthesis, structure and bonding, ligand substitution reactions, ligand transformations, polyhedral rearrangement, cluster fragmentation reactions, and metal clusters as homogeneous catalysts. An eighth provides an extensive bibliography of reviews for the period from 1965 to 1988. Annotation copyrighted by Book News, Inc., Portland, OR
Author: Kenton H. Whitmire
Publisher:
ISBN: 9780677256900
Category : Complex compounds
Languages : en
Pages : 110
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Book Description
This special issue reviews the literature concerning cluster complexes which contain both main group element and transition metal vertices. Synthetic methods and general reactivity patterns are summarized. Emphasis is placed on structural comparisons of cluster geometries for a wide variety of element combinations. Relationships between these mixed clusters and the main group element clusters known as Zintl ions are discussed.
Author: Brian Frederick Gilbert Johnson
Publisher: John Wiley & Sons
ISBN:
Category : Science
Languages : en
Pages : 702
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Book Description
