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Author: K. Sridharan
Publisher: Elsevier
ISBN: 0128096543
Category : Science
Languages : en
Pages : 201
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Book Description
Spectral Methods in Transition Metal Complexes provides a conceptual understanding on how to interpret the optical UV-vis, vibrational EPR, and NMR spectroscopy of transition metal complexes. Metal complexes have broad applications across chemistry in the areas of drug discovery, such as anticancer drugs, sensors, special materials for specific requirements, and catalysis, so a thorough knowledge in preparation and characterization of metal complexes, while niche, is critical. Accessible to both the seasoned researcher and the graduate student alike, this book provides readers with a single source of content that addresses spectral methods in transition metal complexes. - Provides readers with a single reference on metal complexes and coordination compounds - Contains more than 100 figures, tables, and illustrations to aid in the retention of key concepts - Authored by a scientist with nearly 40 years of experience in research and instruction
Author: K. Sridharan
Publisher: Elsevier
ISBN: 0128096543
Category : Science
Languages : en
Pages : 201
Get Book Here
Book Description
Spectral Methods in Transition Metal Complexes provides a conceptual understanding on how to interpret the optical UV-vis, vibrational EPR, and NMR spectroscopy of transition metal complexes. Metal complexes have broad applications across chemistry in the areas of drug discovery, such as anticancer drugs, sensors, special materials for specific requirements, and catalysis, so a thorough knowledge in preparation and characterization of metal complexes, while niche, is critical. Accessible to both the seasoned researcher and the graduate student alike, this book provides readers with a single source of content that addresses spectral methods in transition metal complexes. - Provides readers with a single reference on metal complexes and coordination compounds - Contains more than 100 figures, tables, and illustrations to aid in the retention of key concepts - Authored by a scientist with nearly 40 years of experience in research and instruction
Author: Mandeep Dalal
Publisher: Dalal Institute
ISBN: 8193872002
Category : Science
Languages : en
Pages : 482
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Book Description
An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory; dπ -pπ bonds; Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions; Trends in stepwise constants; Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand; Chelate effect and its thermodynamic origin; Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes; Mechanisms for ligand replacement reactions; Formation of complexes from aquo ions; Ligand displacement reactions in octahedral complexes- acid hydrolysis, base hydrolysis; Racemization of tris chelate complexes; Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes; The trans effect; Theories of trans effect; Mechanism of electron transfer reactions – types; outer sphere electron transfer mechanism and inner sphere electron transfer mechanism; Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory; Molecular orbital theory: octahedral, tetrahedral or square planar complexes; π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals; Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states); Calculation of Dq, B and β parameters; Effect of distortion on the d-orbital energy levels; Structural evidence from electronic spectrum; John-Tellar effect; Spectrochemical and nephalauxetic series; Charge transfer spectra; Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry; Guoy’s method for determination of magnetic susceptibility; Calculation of magnetic moments; Magnetic properties of free ions; Orbital contribution, effect of ligand-field; Application of magneto-chemistry in structure determination; Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes; Wade’s rules; Carboranes; Metal carbonyl clusters - low nuclearity carbonyl clusters; Total electron count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls: structure and bonding; Vibrational spectra of metal carbonyls for bonding and structure elucidation; Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Author: Ágnes Szabados
Publisher: Springer
ISBN: 3662498251
Category : Science
Languages : en
Pages : 259
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Book Description
In this Festschrift dedicated to the 60th birthday of Péter R. Surján, selected researchers in theoretical chemistry present research highlights on major developments in the field. Originally published in the journal Theoretical Chemistry Accounts, these outstanding contributions are now available in a hardcover print format, as well as a special electronic edition. This volume provides valuable content for all researchers in theoretical chemistry and will especially benefit those research groups and libraries with limited access to the journal.
Author: Victor Gutmann
Publisher: Springer Science & Business Media
ISBN: 3709136504
Category : Science
Languages : en
Pages : 474
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Book Description
Organized by Verein Österreichischer Chemiker
Author:
Publisher: ScholarlyEditions
ISBN: 146492077X
Category : Science
Languages : en
Pages : 1063
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Book Description
Transition Elements: Advances in Research and Application: 2011 Edition is a ScholarlyEditions™ eBook that delivers timely, authoritative, and comprehensive information about Transition Elements. The editors have built Transition Elements: Advances in Research and Application: 2011 Edition on the vast information databases of ScholarlyNews.™ You can expect the information about Transition Elements in this eBook to be deeper than what you can access anywhere else, as well as consistently reliable, authoritative, informed, and relevant. The content of Transition Elements: Advances in Research and Application: 2011 Edition has been produced by the world’s leading scientists, engineers, analysts, research institutions, and companies. All of the content is from peer-reviewed sources, and all of it is written, assembled, and edited by the editors at ScholarlyEditions™ and available exclusively from us. You now have a source you can cite with authority, confidence, and credibility. More information is available at http://www.ScholarlyEditions.com/.
Author: Eram Sharmin
Publisher: BoD – Books on Demand
ISBN: 9535136275
Category : Science
Languages : en
Pages : 242
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Book Description
The book presents developments and applications of these methods, such as NMR, mass, and others, including their applications in pharmaceutical and biomedical analyses. The book is divided into two sections. The first section covers spectroscopic methods, their applications, and their significance as characterization tools; the second section is dedicated to the applications of spectrophotometric methods in pharmaceutical and biomedical analyses. This book would be useful for students, scholars, and scientists engaged in synthesis, analyses, and applications of materials/polymers.
Author: Jon Paul Janet
Publisher: American Chemical Society
ISBN: 0841299005
Category : Science
Languages : en
Pages : 189
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Book Description
Recent advances in machine learning or artificial intelligence for vision and natural language processing that have enabled the development of new technologies such as personal assistants or self-driving cars have brought machine learning and artificial intelligence to the forefront of popular culture. The accumulation of these algorithmic advances along with the increasing availability of large data sets and readily available high performance computing has played an important role in bringing machine learning applications to such a wide range of disciplines. Given the emphasis in the chemical sciences on the relationship between structure and function, whether in biochemistry or in materials chemistry, adoption of machine learning by chemistsderivations where they are important
Author: Alan Earnshaw
Publisher: Elsevier
ISBN: 1483270696
Category : Science
Languages : en
Pages : 127
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Book Description
Introduction to Magnetochemistry provides an introduction to the more important aspects of magnetochemistry. The measurement of magnetic moment has been one of the most consistently useful to coordination chemists. For teaching purposes it provides a simple method of illustrating the ideas of electronic structure, and in research it can provide fundamental information about the bonding and stereochemistry of complexes. The book contains six chapters covering topics such as free atoms and ions, transition metal complexes, crystal field theory, second and third row transition metal complexes, antiferromagnetism, and spin-pairing of electrons. The final chapter describes important experimental methods and then to shows briefly the way in which the problems of interpretation may be tackled.
Author: Hartmut Yersin
Publisher: Springer
ISBN: 3540444475
Category : Science
Languages : en
Pages : 198
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Book Description
Transition metal and rare earth compounds are investigated intensively because of important questions concerning fundamental research problems. More recently also their enormous potential for the development of new materials for photophysical and photochemical applications has been explored. Thus, it is important to focus on a deeper understanding of the elctronic energies, transition prohabilities, intermolecular interactions, etc.. This task has been accomplished by leading researchers in the field. They present introductions into, but also detailed reviews of the current state of knowledge of three different subjects.
Author: Muhammad Maqbool
Publisher: Bentham Science Publishers
ISBN: 9815136909
Category : Science
Languages : en
Pages : 402
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Book Description
An Introduction to Non-Ionizing Radiation provides a comprehensive understanding of non-ionizing radiation (NIR), exploring its uses and potential risks. The information is presented in a simple and concise way to facilitate easy understanding of relevant concepts and applications. Chapters provide a summary and include relevant equations that explain NIR physics. Other features of the book include colorful illustrations and detailed reference lists. With a focus on safety and protection, the book also explains how to mitigate the adverse effects of non-ionizing radiation with the help of ANSI guidelines and regulations. An Introduction to Non-Ionizing Radiation comprises twelve chapters, each explaining various aspects of non-ionizing radiation, including: Fundamental concepts of non-ionizing radiation including types and sources Interaction with matter Electromagnetic fields The electromagnetic wave spectrum (UV, visible light, IR waves, microwaves and radio waves) Lasers Acoustic waves and ultrasound Regulations for non-ionizing radiation. Risk management of non-ionizing radiation The book is intended as a primer on non-ionizing radiation for a broad range of scholars and professionals in physics, engineering and clinical medicine.
